IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v231y2021ics0360544221012184.html
   My bibliography  Save this article

Green hydrogen coupling with CO2 utilization of coal-to-methanol for high methanol productivity and low CO2 emission

Author

Listed:
  • Dongliang, Wang
  • Wenliang, Meng
  • Huairong, Zhou
  • Guixian, Li
  • Yong, Yang
  • Hongwei, Li

Abstract

The conventional coal-to-methanol (CTM) process suffers from large CO2 emission. The additional hydrogen supplement to the CTM process can effectively improve the carbon utilization efficiency. However, the CO2 emission intensity and cost of existing hydrogen production technologies based on fossil resources are extremely high. This paper proposes a green hydrogen (GH) production integrated with CO2 utilization of the CTM process. The new process is called GH-CTM process, which can achieve intensive material coupling, improve carbon efficiency, and increase methanol productivity. Process modeling, parameters optimization, and simulation results showed that the energy efficiency, CO2 emission, and methanol output of the proposed process were 10.52% higher, 85.64% lower, and 124.67% higher than those of the conventional CTM process, respectively; moreover, the production cost of the proposed process was 23.95% lower than that of the CTM process, and the payback period of investment (2.8 years) was lower than that of the CTM process (7.2 years). In addition, the internal rate of return of the proposed process was increased by 47.37% compared with that of traditional CTM process. The proposed process provides a promising method for the introduction of green hydrogen to realize CO2 utilization and the sustainable conversion of coal to chemicals.

