IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v163y2021icp1588-1594.html
   My bibliography  Save this article

Zirconium-based MOFs-loaded ionic liquid-catalyzed preparation of biodiesel from Jatropha oil

Author

Listed:
  • Dai, Qiqi
  • Yang, Zifei
  • Li, Jin
  • Cao, Yang
  • Tang, Hongbiao
  • Wei, Xiaocui

Abstract

An environmentally acidic ionic liquid was prepared with 1-methyl-imidazole, 1,3-propyl sultone and H2SO4, and successfully loaded B acidic ionic liquid into three zirconium-based MOFs to synthesize the catalyst used to prepare biodiesel from Jatropha oil by impregnation method. The structure of the catalyst was characterized by XRD, SEM, FTIR and BET. Compare the activities of the three catalysts (through PSH/UiO-66, PSH/UiO-66NO2, PSH/UiO-66-NH2) experiments, the catalytic activity of PSH/UiO-66-NO2 was found to be the highest, and the conversion rates of Jatropha oil was 96.69%. The effect of methanol oil mole ratio, catalyst dosage, reaction temperature, and reaction time on the conversion of Jatropha oil to biodiesel was investigated, an orthogonal test determined the optimum reaction conditions of using PSH/UiO-66-NO2 catalyst. The optimal reaction conditions were obtained: reaction temperature was 343 K, catalyst dosage to oil was 4 wt%, methanol to oil ratio was 25:1, reaction time was 4 h, and the average conversion rates of Jatropha oil was 97.57%, the methyl ester rate was over 99.98%. The results showed that the four reaction factors had significant effects on the Jatropha oil conversion rates: reaction time > catalyst dosage > reaction temperature > methanol to oil ratio.

Suggested Citation

  • Dai, Qiqi & Yang, Zifei & Li, Jin & Cao, Yang & Tang, Hongbiao & Wei, Xiaocui, 2021. "Zirconium-based MOFs-loaded ionic liquid-catalyzed preparation of biodiesel from Jatropha oil," Renewable Energy, Elsevier, vol. 163(C), pages 1588-1594.
    • Handle: RePEc:eee:renene:v:163:y:2021:i:c:p:1588-1594
    DOI: 10.1016/j.renene.2020.09.122
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120315470
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.09.122?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Omar M. Yaghi & Michael O'Keeffe & Nathan W. Ockwig & Hee K. Chae & Mohamed Eddaoudi & Jaheon Kim, 2003. "Reticular synthesis and the design of new materials," Nature, Nature, vol. 423(6941), pages 705-714, June.
    2. Cao, Yang & Zhou, Houbo & Li, Jin, 2016. "Preparation of a supported acidic ionic liquid on silica-gel and its application to the synthesis of biodiesel from waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 871-875.
    3. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    4. Mohammad Fauzi, Ahmad Hafiidz & Amin, Nor Aishah Saidina & Mat, Ramli, 2014. "Esterification of oleic acid to biodiesel using magnetic ionic liquid: Multi-objective optimization and kinetic study," Applied Energy, Elsevier, vol. 114(C), pages 809-818.
    5. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sandouqa, Arwa & Al-Hamamre, Zayed, 2021. "Economical evaluation of jojoba cultivation for biodiesel production in Jordan," Renewable Energy, Elsevier, vol. 177(C), pages 1116-1132.
    2. Panchal, Balaji & Zhu, Zheng & Qin, Shenjun & Chang, Tao & Zhao, Qiaojing & Sun, Yuzhuang & Zhao, Cunliang & Wang, Jinxi & Bian, Kai & Rankhamb, Santosh, 2022. "The current state applications of ethyl carbonate with ionic liquid in sustainable biodiesel production: A review," Renewable Energy, Elsevier, vol. 181(C), pages 341-354.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    2. Nitièma-Yefanova, Svitlana & Coniglio, Lucie & Schneider, Raphaël & Nébié, Roger H.C. & Bonzi-Coulibaly, Yvonne L., 2016. "Ethyl biodiesel production from non-edible oils of Balanites aegyptiaca, Azadirachta indica, and Jatropha curcas seeds – Laboratory scale development," Renewable Energy, Elsevier, vol. 96(PA), pages 881-890.
    3. Cao, Yang & Zhou, Houbo & Li, Jin, 2016. "Preparation of a supported acidic ionic liquid on silica-gel and its application to the synthesis of biodiesel from waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 871-875.
    4. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    5. Vadery, Vinu & Cherikkallinmel, Sudha Kochiyil & Ramakrishnan, Resmi M. & Sugunan, Sankaran & Narayanan, Binitha N., 2019. "Green production of biodiesel over waste borosilicate glass derived catalyst and the process up-gradation in pilot scale," Renewable Energy, Elsevier, vol. 141(C), pages 1042-1053.
    6. Brasil, Alex N. & Oliveira, Leandro S. & Franca, Adriana S., 2015. "Circulation flow reactor with ultrasound irradiation for the transesterification of vegetable oils," Renewable Energy, Elsevier, vol. 83(C), pages 1059-1065.
    7. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    8. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    9. Zahedi, Ali Reza & Mirnezami, Seyed Abolfazl, 2020. "Experimental analysis of biomass to biodiesel conversion using a novel renewable combined cycle system," Renewable Energy, Elsevier, vol. 162(C), pages 1177-1194.
    10. Mohammadreza Beydaghdari & Fahimeh Hooriabad Saboor & Aziz Babapoor & Vikram V. Karve & Mehrdad Asgari, 2022. "Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment," Energies, MDPI, vol. 15(6), pages 1-34, March.
    11. Li, Lirong & Jung, Han Sol & Lee, Jae Won & Kang, Yong Tae, 2022. "Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    12. Mohammad Anwar & Mohammad G. Rasul & Nanjappa Ashwath & Md Mofijur Rahman, 2018. "Optimisation of Second-Generation Biodiesel Production from Australian Native Stone Fruit Oil Using Response Surface Method," Energies, MDPI, vol. 11(10), pages 1-18, September.
    13. Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    14. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.
    15. Shen, Yafei, 2017. "Rice husk silica derived nanomaterials for sustainable applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 453-466.
    16. Melero, Juan A. & Bautista, L. Fernando & Morales, Gabriel & Iglesias, Jose & Sánchez-Vázquez, Rebeca, 2015. "Acid-catalyzed production of biodiesel over arenesulfonic SBA-15: Insights into the role of water in the reaction network," Renewable Energy, Elsevier, vol. 75(C), pages 425-432.
    17. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    18. Rattanaphra, Dussadee & Soodjit, Phansiri & Thanapimmetha, Anusith & Saisriyoot, Maythee & Srinophakun, Penjit, 2019. "Synthesis, characterization and catalytic activity studies of lanthanum oxide from Thai monazite ore for biodiesel production," Renewable Energy, Elsevier, vol. 131(C), pages 1128-1137.
    19. Karmakar, Avishek & Prabakaran, Vivekh & Zhao, Dan & Chua, Kian Jon, 2020. "A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications," Applied Energy, Elsevier, vol. 269(C).
    20. Wang, Yongqiang & Zhao, Dan & Chen, Guanyi & Liu, Shejiang & Ji, Na & Ding, Hui & Fu, Jianfeng, 2019. "Preparation of phosphotungstic acid based poly(ionic liquid) and its application to esterification of palmitic acid," Renewable Energy, Elsevier, vol. 133(C), pages 317-324.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:163:y:2021:i:c:p:1588-1594. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.