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A fast-heat battery system using the heat released from detonated supercooled phase change materials

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  • Ling, Ziye
  • Luo, Mingyun
  • Song, Jiaqi
  • Zhang, Wenbo
  • Zhang, Zhengguo
  • Fang, Xiaoming

Abstract

A heating strategy has been developed for the battery operated at low temperature, which can intelligently control the thermal storage and release of an inorganic phase change material (PCM): CaCl2·6H2O - carboxymethyl cellulose (CMC). With the 0.5 wt % CMC content, this PCM (melts at 25–30 °C) becomes stable in the subcooled state, making it possible to be used as the subcooled liquid at 5 °C to store the heat generated by the battery. The thermal energy stored in the subcooled PCM can be detonated to release by triggering the PCM to crystalize with a special device. The instant crystallization of this subcooled PCM heats the battery rapidly-which is at a rate up to 7.5 °C/min, higher than the battery without PCM (0.8 °C/min) or the battery with the no subcooled PCM(0.4 °C/min). The discharge capacity and power can be improved by 9.87% and 7.56%. This work presents a new method of heating by switching the subcooling of PCM on/off, which extends the application of PCMs to battery heating under low temperatures. This energy-free but efficient method could provide a better alternative to most active heating systems.

Suggested Citation

  • Ling, Ziye & Luo, Mingyun & Song, Jiaqi & Zhang, Wenbo & Zhang, Zhengguo & Fang, Xiaoming, 2021. "A fast-heat battery system using the heat released from detonated supercooled phase change materials," Energy, Elsevier, vol. 219(C).
    • Handle: RePEc:eee:energy:v:219:y:2021:i:c:s0360544220326037
    DOI: 10.1016/j.energy.2020.119496
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    References listed on IDEAS

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    Cited by:

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    2. Huang, Deyang & Chen, Ziqiang & Zhou, Shiyao, 2022. "Self-powered heating strategy for lithium-ion battery pack applied in extremely cold climates," Energy, Elsevier, vol. 239(PB).
    3. Lu, Fenglian & Chen, Weiye & Hu, Shuzhi & Chen, Lei & Sharshir, Swellam W. & Dong, Chuanshuai & Zhang, Lizhi, 2024. "Achieving a smart thermal management for lithium-ion batteries by electrically-controlled crystallization of supercooled calcium chloride hexahydrate solution," Applied Energy, Elsevier, vol. 364(C).
    4. Turunen, Konsta & Mikkola, Valtteri & Laukkanen, Timo & Seppälä, Ari, 2023. "Long-term thermal energy storage prototype of cold-crystallizing erythritol-polyelectrolyte," Applied Energy, Elsevier, vol. 332(C).
    5. Weng, Jingwen & Xiao, Changren & Ouyang, Dongxu & Yang, Xiaoqing & Chen, Mingyi & Zhang, Guoqing & Yuen, Richard Kwok Kit & Wang, Jian, 2022. "Mitigation effects on thermal runaway propagation of structure-enhanced phase change material modules with flame retardant additives," Energy, Elsevier, vol. 239(PC).

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