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Mesoporous aluminosilicate from nanocellulose template: effect of porosity, morphology and catalytic activity for biofuel production

Author

Listed:
  • Jovita, Stella
  • Melenia, Alvina Tata
  • Santoso, Eko
  • Subagyo, Riki
  • Tamim, Rustam
  • Asikin-Mijan, Nurul
  • Holilah, Holilah
  • Bahruji, Hasliza
  • Nugraha, Reva Edra
  • Jalil, Aishah Abdul
  • Tehubijuluw, Hellna
  • Ulfa, Maria
  • Prasetyoko, Didik

Abstract

Mesoporous aluminosilicate (Al-MS) with different morphology and porosity is synthesized using a combination of sol-gel and hydrothermal methods by controlling the ratio between P123 and nanocellulose (NCC). The role of NCC as templates is elucidated based on the transformation of Al-MS from rod-like morphology with hexagonal pores to uniform nanoparticles with intraparticle mesostructure at increasing NCC ratios. Increasing NCC concentration reduced the regularity of the mesopores. TEM analysis revealed a hexagonal pore arrangement for Al-MS and Al-MS (0.25). In contrast, Al-MS (1) with only NCC shows disordered mesostructure. Optimization of P123:NCC ratio enhances the Vmeso/Vmicro to reach the optimum value of ∼18.65, which is essential to enhance hydrocarbon yield. Al-MS (0.25) is the most active catalyst for deoxygenation (DO) of Calophyllum inophyllum oil, reaching 95.98 % conversion, 50.77 % liquid yield and 60.27 % selectivity towards n-(C15+17) hydrocarbon. In general, Al-MS (0.25) demonstrates outstanding performance owing to its good physicochemical characteristics and acidity.

Suggested Citation

  • Jovita, Stella & Melenia, Alvina Tata & Santoso, Eko & Subagyo, Riki & Tamim, Rustam & Asikin-Mijan, Nurul & Holilah, Holilah & Bahruji, Hasliza & Nugraha, Reva Edra & Jalil, Aishah Abdul & Tehubijulu, 2025. "Mesoporous aluminosilicate from nanocellulose template: effect of porosity, morphology and catalytic activity for biofuel production," Renewable Energy, Elsevier, vol. 250(C).
    • Handle: RePEc:eee:renene:v:250:y:2025:i:c:s0960148125009553
    DOI: 10.1016/j.renene.2025.123293
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    References listed on IDEAS

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    1. Pattanaik, Bhabani Prasanna & Misra, Rahul Dev, 2017. "Effect of reaction pathway and operating parameters on the deoxygenation of vegetable oils to produce diesel range hydrocarbon fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 545-557.
    2. Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Norhasyima, R.S., 2011. "Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3501-3515.
    3. Tamim, Rustam & Prasetyoko, Didik & Jovita, Stella & Ni'mah, Yatim Lailun & Nugraha, Reva Edra & Holilah, Holilah & Bahruji, Hasliza & Yusop, Rahimi & Asikin-Mijan, Nurul & Jalil, Aishah Abdul & Harta, 2024. "Low temperature pyrolysis of waste cooking oil using marble waste for bio-jet fuel production," Renewable Energy, Elsevier, vol. 232(C).
    4. Hafriz, R.S.R.M. & Shafizah, I. Nor & Arifin, N.A. & Salmiaton, A. & Yunus, R. & Yap, Y.H. Taufiq & Shamsuddin, A.H., 2021. "Effect of Ni/Malaysian dolomite catalyst synthesis technique on deoxygenation reaction activity of waste cooking oil," Renewable Energy, Elsevier, vol. 178(C), pages 128-143.
    5. Arumugam, A. & Ponnusami, V., 2019. "Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview," Renewable Energy, Elsevier, vol. 131(C), pages 459-471.
    6. Goh, Brandon Han Hoe & Chong, Cheng Tung & Milano, Jassinnee & Tiong, Sieh Kiong & Cui, Yanbin & Ng, Jo-Han, 2024. "Response optimisation of TiO2-supported bimetallic NiCo catalyst for the cracking and deoxygenation of waste cooking oil into jet-fuel range hydrocarbon fuels under non-hydrogen environment," Energy, Elsevier, vol. 309(C).
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    1. Dilmaghani, Amirali & Saidi, Majid, 2026. "In-situ hydrodeoxygenation of anisole as a representative compound of bio-oil oxygenates to biofuel over Ni-Mo/γ-Al2O3 catalyst," Renewable Energy, Elsevier, vol. 260(C).

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