Suggested Citation

  • Dongliang, Wang & Wenliang, Meng & Huairong, Zhou & Guixian, Li & Yong, Yang & Hongwei, Li, 2021. "Green hydrogen coupling with CO2 utilization of coal-to-methanol for high methanol productivity and low CO2 emission," Energy, Elsevier, vol. 231(C).
    • Handle: RePEc:eee:energy:v:231:y:2021:i:c:s0360544221012184
    DOI: 10.1016/j.energy.2021.120970
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221012184
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.120970?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Anicic, B. & Trop, P. & Goricanec, D., 2014. "Comparison between two methods of methanol production from carbon dioxide," Energy, Elsevier, vol. 77(C), pages 279-289.
    2. Ana Gonçalves & Jaime Filipe Puna & Luís Guerra & José Campos Rodrigues & João Fernando Gomes & Maria Teresa Santos & Diogo Alves, 2019. "Towards the Development of Syngas/Biomethane Electrolytic Production, Using Liquefied Biomass and Heterogeneous Catalyst," Energies, MDPI, vol. 12(19), pages 1-21, October.
    3. Chen, Jianjun & Yang, Siyu & Qian, Yu, 2019. "A novel path for carbon-rich resource utilization with lower emission and higher efficiency: An integrated process of coal gasification and coking to methanol production," Energy, Elsevier, vol. 177(C), pages 304-318.
    4. Zhou, Huairong & Qian, Yu & Yang, Siyu, 2015. "Energetic/economic penalty of CO2 emissions and application to coal-to-olefins projects in China," Applied Energy, Elsevier, vol. 156(C), pages 344-353.
    5. Yang, Siyu & Yang, Qingchun & Qian, Yu, 2013. "A composite efficiency metrics for evaluation of resource and energy utilization," Energy, Elsevier, vol. 61(C), pages 455-462.
    6. Martín, Mariano & Grossmann, Ignacio E., 2018. "Optimal integration of renewable based processes for fuels and power production: Spain case study," Applied Energy, Elsevier, vol. 213(C), pages 595-610.
    7. Chen, QianQian & Tang, ZhiYong & Lei, Yang & Sun, YuHan & Jiang, MianHeng, 2015. "Feasibility analysis of nuclear–coal hybrid energy systems from the perspective of low-carbon development," Applied Energy, Elsevier, vol. 158(C), pages 619-630.
    8. Qin, Shiyue & Chang, Shiyan & Yao, Qiang, 2018. "Modeling, thermodynamic and techno-economic analysis of coal-to-liquids process with different entrained flow coal gasifiers," Applied Energy, Elsevier, vol. 229(C), pages 413-432.
    9. Xiang, Dong & Qian, Yu & Man, Yi & Yang, Siyu, 2014. "Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process," Applied Energy, Elsevier, vol. 113(C), pages 639-647.
    10. Yang, Qingchun & Zhang, Dawei & Zhou, Huairong & Zhang, Chenwei, 2018. "Process simulation, analysis and optimization of a coal to ethylene glycol process," Energy, Elsevier, vol. 155(C), pages 521-534.
    11. Zhang, Dongqiang & Duan, Runhao & Li, Hongwei & Yang, Qingchun & Zhou, Huairong, 2020. "Optimal design, thermodynamic, cost and CO2 emission analyses of coal-to-methanol process integrated with chemical looping air separation and hydrogen technology," Energy, Elsevier, vol. 203(C).
    12. Liu, Guang-jian & Li, Zheng & Wang, Ming-hua & Ni, Wei-dou, 2010. "Energy savings by co-production: A methanol/electricity case study," Applied Energy, Elsevier, vol. 87(9), pages 2854-2859, September.
    13. Zhou, Huairong & Yang, Siyu & Xiao, Honghua & Yang, Qingchun & Qian, Yu & Gao, Li, 2016. "Modeling and techno-economic analysis of shale-to-liquid and coal-to-liquid fuels processes," Energy, Elsevier, vol. 109(C), pages 201-210.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Huang, Yue & Zhu, Lin & He, Yangdong & Wang, Yuan & Hao, Qiang & Zhu, Yifei, 2023. "Carbon dioxide utilization based on exergoenvironmental sustainability assessment: A case study of CO2 hydrogenation to methanol," Energy, Elsevier, vol. 273(C).
    2. Hou, Rui & Zhang, Nachuan & Yang, Chengsheng & Zhao, Jing & Li, Peng & Sun, Bo, 2023. "A novel structure of natural gas, electricity, and methanol production using a combined reforming cycle: Integration of biogas upgrading, liquefied natural gas re-gasification, power plant, and methan," Energy, Elsevier, vol. 270(C).
    3. Anetjärvi, Eemeli & Vakkilainen, Esa & Melin, Kristian, 2023. "Benefits of hybrid production of e-methanol in connection with biomass gasification," Energy, Elsevier, vol. 276(C).
    4. Wang, Danfeng & Gu, Yu & Chen, Qianqian & Tang, Zhiyong, 2023. "Direct conversion of syngas to alpha olefins via Fischer–Tropsch synthesis: Process development and comparative techno-economic-environmental analysis," Energy, Elsevier, vol. 263(PE).
    5. Tabibian, Seyed Shayan & Sharifzadeh, Mahdi, 2023. "Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).
    6. Samanta, Samiran & Roy, Dibyendu & Roy, Sumit & Smallbone, Andrew & Roskilly, Anthony Paul, 2023. "Techno-economic analysis of a fuel-cell driven integrated energy hub for decarbonising transportation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).
    7. Christiano B. Peres & Pedro M. R. Resende & Leonel J. R. Nunes & Leandro C. de Morais, 2022. "Advances in Carbon Capture and Use (CCU) Technologies: A Comprehensive Review and CO 2 Mitigation Potential Analysis," Clean Technol., MDPI, vol. 4(4), pages 1-15, November.
    8. Galusnyak, Stefan Cristian & Petrescu, Letitia & Chisalita, Dora Andreea & Cormos, Calin-Cristian, 2022. "Life cycle assessment of methanol production and conversion into various chemical intermediates and products," Energy, Elsevier, vol. 259(C).
    9. Safder, Usman & Loy-Benitez, Jorge & Yoo, ChangKyoo, 2024. "Techno-economic assessment of a novel integrated multigeneration system to synthesize e-methanol and green hydrogen in a carbon-neutral context," Energy, Elsevier, vol. 290(C).
