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Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms

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  • Li, Lirong
  • Jung, Han Sol
  • Lee, Jae Won
  • Kang, Yong Tae

Abstract

Concern about global warming has led to substantial global-scale efforts to remove CO2 from both emission sources and the atmosphere. Metal–organic frameworks, which may be considered a new class of porous materials, exhibit a high working capacity at low CO2 concentrations, owing to their ultrahigh surface area as well as large inner spaces and exterior channels. In this study, diverse of metal–organic frameworks have been clearly presented, including the definitions, origin of the nomenclatures, and development and synthesis methods. Furthermore, research efforts on MOF-based CO2 adsorption and storage have been reviewed, including the CO2 uptake capacity, gas molecule diffusivity, adsorption heat, and binding sites. We also review the numerical methods employed in the visualization of the CO2 adsorption process in MOFs and suggest some features of simulations for comparison with experiments. Finally, a new viewpoint on the adsorption mechanisms of CO2 on MOFs is proposed based on our own research; to this end, the CO2 adsorption isotherms and self-diffusion coefficients of a series of chemically similar MOFs are carefully discussed.

Suggested Citation

  • Li, Lirong & Jung, Han Sol & Lee, Jae Won & Kang, Yong Tae, 2022. "Review on applications of metal–organic frameworks for CO2 capture and the performance enhancement mechanisms," Renewable and Sustainable Energy Reviews, Elsevier, vol. 162(C).
  • Handle: RePEc:eee:rensus:v:162:y:2022:i:c:s1364032122003471
    DOI: 10.1016/j.rser.2022.112441
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    References listed on IDEAS

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    3. Bo Wang & Adrien P. Côté & Hiroyasu Furukawa & Michael O’Keeffe & Omar M. Yaghi, 2008. "Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs," Nature, Nature, vol. 453(7192), pages 207-211, May.
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    Cited by:

    1. Zhang, Chen & Zhang, Xinqi & Su, Tingyu & Zhang, Yiheng & Wang, Liwei & Zhu, Xuancan, 2023. "Modification schemes of efficient sorbents for trace CO2 capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    2. Chakrabortty, Sankha & Kumar, Ramesh & Nayak, Jayato & Jeon, Byong-Hun & Dargar, Shashi Kant & Tripathy, Suraj K. & Pal, Parimal & Ha, Geon-Soo & Kim, Kwang Ho & Jasiński, Michał, 2023. "Green synthesis of MeOH derivatives through in situ catalytic transformations of captured CO2 in a membrane integrated photo-microreactor system: A state-of-art review for carbon capture and utilizati," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).

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