IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v198y2020ics036054422030476x.html
   My bibliography  Save this article

Effect of torrefaction on the physicochemical properties of eucalyptus derived biofuels: estimation of kinetic parameters and optimizing torrefaction using response surface methodology (RSM)

Author

Listed:
  • Singh, Rishikesh Kumar
  • Sarkar, Arnab
  • Chakraborty, Jyoti Prasad

Abstract

Torrefaction of eucalyptus has been carried out in a tubular quartz reactor at different temperatures and residence time under the nitrogen atmosphere. Based on statistical analysis, temperature and residence time both have negative and positive effects on solid yield and HHV, respectively. The temperature had a more severe impact on physicochemical properties as compared to residence time. Based on maximum HHV, the optimum condition has been obtained near 280 °C and 60 min of residence time. Both O/C and H/C ratios have decreased with increasing temperature. There has been an increase of 37.1 and 12.9% in HHV and energy density, respectively, for TEC-280-60 as compared to REC. The decrease in value of CCI and HR with severity resulted in lesser compactability and better flowability, respectively. There have been 433.3% increase and 76.2% decrease in fuel ratio and combustibility index, respectively, for TEC-280-60 as compared to REC. Torrefied biomass, as compared to raw biomass, showed better solid fuel properties for co-combustion with coal. Kinetic parameters revealed that overall activation energy decreased from 179.1 to 81.7 kJ/mol for TEC-280-40 as compared to REC. There has been a decrease in thermal stability of lignin with an increase in severity.