    10. Gu, Hongfei & Liu, Jianzi & Zhou, Xingchen & Wu, Qiwei & Liu, Yaodong & Yu, Shuaixian & Qiu, Wenying & Xu, Jianguo, 2023. "Modelling of a novel electricity and methanol co-generation using heat recovery and CO2 capture: Comprehensive thermodynamic, economic, and environmental analyses," Energy, Elsevier, vol. 278(C).
    11. Wan, Zhanghao & Yang, Shiliang & Hu, Jianhang & Wang, Hua, 2023. "Catalyst-scale investigation of polydispersity effect on thermophysical properties in a commercial-scale catalytic MTO fluidized bed reactor," Energy, Elsevier, vol. 262(PA).
    12. Wang, Yuting & Chen, Heng & Qiao, Shichao & Pan, Peiyuan & Xu, Gang & Dong, Yuehong & Jiang, Xue, 2023. "A novel methanol-electricity cogeneration system based on the integration of water electrolysis and plasma waste gasification," Energy, Elsevier, vol. 267(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yang, Qingchun & Yang, Qing & Xu, Simin & Zhang, Dawei & Liu, Chengling & Zhou, Huairong, 2021. "Optimal design, exergy and economic analyses of coal-to-ethylene glycol process coupling different shale gas reforming technologies," Energy, Elsevier, vol. 228(C).
    2. Zhang, Dongqiang & Duan, Runhao & Li, Hongwei & Yang, Qingchun & Zhou, Huairong, 2020. "Optimal design, thermodynamic, cost and CO2 emission analyses of coal-to-methanol process integrated with chemical looping air separation and hydrogen technology," Energy, Elsevier, vol. 203(C).
    3. Siddig S. Khalafalla & Umer Zahid & Abdul Gani Abdul Jameel & Usama Ahmed & Feraih S. Alenazey & Chul-Jin Lee, 2020. "Conceptual Design Development of Coal-to-Methanol Process with Carbon Capture and Utilization," Energies, MDPI, vol. 13(23), pages 1-21, December.
    4. Wolfersdorf, Christian & Boblenz, Kristin & Pardemann, Robert & Meyer, Bernd, 2015. "Syngas-based annex concepts for chemical energy storage and improving flexibility of pulverized coal combustion power plants," Applied Energy, Elsevier, vol. 156(C), pages 618-627.
    5. Kapsalyamova, Zhanna & Paltsev, Sergey, 2020. "Use of natural gas and oil as a source of feedstocks," Energy Economics, Elsevier, vol. 92(C).
    6. Ye, Liping & Xie, Fei & Hong, Jinglan & Yang, Donglu & Ma, Xiaotian & Li, Xiangzhi, 2018. "Environmental burden mitigation potential of oil field gas-assisted coal-to-olefin production," Energy, Elsevier, vol. 157(C), pages 1015-1024.
    7. Jiang, Peng & Parvez, Ashak Mahmud & Meng, Yang & Xu, Meng-xia & Shui, Tian-chi & Sun, Cheng-gong & Wu, Tao, 2019. "Exergetic, economic and carbon emission studies of bio-olefin production via indirect steam gasification process," Energy, Elsevier, vol. 187(C).
    8. Li, Junjie, 2024. "Spatialized carbon-energy-water footprint of emerging coal chemical industry in China," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    9. Rahmad Syah & Afshin Davarpanah & Marischa Elveny & Amir Ghasemi & Dadan Ramdan, 2021. "The Economic Evaluation of Methanol and Propylene Production from Natural Gas at Petrochemical Industries in Iran," Sustainability, MDPI, vol. 13(17), pages 1-23, September.
    10. Liu, Huan & Guo, Wei & Liu, Shuqin, 2022. "Comparative techno-economic performance analysis of underground coal gasification and surface coal gasification based coal-to-hydrogen process," Energy, Elsevier, vol. 258(C).
    11. Zhou, Huairong & Li, Hongwei & Duan, Runhao & Yang, Qingchun, 2020. "An integrated scheme of coal-assisted oil shale efficient pyrolysis and high-value conversion of pyrolysis oil," Energy, Elsevier, vol. 196(C).
    12. Safder, Usman & Loy-Benitez, Jorge & Yoo, ChangKyoo, 2024. "Techno-economic assessment of a novel integrated multigeneration system to synthesize e-methanol and green hydrogen in a carbon-neutral context," Energy, Elsevier, vol. 290(C).
    13. Tabibian, Seyed Shayan & Sharifzadeh, Mahdi, 2023. "Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).
    14. Ding, Bingqing & Makowski, Marek & Nahorski, Zbigniew & Ren, Hongtao & Ma, Tieju, 2022. "Optimizing the technology pathway of China's liquid fuel production considering uncertain oil prices: A robust programming model," Energy Economics, Elsevier, vol. 115(C).
    15. Gu, Hongfei & Liu, Jianzi & Zhou, Xingchen & Wu, Qiwei & Liu, Yaodong & Yu, Shuaixian & Qiu, Wenying & Xu, Jianguo, 2023. "Modelling of a novel electricity and methanol co-generation using heat recovery and CO2 capture: Comprehensive thermodynamic, economic, and environmental analyses," Energy, Elsevier, vol. 278(C).
    16. Qin, Shiyue & Wang, Ming & Cui, Hongyou & Li, Zhihe & Yi, Weiming, 2022. "Opportunities for renewable electricity utilization in coal to liquid fuels process: Thermodynamic and techo-economic analysis," Energy, Elsevier, vol. 239(PA).
    17. Zhang, Yueling & Li, Junjie & Yang, Xiaoxiao, 2021. "Comprehensive competitiveness assessment of four coal-to-liquid routes and conventional oil refining route in China," Energy, Elsevier, vol. 235(C).
    18. Huo, Hailong & Liu, Xunliang & Wen, Zhi & Lou, Guofeng & Dou, Ruifeng & Su, Fuyong & Zhou, Wenning & Jiang, Zeyi, 2021. "Case study of a novel low rank coal to calcium carbide process based on techno-economic assessment," Energy, Elsevier, vol. 228(C).
    19. Zhou, Huairong & Qian, Yu & Kraslawski, Andrzej & Yang, Qingchun & Yang, Siyu, 2017. "Life-cycle assessment of alternative liquid fuels production in China," Energy, Elsevier, vol. 139(C), pages 507-522.
    20. Farias Neto, G.W. & Leite, M.B.M. & Marcelino, T.O.A.C. & Carneiro, L.O. & Brito, K.D. & Brito, R.P., 2021. "Optimizing the coke oven process by adjusting the temperature of the combustion chambers," Energy, Elsevier, vol. 217(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:231:y:2021:i:c:s0360544221012184. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.