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Torrefaction pretreatment of lignocellulosic biomass for sustainable solid biofuel production

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  • Ivanovski, Maja
  • Goricanec, Darko
  • Krope, Jurij
  • Urbancl, Danijela

Abstract

Torrefaction can upgrade the properties of biomass by reducing its oxygen content. In this study, the effects of torrefaction pretreatment on four different lignocellulosic biomass materials at three different temperatures (200 °C, 250 °C, and 300 °C) were studied using a Bosio EUP 6/1200 electric furnace. The results of proximate and ultimate analyses showed that the oxygen content is reduced with a higher torrefaction temperature, while the heating values increased, with 260 °C being the optimal temperature for the process. Among the torrefied products, oak waste wood (OWW, torrefied at 200 °C) had the highest solid yield, 93.2%, while the energy yield was 95.7%, fixed carbon (FC) content 11.8%, volatile matter (VM) content 80.9%, ash content 0.8%, and HHV 19.1 MJ/kg. The TGA/DTG experiments confirmed typical thermal properties for all lignocellulosic biomaterials, while the FTIR and XRD patterns for miscanthus and OWW indicate that the molecular chains of cellulose are broken (damaged) at temperatures higher than 300 °C. Porous ovals were observed at all temperatures in all biomass materials using SEM. SEM images showed that at higher temperatures the ovals started to crack, leading to materials with better grindability than the raw materials. Therefore, we conclude that solid biofuels with properties similar to coal can be produced with torrefaction.

Suggested Citation

  • Ivanovski, Maja & Goricanec, Darko & Krope, Jurij & Urbancl, Danijela, 2022. "Torrefaction pretreatment of lignocellulosic biomass for sustainable solid biofuel production," Energy, Elsevier, vol. 240(C).
    • Handle: RePEc:eee:energy:v:240:y:2022:i:c:s0360544221027328
    DOI: 10.1016/j.energy.2021.122483
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    References listed on IDEAS

