IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v28y2003i6p939-948.html
   My bibliography  Save this article

Some fatty acids used for latent heat storage: thermal stability and corrosion of metals with respect to thermal cycling

Author

Listed:
  • Sarı, A
  • Kaygusuz, K

Abstract

The present study includes thermal stability of some fatty acids as phase change materials (PCMs). The selected fatty acids were stearic, palmitic, myristic and lauric acid with melting temperatures between 40–63°C and industrial-grade with 90–95 % purity. Latent heat storage capacity and phase transition temperature of the PCMs were determined by Differential Scanning Calorimetry (DSC) technique as a function of after repeated thermal cycles such as 40, 410, 700 and 910. The present work also comprises the investigation of corrosion resistance of some construction materials to the fatty acids over a long period. The containment materials tested were stainless steel (SS 304 L), carbon steel (steel C20), aluminium (Al) and copper (Cu). Gravimetric analysis as mass loss (mg/cm2), corrosion rate (mg/day) and a microscopic or matellographic investigation were performed for corrosion tests after 910 thermal cycles. DSC measurements showed that all fatty acids investigated as PCMs have a good thermal stability as a function of latent heat and phase transition temperature range for an actual middle-term thermal energy storage utility. However, in long-term solar thermal applications, the palmitic acid and myristic acid may be considered more suitable PCMs than the others. From the gravimetric and metallographic results, it can be concluded that stainless steel (SS 304L) with chromium oxide (Cr2O3) surface layer and Al with aluminium oxide (Al2O3) surface layer are essentially compatible with the investigated fatty acids. Carbon steel (Steel C20) and Cupper (Cu) are only preferantially compatible with PCMs.

