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Elucidating the bioenergy potential of raw, hydrothermally carbonized and torrefied waste Arundo donax biomass in terms of physicochemical characterization, kinetic and thermodynamic parameters

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  • Nawaz, Ahmad
  • Kumar, Pradeep

Abstract

The present investigation aimed to understand the pyrolysis kinetic behavior of raw Arundo donax (Raw-AD), hydrothermally carbonized Arundo donax (HTC-AD), and torrefied Arundo donax (TOR-AD) in a thermogravimetric analyzer at dynamic heating rates. The physicochemical characterization analysis revealed that fuel properties have been enhanced after hydrothermal carbonization and torrefaction. The characterization techniques such as FE-SEM, EDX, FTIR, and XRD have been used to investigate the biomass surface morphology, inorganic elements, functional groups, and crystallinity. The kinetic parameters were calculated using the model-free methods of Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), and Vyazovkin (VZK), whereas Criado's z(α) master plot was used to elucidate the reaction mechanism. The average activation energy was obtained to be 259.11, 262.53, and 250.13 kJ/mol for Raw-AD, 115.31, 110.39, and 107.26 kJ/mol for HTC-AD, and 243.46, 242.68, and 233.79 kJ/mol for TOR-AD using OFW, KAS, and VZK method respectively. The thermodynamic analysis divulged that pyrolysis proceeded through various reaction mechanisms.

Suggested Citation

  • Nawaz, Ahmad & Kumar, Pradeep, 2022. "Elucidating the bioenergy potential of raw, hydrothermally carbonized and torrefied waste Arundo donax biomass in terms of physicochemical characterization, kinetic and thermodynamic parameters," Renewable Energy, Elsevier, vol. 187(C), pages 844-856.
    • Handle: RePEc:eee:renene:v:187:y:2022:i:c:p:844-856
    DOI: 10.1016/j.renene.2022.01.102
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    References listed on IDEAS

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    1. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
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    2. Nawaz, Ahmad & Razzak, Shaikh Abdur, 2024. "Co-pyrolysis of biomass and different plastic waste to reduce hazardous waste and subsequent production of energy products: A review on advancement, synergies, and future prospects," Renewable Energy, Elsevier, vol. 224(C).
    3. Petrovič, Aleksandra & Vohl, Sabina & Gruber, Sven & Rola, Klemen & Predikaka, Tjaša Cenčič & Čuček, Lidija & Urbancl, Danijela, 2025. "Thermogravimetric, kinetic and thermodynamic behaviour of raw and hydrothermally pretreated oil cakes during pyrolysis and TG-FTIR analysis of the gaseous products," Renewable Energy, Elsevier, vol. 247(C).
    4. Xu, Hao & Hungwe, Douglas & Yang, Pu & Yu, Mengzhu & Tie, Hieng Ong & Yoshikawa, Kunio & Takahashi, Fumitake, 2026. "Integrated hydrothermal carbonization and pyrolysis for valorizing high-moisture biomass: Structural evolution and energy efficiency evaluation," Renewable Energy, Elsevier, vol. 258(C).
    5. Nawaz, Ahmad & Kumar, Pradeep, 2023. "Thermocatalytic pyrolysis of Sesbania bispinosa biomass over Y-zeolite catalyst towards clean fuel and valuable chemicals," Energy, Elsevier, vol. 263(PB).
    6. Nawaz, Ahmad & Kumar, Pradeep, 2022. "Pyrolysis behavior of low value biomass (Sesbania bispinosa) to elucidate its bioenergy potential: Kinetic, thermodynamic and prediction modelling using artificial neural network," Renewable Energy, Elsevier, vol. 200(C), pages 257-270.

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