    as
    1. Park, Sunyong & Kim, Seok Jun & Oh, Kwang Cheol & Cho, Lahoon & Kim, Min Jun & Jeong, In Seon & Lee, Chung Geon & Kim, DaeHyun, 2020. "Investigation of agro-byproduct pellet properties and improvement in pellet quality through mixing," Energy, Elsevier, vol. 190(C).
    2. Bach, Quang-Vu & Skreiberg, Øyvind & Lee, Chul-Jin, 2017. "Process modeling and optimization for torrefaction of forest residues," Energy, Elsevier, vol. 138(C), pages 348-354.
    3. Tymoszuk, Mateusz & Mroczek, Kazimierz & Kalisz, Sylwester & Kubiczek, Henryk, 2019. "An investigation of biomass grindability," Energy, Elsevier, vol. 183(C), pages 116-126.
    4. Gan, Yong Yang & Ong, Hwai Chyuan & Ling, Tau Chuan & Chen, Wei-Hsin & Chong, Cheng Tung, 2019. "Torrefaction of de-oiled Jatropha seed kernel biomass for solid fuel production," Energy, Elsevier, vol. 170(C), pages 367-374.
    5. Wilk, Małgorzata & Magdziarz, Aneta, 2017. "Hydrothermal carbonization, torrefaction and slow pyrolysis of Miscanthus giganteus," Energy, Elsevier, vol. 140(P1), pages 1292-1304.
    6. Wang, L. & Barta-Rajnai, E. & Skreiberg, Ø. & Khalil, R. & Czégény, Z. & Jakab, E. & Barta, Z. & Grønli, M., 2018. "Effect of torrefaction on physiochemical characteristics and grindability of stem wood, stump and bark," Applied Energy, Elsevier, vol. 227(C), pages 137-148.
    7. Chen, Wei-Hsin & Lin, Bo-Jhih & Colin, Baptiste & Chang, Jo-Shu & Pétrissans, Anélie & Bi, Xiaotao & Pétrissans, Mathieu, 2018. "Hygroscopic transformation of woody biomass torrefaction for carbon storage," Applied Energy, Elsevier, vol. 231(C), pages 768-776.
    8. Jóźwiak, Piotr & Hercog, Jarosław & Kiedrzyńska, Aleksandra & Badyda, Krzysztof, 2019. "CFD analysis of natural gas substitution with syngas in the industrial furnaces," Energy, Elsevier, vol. 179(C), pages 593-602.
    9. Rodriguez Alonso, Elvira & Dupont, Capucine & Heux, Laurent & Da Silva Perez, Denilson & Commandre, Jean-Michel & Gourdon, Christophe, 2016. "Study of solid chemical evolution in torrefaction of different biomasses through solid-state 13C cross-polarization/magic angle spinning NMR (nuclear magnetic resonance) and TGA (thermogravimetric ana," Energy, Elsevier, vol. 97(C), pages 381-390.
    10. González Martínez, María & Dupont, Capucine & Anca-Couce, Andrés & da Silva Perez, Denilson & Boissonnet, Guillaume & Thiéry, Sébastien & Meyer, Xuân-mi & Gourdon, Christophe, 2020. "Understanding the torrefaction of woody and agricultural biomasses through their extracted macromolecular components. Part 2: Torrefaction model," Energy, Elsevier, vol. 210(C).
    11. Akbari, Maryam & Oyedun, Adetoyese Olajire & Kumar, Amit, 2020. "Techno-economic assessment of wet and dry torrefaction of biomass feedstock," Energy, Elsevier, vol. 207(C).
    12. González Martínez, María & Dupont, Capucine & da Silva Perez, Denilson & Mortha, Gérard & Thiéry, Sébastien & Meyer, Xuân-mi & Gourdon, Christophe, 2020. "Understanding the torrefaction of woody and agricultural biomasses through their extracted macromolecular components. Part 1: Experimental thermogravimetric solid mass loss," Energy, Elsevier, vol. 205(C).
    13. Singh, Rishikesh Kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2020. "Effect of torrefaction on the physicochemical properties of eucalyptus derived biofuels: estimation of kinetic parameters and optimizing torrefaction using response surface methodology (RSM)," Energy, Elsevier, vol. 198(C).
    14. Jorge Miguel Carneiro Ribeiro & Radu Godina & João Carlos de Oliveira Matias & Leonel Jorge Ribeiro Nunes, 2018. "Future Perspectives of Biomass Torrefaction: Review of the Current State-Of-The-Art and Research Development," Sustainability, MDPI, vol. 10(7), pages 1-17, July.
    15. Zhang, Zhiqing & Duan, Hanqi & Zhang, Youjun & Guo, Xiaojuan & Yu, Xi & Zhang, Xingguang & Rahman, Md. Maksudur & Cai, Junmeng, 2020. "Investigation of kinetic compensation effect in lignocellulosic biomass torrefaction: Kinetic and thermodynamic analyses," Energy, Elsevier, vol. 207(C).
    16. Ximei Li & Jianmin Gao & Yaning Zhang & Yu Zhang & Qian Du & Shaohua Wu & Yukun Qin, 2020. "Energy, Exergy and Economic Analyses of a Combined Heating and Power System with Turbine-Driving Fans and Pumps in Northeast China," Energies, MDPI, vol. 13(4), pages 1-22, February.
    17. Li, Yueh-Heng & Lin, Hsien-Tsung & Xiao, Kai-Lin & Lasek, Janusz, 2018. "Combustion behavior of coal pellets blended with Miscanthus biochar," Energy, Elsevier, vol. 163(C), pages 180-190.
    18. Xin, Shanzhi & Mi, Tie & Liu, Xiaoye & Huang, Fang, 2018. "Effect of torrefaction on the pyrolysis characteristics of high moisture herbaceous residues," Energy, Elsevier, vol. 152(C), pages 586-593.
    19. Duan, Hanqi & Zhang, Zhiqing & Rahman, Md Maksudur & Guo, Xiaojuan & Zhang, Xingguang & Cai, Junmeng, 2020. "Insight into torrefaction of woody biomass: Kinetic modeling using pattern search method," Energy, Elsevier, vol. 201(C).
    20. Director, L.B. & Sinelshchikov, V.A., 2019. "Numerical modeling of torrefaction reactor integrated in energy technological complex," Energy, Elsevier, vol. 167(C), pages 1194-1204.
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