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Reticular synthesis and the design of new materials

Author

Listed:
  • Omar M. Yaghi

    (University of Michigan)

  • Michael O'Keeffe

    (Arizona State University)

  • Nathan W. Ockwig

    (University of Michigan)

  • Hee K. Chae

    (University of Michigan
    Hankuk University of Foreign Studies)

  • Mohamed Eddaoudi

    (University of Michigan)

  • Jaheon Kim

    (University of Michigan)

Abstract

The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal–oxygen–carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.

Suggested Citation

  • Omar M. Yaghi & Michael O'Keeffe & Nathan W. Ockwig & Hee K. Chae & Mohamed Eddaoudi & Jaheon Kim, 2003. "Reticular synthesis and the design of new materials," Nature, Nature, vol. 423(6941), pages 705-714, June.
    • Handle: RePEc:nat:nature:v:423:y:2003:i:6941:d:10.1038_nature01650
    DOI: 10.1038/nature01650
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    Cited by:

    1. Karmakar, Avishek & Prabakaran, Vivekh & Zhao, Dan & Chua, Kian Jon, 2020. "A review of metal-organic frameworks (MOFs) as energy-efficient desiccants for adsorption driven heat-transformation applications," Applied Energy, Elsevier, vol. 269(C).
    2. Ryunosuke Hayashi & Shohei Tashiro & Masahiro Asakura & Shinya Mitsui & Mitsuhiko Shionoya, 2023. "Effector-dependent structural transformation of a crystalline framework with allosteric effects on molecular recognition ability," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    3. Chengjun Kang & Kuiwei Yang & Zhaoqiang Zhang & Adam K. Usadi & David C. Calabro & Lisa Saunders Baugh & Yuxiang Wang & Jianwen Jiang & Xiaodong Zou & Zhehao Huang & Dan Zhao, 2022. "Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Wenhe Xie & Yuan Ren & Fengluan Jiang & Xin-Yu Huang & Bingjie Yu & Jianhong Liu & Jichun Li & Keyu Chen & Yidong Zou & Bingwen Hu & Yonghui Deng, 2023. "Solvent-pair surfactants enabled assembly of clusters and copolymers towards programmed mesoporous metal oxides," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Gordeeva, Larisa G. & Solovyeva, Marina V. & Aristov, Yuri I., 2016. "NH2-MIL-125 as a promising material for adsorptive heat transformation and storage," Energy, Elsevier, vol. 100(C), pages 18-24.
    6. Hong-Jing Zhu & Duan-Hui Si & Hui Guo & Ziao Chen & Rong Cao & Yuan-Biao Huang, 2024. "Oxygen-tolerant CO2 electroreduction over covalent organic frameworks via photoswitching control oxygen passivation strategy," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    7. Sirong Li & Zijun Zhou & Zuoxiu Tie & Bing Wang & Meng Ye & Lei Du & Ran Cui & Wei Liu & Cuihong Wan & Quanyi Liu & Sheng Zhao & Quan Wang & Yihong Zhang & Shuo Zhang & Huigang Zhang & Yan Du & Hui We, 2022. "Data-informed discovery of hydrolytic nanozymes," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    8. Jie Liu & Yanjun Li & Zhichao Lou, 2022. "Recent Advancements in MOF/Biomass and Bio-MOF Multifunctional Materials: A Review," Sustainability, MDPI, vol. 14(10), pages 1-17, May.
    9. J. Perego & Charl X. Bezuidenhout & I. Villa & F. Cova & R. Crapanzano & I. Frank & F. Pagano & N. Kratochwill & E. Auffray & S. Bracco & A. Vedda & C. Dujardin & P. E. Sozzani & F. Meinardi & A. Como, 2022. "Highly luminescent scintillating hetero-ligand MOF nanocrystals with engineered Stokes shift for photonic applications," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    10. Chakrabortty, Sankha & Kumar, Ramesh & Nayak, Jayato & Jeon, Byong-Hun & Dargar, Shashi Kant & Tripathy, Suraj K. & Pal, Parimal & Ha, Geon-Soo & Kim, Kwang Ho & Jasiński, Michał, 2023. "Green synthesis of MeOH derivatives