IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i11p4333-d1156006.html
   My bibliography  Save this article

Influence of Nickel Loading and the Synthesis Method on the Efficiency of Ni/TiO 2 Catalysts for Renewable Diesel Production

Author

Listed:
  • George Petropoulos

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece)

  • John Zafeiropoulos

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece)

  • Eleana Kordouli

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece
    Department of Chemistry, University of Patras, 26504 Patras, Greece)

  • Alexis Lycourghiotis

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece
    Department of Chemistry, University of Patras, 26504 Patras, Greece)

  • Christos Kordulis

    (Department of Chemistry, University of Patras, 26504 Patras, Greece
    Foundation of Research and Technology, Institute of Chemical Engineering Science (FORTH/ICE-HT) Stadiou Str. Platani, 26500 Patras, Greece)

  • Kyriakos Bourikas

    (School of Science and Technology, Hellenic Open University, Parodos Aristotelous 18, 26335 Patras, Greece)

Abstract

The efficiency of Ni/TiO 2 catalysts for renewable diesel production was evaluated in the present study. Two series of catalysts were synthesized and characterized using various physicochemical techniques (N 2 physisorption, XRD, SEM, XPS, H 2 -TPR, and NH 3 –TPD). In the first series of catalysts, successive dry impregnations (SDI) were used for depositing 10, 20, 30, 50, and 60 wt.% Ni. The yield towards renewable diesel is maximized over the catalyst with 50 wt.% Ni loading. Selecting this optimum loading, a second series of catalysts were synthesized via three additional preparation methods: wet impregnation (WI) and deposition–precipitation using either ammonia (DP-NH 3 ) or urea (DP-Urea) as the precipitation agent. The catalysts’ efficiency in the production of green diesel is influenced by the preparation method following the order: DP-Urea > DP-NH 3 > WI ≈ SDI. The metallic surface area and the balanced acidity mainly determine the performance of the catalysts.

