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Biodiesel production in an autoclave reactor using waste palm oil and coconut coir husk derived catalyst

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  • Thushari, Indika
  • Babel, Sandhya
  • Samart, Chanatip

Abstract

The present study investigates biodiesel production from waste palm oil (WPO) using coconut coir husk (CCH) derived solid acid catalyst. The catalyst was prepared by the direct in-situ concentrated sulfuric acid impregnation. The presence of active sites, such as sulfonic, carboxylic, and phenolic OH functional groups on the catalyst was confirmed by Fourier transform infrared (FT-IR) spectroscopy and X-ray photoelectron spectroscopy (XPS). The highest biodiesel yield of 89.8% was obtained under optimum conditions of 10 wt % catalyst, 12:1 methanol:oil (molar ratio), after 3 h at 130 °C and 500 rpm, in a laboratory autoclave reactor. It was found that biodiesel yield increases with increasing reaction temperature, reaction time, and catalyst loading, up to an optimum value. The catalyst can be reused for four cycles and the biodiesel yield was >77%. Relatively higher activity may be due to the high acid density of the catalyst due to the presence of hydrophilic functional groups bonded to the hydrophobic carbon structure. It was found that, kinematic viscosity (2.9 mm2 s−1), pour point (−6 °C), heating value (38.1 MJ kg−1), and oxidation stability (3 h) of the produced biodiesel are in accordance with the international standards. Therefore, the produced biodiesel can be used.

Suggested Citation

  • Thushari, Indika & Babel, Sandhya & Samart, Chanatip, 2019. "Biodiesel production in an autoclave reactor using waste palm oil and coconut coir husk derived catalyst," Renewable Energy, Elsevier, vol. 134(C), pages 125-134.
    • Handle: RePEc:eee:renene:v:134:y:2019:i:c:p:125-134
    DOI: 10.1016/j.renene.2018.11.030
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    1. Guo, Feng & Xiu, Zhi-Long & Liang, Zhi-Xia, 2012. "Synthesis of biodiesel from acidified soybean soapstock using a lignin-derived carbonaceous catalyst," Applied Energy, Elsevier, vol. 98(C), pages 47-52.
    2. Dhawane, Sumit H. & Bora, Akash Pratim & Kumar, Tarkeshwar & Halder, Gopinath, 2017. "Parametric optimization of biodiesel synthesis from rubber seed oil using iron doped carbon catalyst by Taguchi approach," Renewable Energy, Elsevier, vol. 105(C), pages 616-624.
    3. Akinfalabi, Shehu-Ibrahim & Rashid, Umer & Yunus, Robiah & Taufiq-Yap, Yun Hin, 2017. "Synthesis of biodiesel from palm fatty acid distillate using sulfonated palm seed cake catalyst," Renewable Energy, Elsevier, vol. 111(C), pages 611-619.
    4. Korkut, Ibrahim & Bayramoglu, Mahmut, 2018. "Selection of catalyst and reaction conditions for ultrasound assisted biodiesel production from canola oil," Renewable Energy, Elsevier, vol. 116(PA), pages 543-551.
    5. César, Aldara da Silva & Werderits, Dayana Elizabeth & de Oliveira Saraiva, Gabriela Leal & Guabiroba, Ricardo César da Silva, 2017. "The potential of waste cooking oil as supply for the Brazilian biodiesel chain," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 246-253.
    6. Subramonia Pillai, N. & Kannan, P. Seeni & Vettivel, S.C. & Suresh, S., 2017. "Optimization of transesterification of biodiesel using green catalyst derived from Albizia Lebbeck Pods by mixture design," Renewable Energy, Elsevier, vol. 104(C), pages 185-196.
    7. Nongbe, Medy C. & Ekou, Tchirioua & Ekou, Lynda & Yao, Kouassi Benjamin & Le Grognec, Erwan & Felpin, François-Xavier, 2017. "Biodiesel production from palm oil using sulfonated graphene catalyst," Renewable Energy, Elsevier, vol. 106(C), pages 135-141.
    8. Hajjari, Masoumeh & Tabatabaei, Meisam & Aghbashlo, Mortaza & Ghanavati, Hossein, 2017. "A review on the prospects of sustainable biodiesel production: A global scenario with an emphasis on waste-oil biodiesel utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 445-464.
    9. Lokman, Ibrahim M. & Rashid, Umer & Taufiq-Yap, Yun Hin & Yunus, Robiah, 2015. "Methyl ester production from palm fatty acid distillate using sulfonated glucose-derived acid catalyst," Renewable Energy, Elsevier, vol. 81(C), pages 347-354.
    10. Ngaosuwan, Kanokwan & Goodwin, James G. & Prasertdham, Piyasan, 2016. "A green sulfonated carbon-based catalyst derived from coffee residue for esterification," Renewable Energy, Elsevier, vol. 86(C), pages 262-269.
    11. Shu, Qing & Gao, Jixian & Nawaz, Zeeshan & Liao, Yuhui & Wang, Dezheng & Wang, Jinfu, 2010. "Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst," Applied Energy, Elsevier, vol. 87(8), pages 2589-2596, August.
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    5. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.

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