Suggested Citation

  • Singh, Rishikesh Kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2020. "Effect of torrefaction on the physicochemical properties of eucalyptus derived biofuels: estimation of kinetic parameters and optimizing torrefaction using response surface methodology (RSM)," Energy, Elsevier, vol. 198(C).
    • Handle: RePEc:eee:energy:v:198:y:2020:i:c:s036054422030476x
    DOI: 10.1016/j.energy.2020.117369
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054422030476X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2020.117369?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Martín-Lara, M.A. & Blázquez, G. & Ronda, A. & Calero, M., 2016. "Kinetic study of the pyrolysis of pine cone shell through non-isothermal thermogravimetry: Effect of heavy metals incorporated by biosorption," Renewable Energy, Elsevier, vol. 96(PA), pages 613-624.
    2. Álvarez, Ana & Nogueiro, Dositeo & Pizarro, Consuelo & Matos, María & Bueno, Julio L., 2018. "Non-oxidative torrefaction of biomass to enhance its fuel properties," Energy, Elsevier, vol. 158(C), pages 1-8.
    3. Zhang, Congyu & Ho, Shih-Hsin & Chen, Wei-Hsin & Xie, Youping & Liu, Zhenquan & Chang, Jo-Shu, 2018. "Torrefaction performance and energy usage of biomass wastes and their correlations with torrefaction severity index," Applied Energy, Elsevier, vol. 220(C), pages 598-604.
    4. Jack P. C. Kleijnen, 2015. "Response Surface Methodology," International Series in Operations Research & Management Science, in: Michael C Fu (ed.), Handbook of Simulation Optimization, edition 127, chapter 0, pages 81-104, Springer.
    5. Niu, Yanqing & Lv, Yuan & Lei, Yu & Liu, Siqi & Liang, Yang & Wang, Denghui & Hui, Shi'en, 2019. "Biomass torrefaction: properties, applications, challenges, and economy," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
    6. Parkhurst, Kristen M. & Saffron, Christopher M. & Miller, Raymond O., 2016. "An energy analysis comparing biomass torrefaction in depots to wind with natural gas combustion for electricity generation," Applied Energy, Elsevier, vol. 179(C), pages 171-181.
    7. Nam, Hyungseok & Capareda, Sergio, 2015. "Experimental investigation of torrefaction of two agricultural wastes of different composition using RSM (response surface methodology)," Energy, Elsevier, vol. 91(C), pages 507-516.
    8. Gupta, Goutam Kishore & Mondal, Monoj Kumar, 2019. "Bio-energy generation from sagwan sawdust via pyrolysis: Product distributions, characterizations and optimization using response surface methodology," Energy, Elsevier, vol. 170(C), pages 423-437.
    9. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Torrefaction and co-torrefaction characterization of hemicellulose, cellulose and lignin as well as torrefaction of some basic constituents in biomass," Energy, Elsevier, vol. 36(2), pages 803-811.
    10. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2006. "More efficient biomass gasification via torrefaction," Energy, Elsevier, vol. 31(15), pages 3458-3470.
    11. Chen, Wei-Hsin & Cheng, Wen-Yi & Lu, Ke-Miao & Huang, Ying-Pin, 2011. "An evaluation on improvement of pulverized biomass property for solid fuel through torrefaction," Applied Energy, Elsevier, vol. 88(11), pages 3636-3644.
    12. Singh, Rishikesh kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2019. "Effect of torrefaction on the physicochemical properties of pigeon pea stalk (Cajanus cajan) and estimation of kinetic parameters," Renewable Energy, Elsevier, vol. 138(C), pages 805-819.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ma, Jiao & Feng, Shuo & Zhang, Zhikun & Wang, Zhuozhi & Kong, Wenwen & Yuan, Peng & Shen, Boxiong & Mu, Lan, 2022. "Effect of torrefaction pretreatment on the combustion characteristics of the biodried products derived from municipal organic wastes," Energy, Elsevier, vol. 239(PD).
    2. Silveira, Edgar A. & Macedo, Lucélia A. & Rousset, Patrick & Candelier, Kevin & Galvão, Luiz Gustavo O. & Chaves, Bruno S. & Commandré, Jean-Michel, 2022. "A potassium responsive numerical path to model catalytic torrefaction kinetics," Energy, Elsevier, vol. 239(PB).
    3. Cardarelli, Alessandro & Pinzi, Sara & Barbanera, Marco, 2022. "Effect of torrefaction temperature on spent coffee grounds thermal behaviour and kinetics," Renewable Energy, Elsevier, vol. 185(C), pages 704-716.
    4. Ivanovski, Maja & Goricanec, Darko & Krope, Jurij & Urbancl, Danijela, 2022. "Torrefaction pretreatment of lignocellulosic biomass for sustainable solid biofuel production," Energy, Elsevier, vol. 240(C).
    5. Lin, Yi-Li & Zheng, Nai-Yun & Lin, Ching-Shi, 2021. "Repurposing Washingtonia filifera petiole and Sterculia foetida follicle waste biomass for renewable energy through torrefaction," Energy, Elsevier, vol. 223(C).
    6. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    7. Sher, Farooq & Yaqoob, Aqsa & Saeed, Farrukh & Zhang, Shengfu & Jahan, Zaib & Klemeš, Jiří Jaromír, 2020. "Torrefied biomass fuels as a renewable alternative to coal in co-firing for power generation," Energy, Elsevier, vol. 209(C).