Suggested Citation

  • Sarı, A & Kaygusuz, K, 2003. "Some fatty acids used for latent heat storage: thermal stability and corrosion of metals with respect to thermal cycling," Renewable Energy, Elsevier, vol. 28(6), pages 939-948.
    • Handle: RePEc:eee:renene:v:28:y:2003:i:6:p:939-948
    DOI: 10.1016/S0960-1481(02)00110-6
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148102001106
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/S0960-1481(02)00110-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hasan, A. & Sayigh, A.A., 1994. "Some fatty acids as phase-change thermal energy storage materials," Renewable Energy, Elsevier, vol. 4(1), pages 69-76.
    2. Sarı, Ahmet & Kaygusuz, Kamil, 2001. "Thermal performance of myristic acid as a phase change material for energy storage application," Renewable Energy, Elsevier, vol. 24(2), pages 303-317.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, G.H. & Zhao, C.Y., 2011. "Thermal and rheological properties of microencapsulated phase change materials," Renewable Energy, Elsevier, vol. 36(11), pages 2959-2966.
    2. Karaipekli, Ali & Sarı, Ahmet, 2008. "Capric–myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 33(12), pages 2599-2605.
    3. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    4. Abhishek Anand & Karunesh Kant & Amritanshu Shukla & Chang-Ren Chen & Atul Sharma, 2021. "Thermal Stability and Reliability Test of Some Saturated Fatty Acids for Low and Medium Temperature Thermal Energy Storage," Energies, MDPI, vol. 14(15), pages 1-22, July.
    5. He, Hongtao & Zhao, Pin & Yue, Qinyan & Gao, Baoyu & Yue, Dongting & Li, Qian, 2015. "A novel polynary fatty acid/sludge ceramsite composite phase change materials and its applications in building energy conservation," Renewable Energy, Elsevier, vol. 76(C), pages 45-52.
    6. Simonsen, Galina & Ravotti, Rebecca & O'Neill, Poppy & Stamatiou, Anastasia, 2023. "Biobased phase change materials in energy storage and thermal management technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    7. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
    8. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    9. Zhao, Pin & Yue, Qinyan & He, Hongtao & Gao, Baoyu & Wang, Yan & Li, Qian, 2014. "Study on phase diagram of fatty acids mixtures to determine eutectic temperatures and the corresponding mixing proportions," Applied Energy, Elsevier, vol. 115(C), pages 483-490.
    10. Seddegh, Saeid & Wang, Xiaolin & Henderson, Alan D. & Xing, Ziwen, 2015. "Solar domestic hot water systems using latent heat energy storage medium: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 49(C), pages 517-533.
    11. Saeed, Rami M. & Schlegel, J.P. & Sawafta, R., 2019. "Characterization of high-temperature PCMs for enhancing passive safety and heat removal capabilities in nuclear reactor systems," Energy, Elsevier, vol. 189(C).
    12. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2018. "A comprehensive study of properties of paraffin phase change materials for solar thermal energy storage and thermal management applications," Energy, Elsevier, vol. 162(C), pages 1169-1182.
    13. Ferrer, Gerard & Solé, Aran & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2015. "Review on the methodology used in thermal stability characterization of phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 665-685.
    14. Islam, Md. Parvez & Morimoto, Tetsuo, 2018. "Advances in low to medium temperature non-concentrating solar thermal technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2066-2093.
    15. Rathod, Manish K. & Banerjee, Jyotirmay, 2013. "Thermal stability of phase change materials used in latent heat energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 246-258.
    16. Cai, Yibing & Gao, Chuntao & Zhang, Ting & Zhang, Zhen & Wei, Qufu & Du, Jinmei & Hu, Yuan & Song, Lei, 2013. "Influences of expanded graphite on structural morphology and thermal performance of composite phase change materials consisting of fatty acid eutectics and electrospun PA6 nanofibrous mats," Renewable Energy, Elsevier, vol. 57(C), pages 163-170.
    17. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    18. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    19. Browne, Maria C. & Boyd, Ellen & McCormack, Sarah J., 2017. "Investigation of the corrosive properties of phase change materials in contact with metals and plastic," Renewable Energy, Elsevier, vol. 108(C), pages 555-568.
    20. Golestaneh, Seyyed Iman & Karimi, Gholamreza & Babapoor, Aziz & Torabi, Farshid, 2018. "Thermal performance of co-electrospun fatty acid nanofiber composites in the presence of nanoparticles," Applied Energy, Elsevier, vol. 212(C), pages 552-564.
    21. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Cai, Yibing & Gao, Chuntao & Zhang, Ting & Zhang, Zhen & Wei, Qufu & Du, Jinmei & Hu, Yuan & Song, Lei, 2013. "Influences of expanded graphite on structural morphology and thermal performance of composite phase change materials consisting of fatty acid eutectics and electrospun PA6 nanofibrous mats," Renewable Energy, Elsevier, vol. 57(C), pages 163-170.
    2. Karaipekli, Ali & Sarı, Ahmet, 2008. "Capric–myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 33(12), pages 2599-2605.
    3. İnce, Şeyma & Seki, Yoldas & Akif Ezan, Mehmet & Turgut, Alpaslan & Erek, Aytunc, 2015. "Thermal properties of myristic acid/graphite nanoplates composite phase change materials," Renewable Energy, Elsevier, vol. 75(C), pages 243-248.
    4. Tunçbilek, Kadir & Sari, Ahmet & Tarhan, Sefa & Ergüneş, Gazanfer & Kaygusuz, Kamil, 2005. "Lauric and palmitic acids eutectic mixture as latent heat storage material for low temperature heating applications," Energy, Elsevier, vol. 30(5), pages 677-692.
    5. Karaipekli, Ali & Sarı, Ahmet & Kaygusuz, Kamil, 2007. "Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications," Renewable Energy, Elsevier, vol. 32(13), pages 2201-2210.
    6. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
    7. Yuan, Yanping & Zhang, Nan & Tao, Wenquan & Cao, Xiaoling & He, Yaling, 2014. "Fatty acids as phase change materials: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 482-498.
    8. Haiming Long & Yunkun Lu & Liang Chang & Haifeng Zhang & Jingcen Zhang & Gaoqun Zhang & Junjie Hao, 2022. "Molecular Dynamics Simulation of Thermophysical Properties and the Microstructure of Na 2 CO 3 Heat Storage Materials," Energies, MDPI, vol. 15(19), pages 1-13, September.
    9. Xu, Ben & Li, Peiwen & Chan, Cholik, 2015. "Application of phase change materials for thermal energy storage in concentrated solar thermal power plants: A review to recent developments," Applied Energy, Elsevier, vol. 160(C), pages 286-307.
    10. Liu, Chenzhen & Cheng, Qingjiang & Li, Baohuan & Liu, Xinjian & Rao, Zhonghao, 2023. "Recent advances of sugar alcohols phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    11. Rathod, Manish K. & Banerjee, Jyotirmay, 2013. "Thermal stability of phase change materials used in latent heat energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 246-258.
    12. Li, C. & Wang, R.Z., 2012. "Building integrated energy storage opportunities in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6191-6211.
    13. Al-Jandal, S.S. & Sayigh, A.A.M., 1994. "Thermal performance characteristics of STC system with Phase Change Storage," Renewable Energy, Elsevier, vol. 5(1), pages 390-399.
    14. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    15. He, Hongtao & Zhao, Pin & Yue, Qinyan & Gao, Baoyu & Yue, Dongting & Li, Qian, 2015. "A novel polynary fatty acid/sludge ceramsite composite phase change materials and its applications in building energy conservation," Renewable Energy, Elsevier, vol. 76(C), pages 45-52.
    16. Shukla, Anant & Buddhi, D. & Sawhney, R.L., 2008. "Thermal cycling test of few selected inorganic and organic phase change materials," Renewable Energy, Elsevier, vol. 33(12), pages 2606-2614.
    17. Oró, Eduard & Barreneche, Camila & Farid, Mohammed M. & Cabeza, Luisa F., 2013. "Experimental study on the selection of phase change materials for low temperature applications," Renewable Energy, Elsevier, vol. 57(C), pages 130-136.
    18. Zain Ul Abdin & Ahmed Rachid, 2021. "A Survey on Applications of Hybrid PV/T Panels," Energies, MDPI, vol. 14(4), pages 1-23, February.
    19. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    20. Menoufi, Karim & Castell, Albert & Farid, Mohammed M. & Boer, Dieter & Cabeza, Luisa F., 2013. "Life Cycle Assessment of experimental cubicles including PCM manufactured from natural resources (esters): A theoretical study," Renewable Energy, Elsevier, vol. 51(C), pages 398-403.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:28:y:2003:i:6:p:939-948. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.