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Waste capiz (Amusium cristatum) shell as a new heterogeneous catalyst for biodiesel production

Author

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  • Suryaputra, Wijaya
  • Winata, Indra
  • Indraswati, Nani
  • Ismadji, Suryadi

Abstract

The waste Capiz shell was utilized as raw material for catalyst production for biodiesel preparation. During calcination process, the calcium carbonate content in the waste capiz shell was converted to CaO. This calcium oxide was used as catalyst for transesterification reaction between palm oil and methanol to produce biodiesel. The biodiesel preparation was conducted under the following conditions: the mole ration between methanol and palm oil was 8:1, stirring speed was 700 rpm, and reaction temperature was 60 °C for 4, 5, and 6 h reaction time. The amount of catalyst was varied at 1, 2, 3, 4, and 5 wt %. The maximum yield of biodiesel was 93 ± 2.2%, obtained at 6 h of reaction time and 3 wt % of amount of catalyst. In order to examine the reusability of catalyst developed from waste of capiz (Amusium cristatum) shell, three transesterification reaction cycles were also performed.

Suggested Citation

  • Suryaputra, Wijaya & Winata, Indra & Indraswati, Nani & Ismadji, Suryadi, 2013. "Waste capiz (Amusium cristatum) shell as a new heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 50(C), pages 795-799.
    • Handle: RePEc:eee:renene:v:50:y:2013:i:c:p:795-799
    DOI: 10.1016/j.renene.2012.08.060
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    8. Olutoye, M.A. & Wong, S.W. & Chin, L.H. & Amani, H. & Asif, M. & Hameed, B.H., 2016. "Synthesis of fatty acid methyl esters via the transesterification of waste cooking oil by methanol with a barium-modified montmorillonite K10 catalyst," Renewable Energy, Elsevier, vol. 86(C), pages 392-398.
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    10. Singh, Bhaskar & Guldhe, Abhishek & Rawat, Ismail & Bux, Faizal, 2014. "Towards a sustainable approach for development of biodiesel from plant and microalgae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 216-245.
    11. Amani, H. & Ahmad, Z. & Hameed, B.H., 2014. "Synthesis of fatty acid methyl esters via the methanolysis of palm oil over Ca3.5xZr0.5yAlxO3 mixed oxide catalyst," Renewable Energy, Elsevier, vol. 66(C), pages 680-685.
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    13. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    14. Niu, Shengli & Zhou, Yan & Li, Hui & Lu, Chunmei & Liu, Li, 2015. "An investigation on the catalytic capability of the modified white mud after activation in transesterification and kinetic calculation," Energy, Elsevier, vol. 89(C), pages 982-989.
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    16. Shehu, Basiru Gwandu & Clarke, Michèle L., 2020. "Successful and sustainable crop based biodiesel programme in Nigeria through ecological optimisation and intersectoral policy realignment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
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    18. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.

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