through in situ catalytic transformations of captured CO2 in a membrane integrated photo-microreactor system: A state-of-art review for carbon capture and utilizati," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    11. Pooja Sindhu & K. S. Ananthram & Anil Jain & Kartick Tarafder & Nirmalya Ballav, 2023. "Insulator-to-metal-like transition in thin films of a biological metal-organic framework," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    12. Mohammadreza Beydaghdari & Fahimeh Hooriabad Saboor & Aziz Babapoor & Vikram V. Karve & Mehrdad Asgari, 2022. "Recent Advances in MOF-Based Adsorbents for Dye Removal from the Aquatic Environment," Energies, MDPI, vol. 15(6), pages 1-34, March.
    13. Chong-Chen Wang & Yuh-Shan Ho, 2016. "Research trend of metal–organic frameworks: a bibliometric analysis," Scientometrics, Springer;Akadémiai Kiadó, vol. 109(1), pages 481-513, October.
    14. Dai, Qiqi & Yang, Zifei & Li, Jin & Cao, Yang & Tang, Hongbiao & Wei, Xiaocui, 2021. "Zirconium-based MOFs-loaded ionic liquid-catalyzed preparation of biodiesel from Jatropha oil," Renewable Energy, Elsevier, vol. 163(C), pages 1588-1594.
    15. Le Zeng & Tiexin Zhang & Renhai Liu & Wenming Tian & Kaifeng Wu & Jingyi Zhu & Zhonghe Wang & Cheng He & Jing Feng & Xiangyang Guo & Abdoulkader Ibro Douka & Chunying Duan, 2023. "Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    16. Li, Lirong & Jung, Han Sol & Lee, Jae Won & Kang, Yong Tae, 2022. "Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
    17. Zhi-Zhou Ma & Qiao-Hong Li & Zirui Wang & Zhi-Gang Gu & Jian Zhang, 2022. "Electrically regulating nonlinear optical limiting of metal-organic framework film," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    18. Louis Frentzel-Beyme & Pascal Kolodzeiski & Jan-Benedikt Weiß & Andreas Schneemann & Sebastian Henke, 2022. "Quantification of gas-accessible microporosity in metal-organic framework glasses," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    19. Onur Yildirim & Matteo Bonomo & Nadia Barbero & Cesare Atzori & Bartolomeo Civalleri & Francesca Bonino & Guido Viscardi & Claudia Barolo, 2020. "Application of Metal-Organic Frameworks and Covalent Organic Frameworks as (Photo)Active Material in Hybrid Photovoltaic Technologies," Energies, MDPI, vol. 13(21), pages 1-48, October.
    20. Jyoti Shanker Pandey & Nicolas von Solms, 2022. "Metal–Organic Frameworks and Gas Hydrate Synergy: A Pandora’s Box of Unanswered Questions and Revelations," Energies, MDPI, vol. 16(1), pages 1-30, December.
    21. Gordeeva, Larisa G. & Solovyeva, Marina V. & Sapienza, Alessio & Aristov, Yuri I., 2020. "Potable water extraction from the atmosphere: Potential of MOFs," Renewable Energy, Elsevier, vol. 148(C), pages 72-80.
    22. Tatsidjodoung, Parfait & Le Pierrès, Nolwenn & Luo, Lingai, 2013. "A review of potential materials for thermal energy storage in building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 327-349.
    23. Raoof, Jahan-Bakhsh & Hosseini, Sayed Reza & Ojani, Reza & Mandegarzad, Sakineh, 2015. "MOF-derived Cu/nanoporous carbon composite and its application for electro-catalysis of hydrogen evolution reaction," Energy, Elsevier, vol. 90(P1), pages 1075-1081.
    24. Xinxing Peng & Philipp M. Pelz & Qiubo Zhang & Peican Chen & Lingyun Cao & Yaqian Zhang & Hong-Gang Liao & Haimei Zheng & Cheng Wang & Shi-Gang Sun & Mary C. Scott, 2022. "Observation of formation and local structures of metal-organic layers via complementary electron microscopy techniques," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    25. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.

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