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Conceptual Design Development of Coal-to-Methanol Process with Carbon Capture and Utilization

Author

Listed:
  • Siddig S. Khalafalla

    (Chemical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia)

  • Umer Zahid

    (Chemical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia)

  • Abdul Gani Abdul Jameel

    (Chemical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia)

  • Usama Ahmed

    (Chemical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia)

  • Feraih S. Alenazey

    (King Abdulaziz City for Science and Technology (KACST), Riyadh 11442, Saudi Arabia)

  • Chul-Jin Lee

    (School of Chemical Engineering and Materials Science, Chung-Ang University, 84 Heukseok-ro, Dongjak-gu, Seoul 06974, Korea)

Abstract

Methanol is a clean fuel and an important feedstock for the petrochemical industry. Conventionally, the coal-to-methanol process generates a substantial amount of CO 2 emissions with a low yield of methanol. In this study, we propose the conceptual design development of coal-to-methanol process using captured CO 2 from the gasification plant by implying process intensification. The base case and three alternative designs have been developed using the Aspen Plus to analyze the process performance. The four designs have been compared in terms of their energy consumption, economics, methanol production rate, and carbon emissions while maintaining the gasifier operation conditions, sulfur content in the syngas, and stoichiometric number at the methanol synthesis reactor. Among the developed designs, the most feasible design requires an energy requirement and product cost of 21.9 GJ and $142.5 per ton of methanol product. The study also showed that the coal-to-methanol process assisted with external hydrogen from electrolysis plant for achieving higher production rates and low CO 2 emissions is currently not economical due to the high H 2 cost.

Suggested Citation

  • Siddig S. Khalafalla & Umer Zahid & Abdul Gani Abdul Jameel & Usama Ahmed & Feraih S. Alenazey & Chul-Jin Lee, 2020. "Conceptual Design Development of Coal-to-Methanol Process with Carbon Capture and Utilization," Energies, MDPI, vol. 13(23), pages 1-21, December.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:23:p:6421-:d:457012
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    References listed on IDEAS

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    1. Chen, Jianjun & Yang, Siyu & Qian, Yu, 2019. "A novel path for carbon-rich resource utilization with lower emission and higher efficiency: An integrated process of coal gasification and coking to methanol production," Energy, Elsevier, vol. 177(C), pages 304-318.
    2. Mike Hulme, 2020. "Is it too late (to stop dangerous climate change)? An editorial," Wiley Interdisciplinary Reviews: Climate Change, John Wiley & Sons, vol. 11(1), January.
    3. Ye, Chao & Wang, Qinhui & Zheng, Youqu & Li, Guoneng & Zhang, Zhiguo & Luo, Zhongyang, 2019. "Techno-economic analysis of methanol and electricity poly-generation system based on coal partial gasification," Energy, Elsevier, vol. 185(C), pages 624-632.
    4. Zhang, Dongqiang & Duan, Runhao & Li, Hongwei & Yang, Qingchun & Zhou, Huairong, 2020. "Optimal design, thermodynamic, cost and CO2 emission analyses of coal-to-methanol process integrated with chemical looping air separation and hydrogen technology," Energy, Elsevier, vol. 203(C).
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    2. Yusra Muazzam & Muhammad Yousaf & Muhammad Zaman & Ali Elkamel & Asif Mahmood & Muhammad Rizwan & Muhammad Adnan, 2022. "Thermo-Economic Analysis of Integrated Hydrogen, Methanol and Dimethyl Ether Production Using Water Electrolyzed Hydrogen," Resources, MDPI, vol. 11(10), pages 1-27, September.
    3. Tabibian, Seyed Shayan & Sharifzadeh, Mahdi, 2023. "Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).
    4. Hosseinzadeh-Bandbafha, Homa & Tan, Yie Hua & Kansedo, Jibrail & Mubarak, N.M. & Liew, Rock Keey & Yek, Peter Nai Yuh & Aghbashlo, Mortaza & Ng, Hui Suan & Chong, William Woei Fong & Lam, Su Shiung & , 2023. "Assessing biodiesel production using palm kernel shell-derived sulfonated magnetic biochar from the life cycle assessment perspective," Energy, Elsevier, vol. 282(C).
    5. Fayez Nasir Al-Rowaili & Siddig S. Khalafalla & Aqil Jamal & Dhaffer S. Al-Yami & Umer Zahid & Eid M. Al-Mutairi, 2021. "Techno-Economic Evaluation of Hydrogen Production via Gasification of Vacuum Residue Integrated with Dry Methane Reforming," Sustainability, MDPI, vol. 13(24), pages 1-11, December.

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