    8. Awais, Muhammad & Omar, Muhammad Mubashar & Munir, Anjum & li, Wei & Ajmal, Muhammad & Hussain, Sajjad & Ahmad, Syed Amjad & Ali, Amjad, 2022. "Co-gasification of different biomass feedstock in a pilot-scale (24 kWe) downdraft gasifier: An experimental approach," Energy, Elsevier, vol. 238(PB).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Singh, Rishikesh Kumar & Chakraborty, Jyoti Prasad & Sarkar, Arnab, 2020. "Optimizing the torrefaction of pigeon pea stalk (cajanus cajan) using response surface methodology (RSM) and characterization of solid, liquid and gaseous products," Renewable Energy, Elsevier, vol. 155(C), pages 677-690.
    2. Ong, Hwai Chyuan & Yu, Kai Ling & Chen, Wei-Hsin & Pillejera, Ma Katreena & Bi, Xiaotao & Tran, Khanh-Quang & Pétrissans, Anelie & Pétrissans, Mathieu, 2021. "Variation of lignocellulosic biomass structure from torrefaction: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    3. Abdulyekeen, Kabir Abogunde & Umar, Ahmad Abulfathi & Patah, Muhamad Fazly Abdul & Daud, Wan Mohd Ashri Wan, 2021. "Torrefaction of biomass: Production of enhanced solid biofuel from municipal solid waste and other types of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    4. Sukiran, Mohamad Azri & Wan Daud, Wan Mohd Ashri & Abnisa, Faisal & Nasrin, Abu Bakar & Abdul Aziz, Astimar & Loh, Soh Kheang, 2021. "A comprehensive study on torrefaction of empty fruit bunches: Characterization of solid, liquid and gas products," Energy, Elsevier, vol. 230(C).
    5. Chai, Meiyun & Xie, Li & Yu, Xi & Zhang, Xingguang & Yang, Yang & Rahman, Md. Maksudur & Blanco, Paula H. & Liu, Ronghou & Bridgwater, Anthony V. & Cai, Junmeng, 2021. "Poplar wood torrefaction: Kinetics, thermochemistry and implications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    6. Tran, Khanh-Quang & Luo, Xun & Seisenbaeva, Gulaim & Jirjis, Raida, 2013. "Stump torrefaction for bioenergy application," Applied Energy, Elsevier, vol. 112(C), pages 539-546.
    7. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    8. Niu, Qi & Ronsse, Frederik & Qi, Zhiyong & Zhang, Dongdong, 2022. "Fast torrefaction of large biomass particles by superheated steam: Enhanced solid products for multipurpose production," Renewable Energy, Elsevier, vol. 185(C), pages 552-563.
    9. Kartal, Furkan & Özveren, Uğur, 2022. "Prediction of torrefied biomass properties from raw biomass," Renewable Energy, Elsevier, vol. 182(C), pages 578-591.
    10. da Silva, Jean Constantino Gomes & Pereira, Jefferson Leque Claudio & Andersen, Silvia Layara Floriani & Moreira, Regina de Fatima Peralta Muniz & José, Humberto Jorge, 2020. "Torrefaction of ponkan peel waste in tubular fixed-bed reactor: In-depth bioenergetic evaluation of torrefaction products," Energy, Elsevier, vol. 210(C).
    11. Duan, Hanqi & Zhang, Zhiqing & Rahman, Md Maksudur & Guo, Xiaojuan & Zhang, Xingguang & Cai, Junmeng, 2020. "Insight into torrefaction of woody biomass: Kinetic modeling using pattern search method," Energy, Elsevier, vol. 201(C).
    12. Ma, Jiao & Feng, Shuo & Zhang, Zhikun & Wang, Zhuozhi & Kong, Wenwen & Yuan, Peng & Shen, Boxiong & Mu, Lan, 2022. "Effect of torrefaction pretreatment on the combustion characteristics of the biodried products derived from municipal organic wastes," Energy, Elsevier, vol. 239(PD).
    13. Wilk, Małgorzata & Magdziarz, Aneta & Kalemba, Izabela, 2015. "Characterisation of renewable fuels' torrefaction process with different instrumental techniques," Energy, Elsevier, vol. 87(C), pages 259-269.
    14. Maja Ivanovski & Aleksandra Petrovič & Darko Goričanec & Danijela Urbancl & Marjana Simonič, 2023. "Exploring the Properties of the Torrefaction Process and Its Prospective in Treating Lignocellulosic Material," Energies, MDPI, vol. 16(18), pages 1-20, September.
    15. Gan, Yong Yang & Ong, Hwai Chyuan & Ling, Tau Chuan & Chen, Wei-Hsin & Chong, Cheng Tung, 2019. "Torrefaction of de-oiled Jatropha seed kernel biomass for solid fuel production," Energy, Elsevier, vol. 170(C), pages 367-374.
    16. Dimitrios K. Sidiras & Antonios G. Nazos & Georgios E. Giakoumakis & Dorothea V. Politi, 2020. "Simulating the Effect of Torrefaction on the Heating Value of Barley Straw," Energies, MDPI, vol. 13(3), pages 1-15, February.
    17. Oh, Kwang Cheol & Park, Sun Young & Kim, Seok Jun & Choi, Yun Sung & Lee, Chung Geon & Cho, La Hoon & Kim, Dae Hyun, 2019. "Development and validation of mass reduction model to optimize torrefaction for agricultural byproduct biomass," Renewable Energy, Elsevier, vol. 139(C), pages 988-999.
    18. Arriola, Emmanuel & Chen, Wei-Hsin & Chih, Yi-Kai & De Luna, Mark Daniel & Show, Pau Loke, 2020. "Impact of post-torrefaction process on biochar formation from wood pellets and self-heating phenomena for production safety," Energy, Elsevier, vol. 207(C).
    19. Singh, Rishikesh kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2019. "Effect of torrefaction on the physicochemical properties of pigeon pea stalk (Cajanus cajan) and estimation of kinetic parameters," Renewable Energy, Elsevier, vol. 138(C), pages 805-819.
    20. Yek, Peter Nai Yuh & Cheng, Yoke Wang & Liew, Rock Keey & Wan Mahari, Wan Adibah & Ong, Hwai Chyuan & Chen, Wei-Hsin & Peng, Wanxi & Park, Young-Kwon & Sonne, Christian & Kong, Sieng Huat & Tabatabaei, 2021. "Progress in the torrefaction technology for upgrading oil palm wastes to energy-dense biochar: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:198:y:2020:i:c:s036054422030476x. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.