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Comparative study of natural dolomitic rock and waste mixed seashells as heterogeneous catalysts for the methanolysis of palm oil to biodiesel

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  • Jaiyen, Siyada
  • Naree, Thikumporn
  • Ngamcharussrivichai, Chawalit

Abstract

Natural dolomitic rock and waste mixed seashells were investigated as renewable sources for preparing heterogeneous catalysts for the methanolysis of palm oil to biodiesel as fatty acid methyl esters (FAME) at 60 °C and ambient pressure. After calcination at 800 °C, the dolomite as the mixed CaO·MgO catalyst possessed smaller CaO crystallites, a higher thermal stability and higher basicity than the pure CaO catalyst derived from the seashells. Although both catalysts gave the FAME yield >98% (w/w), the calcined dolomite exhibited a faster methanolysis rate and higher stability in use than the likewise calcined seashells. The linear correlation of the FAME yield to the amount of CaO phase containing in both catalysts supported that CaO was the active site. The catalyst deactivation was relevant to the formation of calcium glyceroxides. The presence of MgO dispersed in the CaO matrix was important for the superior physicochemical and catalytic properties of the natural dolomite calcined at 800 °C.

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  • Jaiyen, Siyada & Naree, Thikumporn & Ngamcharussrivichai, Chawalit, 2015. "Comparative study of natural dolomitic rock and waste mixed seashells as heterogeneous catalysts for the methanolysis of palm oil to biodiesel," Renewable Energy, Elsevier, vol. 74(C), pages 433-440.
    • Handle: RePEc:eee:renene:v:74:y:2015:i:c:p:433-440
    DOI: 10.1016/j.renene.2014.08.050
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    1. Noiroj, Krisada & Intarapong, Pisitpong & Luengnaruemitchai, Apanee & Jai-In, Samai, 2009. "A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil," Renewable Energy, Elsevier, vol. 34(4), pages 1145-1150.
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    2. Nahas, Lea & Dahdah, Eliane & Aouad, Samer & El Khoury, Bilal & Gennequin, Cedric & Abi Aad, Edmond & Estephane, Jane, 2023. "Highly efficient scallop seashell-derived catalyst for biodiesel production from sunflower and waste cooking oils: Reaction kinetics and effect of calcination temperature studies," Renewable Energy, Elsevier, vol. 202(C), pages 1086-1095.
    3. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.
    4. Jindapon, Wayu & Ruengyoo, Supapan & Kuchonthara, Prapan & Ngamcharussrivichai, Chawalit & Vitidsant, Tharapong, 2020. "Continuous production of fatty acid methyl esters and high-purity glycerol over a dolomite-derived extrudate catalyst in a countercurrent-flow trickle-bed reactor," Renewable Energy, Elsevier, vol. 157(C), pages 626-636.
    5. Bet-Moushoul, Elsie & Farhadi, Khalil & Mansourpanah, Yaghoub & Molaie, Rahim & Forough, Mehrdad & Nikbakht, Ali Mohammad, 2016. "Development of novel Ag/bauxite nanocomposite as a heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 92(C), pages 12-21.
    6. Xu, Chunping & Nasrollahzadeh, Mahmoud & Sajjadi, Mohaddeseh & Maham, Mehdi & Luque, Rafael & Puente-Santiago, Alain R., 2019. "Benign-by-design nature-inspired nanosystems in biofuels production and catalytic applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 195-252.
    7. Sundus, F. & Fazal, M.A. & Masjuki, H.H., 2017. "Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 399-412.
    8. Thitsartarn, Warintorn & Maneerung, Thawatchai & Kawi, Sibudjing, 2015. "Highly active and durable Ca-doped Ce-SBA-15 catalyst for biodiesel production," Energy, Elsevier, vol. 89(C), pages 946-956.
    9. Vargas, Edgar M. & Neves, Márcia C. & Tarelho, Luís A.C. & Nunes, Maria I., 2019. "Solid catalysts obtained from wastes for FAME production using mixtures of refined palm oil and waste cooking oils," Renewable Energy, Elsevier, vol. 136(C), pages 873-883.

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