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Castor oil transesterification reaction: A kinetic study and optimization of parameters

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  • Ramezani, K.
  • Rowshanzamir, S.
  • Eikani, M.H.

Abstract

In this paper, parameters affecting castor oil transesterification reaction were investigated. Applying four basic catalysts including NaOCH3, NaOH, KOCH3 and KOH the best one with maximum biodiesel yield was identified. Using Taguchi method consisting four parameters and three levels, the best experimental conditions were determined. Reaction temperature (25, 65 and 80°C), mixing intensity (250, 400 and 600rpm), alcohol/oil ratio (4:1, 6:1 and 8:1) and catalyst concentration (0.25, 0.35 and 0.5%) were selected as experimental parameters. It was concluded that reaction temperature and mixing intensity can be optimized. Using the optimum results, we proposed a kinetic model which resulted in establishing an equation for the beginning rate of transesterification reaction. Furthermore, applying ASTM D 976 correlation, minimum cetane number of produced biodiesel was determined as 37.1.

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  • Ramezani, K. & Rowshanzamir, S. & Eikani, M.H., 2010. "Castor oil transesterification reaction: A kinetic study and optimization of parameters," Energy, Elsevier, vol. 35(10), pages 4142-4148.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:10:p:4142-4148
    DOI: 10.1016/j.energy.2010.06.034
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    2. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    3. López, I. & Pinzi, S. & Leiva-Candia, D. & Dorado, M.P., 2016. "Multiple response optimization to reduce exhaust emissions and fuel consumption of a diesel engine fueled with olive pomace oil methyl ester/diesel fuel blends," Energy, Elsevier, vol. 117(P2), pages 398-404.
    4. Perdomo-Hurtado, Luis & Rincón Tabares, Juan Sebastián & Correa, Danahe Marmolejo & Perdomo, Felipe A., 2017. "Castor oil preheater selection based on entropy generation and exergy effectiveness criteria," Energy, Elsevier, vol. 120(C), pages 805-815.
    5. Akhabue, Christopher Ehiaguina & Osa-Benedict, Evidence Osayi & Oyedoh, Eghe Amenze & Otoikhian, Shegun Kevin, 2020. "Development of a bio-based bifunctional catalyst for simultaneous esterification and transesterification of neem seed oil: Modeling and optimization studies," Renewable Energy, Elsevier, vol. 152(C), pages 724-735.
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    7. Silva, Wellington Costa & Castro, Maria Priscila Pessanha & Perez, Victor Haber & Machado, Francisco A. & Mota, Leonardo & Sthel, Marcelo Silva, 2016. "Thermal degradation of ethanolic biodiesel: Physicochemical and thermal properties evaluation," Energy, Elsevier, vol. 114(C), pages 1093-1099.
    8. Ezzati, Rohollah & Ranjbar, Shahram & Soltanabadi, Azim, 2021. "Kinetics models of transesterification reaction for biodiesel production: A theoretical analysis," Renewable Energy, Elsevier, vol. 168(C), pages 280-296.
    9. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    10. Aboelazayem, Omar & El-Gendy, Nour Sh. & Abdel-Rehim, Ahmed A. & Ashour, Fatma & Sadek, Mohamed A., 2018. "Biodiesel production from castor oil in Egypt: Process optimisation, kinetic study, diesel engine performance and exhaust emissions analysis," Energy, Elsevier, vol. 157(C), pages 843-852.
    11. Thakkar, Kartikkumar & Kachhwaha, Surendra Singh & Kodgire, Pravin & Srinivasan, Seshasai, 2021. "Combustion investigation of ternary blend mixture of biodiesel/n-butanol/diesel: CI engine performance and emission control," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    12. Vieira, Bruno & Nadaleti, Willian Cézar & Sarto, Ewerson, 2021. "The effect of the addition of castor oil to residual soybean oil to obtain biodiesel in Brazil: Energy matrix diversification," Renewable Energy, Elsevier, vol. 165(P1), pages 657-667.
    13. Dias, J.M. & Araújo, J.M. & Costa, J.F. & Alvim-Ferraz, M.C.M. & Almeida, M.F., 2013. "Biodiesel production from raw castor oil," Energy, Elsevier, vol. 53(C), pages 58-66.
    14. Kaur, Ravneet & Gera, Poonam & Jha, Mithilesh Kumar & Bhaskar, Thallada, 2019. "Reaction parameters effect on hydrothermal liquefaction of castor (Ricinus Communis) residue for energy and valuable hydrocarbons recovery," Renewable Energy, Elsevier, vol. 141(C), pages 1026-1041.
    15. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    16. Ko, Chun-Han & Yeh, Kai-Wun & Wang, Ya-Nang & Wu, Chien-Hou & Chang, Fang-Chih & Cheng, Ming-Hsun & Liou, Chia-Shin, 2012. "Impact of methanol addition strategy on enzymatic transesterification of jatropha oil for biodiesel processing," Energy, Elsevier, vol. 48(1), pages 375-379.
    17. José María Encinar & Ana Pardal & Nuria Sánchez & Sergio Nogales, 2018. "Biodiesel by Transesterification of Rapeseed Oil Using Ultrasound: A Kinetic Study of Base-Catalysed Reactions," Energies, MDPI, vol. 11(9), pages 1-13, August.
    18. Arunkumar, M. & Kannan, M. & Murali, G., 2019. "Experimental studies on engine performance and emission characteristics using castor biodiesel as fuel in CI engine," Renewable Energy, Elsevier, vol. 131(C), pages 737-744.
    19. Niu, Shengli & Zhou, Yan & Li, Hui & Lu, Chunmei & Liu, Li, 2015. "An investigation on the catalytic capability of the modified white mud after activation in transesterification and kinetic calculation," Energy, Elsevier, vol. 89(C), pages 982-989.
    20. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    21. Torrentes-Espinoza, G. & Miranda, B.C. & Vega-Baudrit, J. & Mata-Segreda, Julio F., 2017. "Castor oil (Ricinus communis) supercritical methanolysis," Energy, Elsevier, vol. 140(P1), pages 426-435.
    22. Satyanarayana, M. & Muraleedharan, C., 2011. "A comparative study of vegetable oil methyl esters (biodiesels)," Energy, Elsevier, vol. 36(4), pages 2129-2137.
    23. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.

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