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Thermal degradation of ethanolic biodiesel: Physicochemical and thermal properties evaluation

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  • Silva, Wellington Costa
  • Castro, Maria Priscila Pessanha
  • Perez, Victor Haber
  • Machado, Francisco A.
  • Mota, Leonardo
  • Sthel, Marcelo Silva

Abstract

The aim of this paper was to study the thermal degradation of soybean biodiesel attained by ethanolic route. The soybean biodiesel samples were subjected to heating treatment at 150 °C for 24 h in a closed oven under controlled atmosphere. During the experiments, samples were withdrawn at intervals of 3, 6, 9, 12, 15 and 24 h for physicochemical and thermophysical properties analysis. The biodiesel degradation was validated by Thermogravimetric analysis since their profiles for control and treated biodiesel were different. Also, 1H NMR confirmed this result due to a significant reduction at the signals related to the 1H located near to the double bonds in the unsaturated ethyl esters in agreement with an iodine index reduction and viscosity increase observed during degradation. Nevertheless, degraded biodiesel, under study conditions, preserved its thermophysical properties. These results may be relevant to qualify the produced biodiesel quality and collect physicochemical and thermophysical data important for applications in combustion studies including project of fuel injection systems.

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  • Silva, Wellington Costa & Castro, Maria Priscila Pessanha & Perez, Victor Haber & Machado, Francisco A. & Mota, Leonardo & Sthel, Marcelo Silva, 2016. "Thermal degradation of ethanolic biodiesel: Physicochemical and thermal properties evaluation," Energy, Elsevier, vol. 114(C), pages 1093-1099.
    • Handle: RePEc:eee:energy:v:114:y:2016:i:c:p:1093-1099
    DOI: 10.1016/j.energy.2016.08.052
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    1. Armando Caldeira-Pires & Sandra Maria Da Luz & Silvia Palma-Rojas & Thiago Oliveira Rodrigues & Vanessa Chaves Silverio & Frederico Vilela & Paulo Cesar Barbosa & Ana Maria Alves, 2013. "Sustainability of the Biorefinery Industry for Fuel Production," Energies, MDPI, vol. 6(1), pages 1-22, January.
    2. Ramezani, K. & Rowshanzamir, S. & Eikani, M.H., 2010. "Castor oil transesterification reaction: A kinetic study and optimization of parameters," Energy, Elsevier, vol. 35(10), pages 4142-4148.
    3. Shahid, Ejaz M. & Jamal, Younis, 2011. "Production of biodiesel: A technical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4732-4745.
    4. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul & Aghili, Nasim, 2013. "The scenario of greenhouse gases reduction in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 400-409.
    5. Pereira Jr., Amaro Olimpio & Soares, Jeferson Borghetti & de Oliveira, Ricardo Gorini & de Queiroz, Renato Pinto, 2008. "Energy in Brazil: Toward sustainable development?," Energy Policy, Elsevier, vol. 36(1), pages 73-83, January.
    6. Geraldes Castanheira, Érica & Grisoli, Renata & Freire, Fausto & Pecora, Vanessa & Coelho, Suani Teixeira, 2014. "Environmental sustainability of biodiesel in Brazil," Energy Policy, Elsevier, vol. 65(C), pages 680-691.
    7. Costa, A.O. & Oliveira, L.B. & Lins, M.P.E. & Silva, A.C.M. & Araujo, M.S.M. & Pereira Jr., A.O. & Rosa, L.P., 2013. "Sustainability analysis of biodiesel production: A review on different resources in Brazil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 407-412.
    8. Souza, Simone Pereira & Seabra, Joaquim E.A., 2013. "Environmental benefits of the integrated production of ethanol and biodiesel," Applied Energy, Elsevier, vol. 102(C), pages 5-12.
    9. Khor, Cheng Seong & Lalchand, G., 2014. "A review on sustainable power generation in Malaysia to 2030: Historical perspective, current assessment, and future strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 952-960.
    10. Rawat, Devendra S. & Joshi, Girdhar & Lamba, Bhawna Y. & Tiwari, Avanish K. & Kumar, Pankaj, 2015. "The effect of binary antioxidant proportions on antioxidant synergy and oxidation stability of Jatropha and Karanja biodiesels," Energy, Elsevier, vol. 84(C), pages 643-655.
    11. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    12. Seo, Youngguk & Kim, Seong-Min, 2013. "Estimation of greenhouse gas emissions from road traffic: A case study in Korea," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 777-787.
    13. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    14. Ayoub, Muhammad & Abdullah, Ahmad Zuhairi, 2012. "Critical review on the current scenario and significance of crude glycerol resulting from biodiesel industry towards more sustainable renewable energy industry," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2671-2686.
    15. Lešnik, Luka & Vajda, Blaž & Žunič, Zoran & Škerget, Leopold & Kegl, Breda, 2013. "The influence of biodiesel fuel on injection characteristics, diesel engine performance, and emission formation," Applied Energy, Elsevier, vol. 111(C), pages 558-570.
    16. Rajasekar, E. & Selvi, S., 2014. "Review of combustion characteristics of CI engines fueled with biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 390-399.
    17. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    18. de Lucena, André Frossard Pereira & Szklo, Alexandre Salem & Schaeffer, Roberto & de Souza, Raquel Rodrigues & Borba, Bruno Soares Moreira Cesar & da Costa, Isabella Vaz Leal & Júnior, Amaro Olimpio P, 2009. "The vulnerability of renewable energy to climate change in Brazil," Energy Policy, Elsevier, vol. 37(3), pages 879-889, March.
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