Suggested Citation

  • George Petropoulos & John Zafeiropoulos & Eleana Kordouli & Alexis Lycourghiotis & Christos Kordulis & Kyriakos Bourikas, 2023. "Influence of Nickel Loading and the Synthesis Method on the Efficiency of Ni/TiO 2 Catalysts for Renewable Diesel Production," Energies, MDPI, vol. 16(11), pages 1-15, May.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:11:p:4333-:d:1156006
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/11/4333/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/11/4333/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    2. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    3. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    4. Glisic, Sandra B. & Pajnik, Jelena M. & Orlović, Aleksandar M., 2016. "Process and techno-economic analysis of green diesel production from waste vegetable oil and the comparison with ester type biodiesel production," Applied Energy, Elsevier, vol. 170(C), pages 176-185.
    5. José Rodríguez-Fernández & Juan José Hernández & Alejandro Calle-Asensio & Ángel Ramos & Javier Barba, 2019. "Selection of Blends of Diesel Fuel and Advanced Biofuels Based on Their Physical and Thermochemical Properties," Energies, MDPI, vol. 12(11), pages 1-13, May.
    6. Mantha Gousi & Eleana Kordouli & Kyriakos Bourikas & Emmanouil Symianakis & Spyros Ladas & Christos Kordulis & Alexis Lycourghiotis, 2020. "Green Diesel Production over Nickel-Alumina Nanostructured Catalysts Promoted by Copper," Energies, MDPI, vol. 13(14), pages 1-17, July.
    7. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    2. Tsiotsias, Anastasios I. & Hafeez, Sanaa & Charisiou, Nikolaos D. & Al-Salem, Sultan M. & Manos, George & Constantinou, Achilleas & AlKhoori, Sara & Sebastian, Victor & Hinder, Steven J. & Baker, Mark, 2023. "Selective catalytic deoxygenation of palm oil to produce green diesel over Ni catalysts supported on ZrO2 and CeO2–ZrO2: Experimental and process simulation modelling studies," Renewable Energy, Elsevier, vol. 206(C), pages 582-596.
    3. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    4. Wu, Wei & Supankanok, Rasa & Chandra-Ambhorn, Walairat & Taipabu, Muhammad Ikhsan, 2023. "Novel CO2-negative design of palm oil-based polygeneration systems," Renewable Energy, Elsevier, vol. 203(C), pages 622-633.
    5. Abul Kalam Azad & Abhijaysinh Chandrasinh Jadeja & Arun Teja Doppalapudi & Nur Md Sayeed Hassan & Md Nurun Nabi & Roshan Rauniyar, 2024. "Design and Simulation of the Biodiesel Process Plant for Sustainable Fuel Production," Sustainability, MDPI, vol. 16(8), pages 1-17, April.
    6. Piotr Łagowski & Grzegorz Wcisło & Dariusz Kurczyński, 2022. "Comparison of the Combustion Process Parameters in a Diesel Engine Powered by Second-Generation Biodiesel Compared to the First-Generation Biodiesel," Energies, MDPI, vol. 15(18), pages 1-21, September.
    7. Jacek Wasilewski & Grzegorz Zając & Joanna Szyszlak-Bargłowicz & Andrzej Kuranc, 2022. "Evaluation of Greenhouse Gas Emission Levels during the Combustion of Selected Types of Agricultural Biomass," Energies, MDPI, vol. 15(19), pages 1-14, October.
    8. Saifuddin Nomanbhay & Mei Yin Ong & Kit Wayne Chew & Pau-Loke Show & Man Kee Lam & Wei-Hsin Chen, 2020. "Organic Carbonate Production Utilizing Crude Glycerol Derived as By-Product of Biodiesel Production: A Review," Energies, MDPI, vol. 13(6), pages 1-23, March.
    9. Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.
    10. Anderson Breno Souza & Alvaro Antonio Villa Ochoa & José Ângelo Peixoto da Costa & Gustavo de Novaes Pires Leite & Héber Claudius Nunes Silva & Andrezza Carolina Carneiro Tómas & David Campos Barbosa , 2023. "A Review of Tropical Organic Materials for Biodiesel as a Substitute Energy Source in Internal Combustion Engines: A Viable Solution?," Energies, MDPI, vol. 16(9), pages 1-25, April.
    11. Nils Kretzschmar & Markus Seifert & Oliver Busse & Jan J. Weigand, 2022. "Prediction of Retention Indices and Response Factors of Oxygenates for GC-FID by Multilinear Regression," Data, MDPI, vol. 7(9), pages 1-12, September.
    12. Wilhelm Jan Tic & Joanna Guziałowska-Tic, 2023. "A System of Improving Energy and Ecological Efficiency, Using the Example of Fuel Oil Combustion in Power Plant Boilers," Energies, MDPI, vol. 16(3), pages 1-15, January.
    13. Hongshen Li & Hongrui Liu & Yufang Li & Jilin Nan & Chen Shi & Shizhong Li, 2021. "Combined Vapor Permeation and Continuous Solid-State Distillation for Energy-Efficient Bioethanol Production," Energies, MDPI, vol. 14(8), pages 1-15, April.
    14. Janbarari, Seyed Reza & Ahmadian Behrooz, Hesam, 2020. "Optimal and robust synthesis of the biodiesel production process using waste cooking oil from different feedstocks," Energy, Elsevier, vol. 198(C).
    15. Jakub Čedík & Martin Pexa & Michal Holúbek & Zdeněk Aleš & Radek Pražan & Peter Kuchar, 2020. "Effect of Diesel Fuel-Coconut Oil-Butanol Blends on Operational Parameters of Diesel Engine," Energies, MDPI, vol. 13(15), pages 1-16, July.
    16. Savvas L. Douvartzides & Aristidis Tsiolikas & Nikolaos D. Charisiou & Manolis Souliotis & Vayos Karayannis & Nikolaos Taousanidis, 2022. "Energy and Exergy-Based Screening of Various Refrigerants, Hydrocarbons and Siloxanes for the Optimization of Biomass Boiler–Organic Rankine Cycle (BB–ORC) Heat and Power Cogeneration Plants," Energies, MDPI, vol. 15(15), pages 1-26, July.
    17. Miao, Caixia & Zhou, Guilin & Chen, Shuang & Xie, Hongmei & Zhang, Xianming, 2020. "Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate," Renewable Energy, Elsevier, vol. 153(C), pages 1439-1454.
    18. Melad Atrash & Karen Molina & El-Or Sharoni & Gilbert Azwat & Marina Nisnevitch & Yael Albo & Faina Nakonechny, 2023. "Toward Efficient Continuous Production of Biodiesel from Brown Grease," Sustainability, MDPI, vol. 15(11), pages 1-17, May.
    19. Guido Busca, 2021. "Production of Gasolines and Monocyclic Aromatic Hydrocarbons: From Fossil Raw Materials to Green Processes," Energies, MDPI, vol. 14(13), pages 1-32, July.
    20. Ganesha Thippeshnaik & Sajjal Basanna Prakash & Ajith Bintravalli Suresh & Manjunath Patel Gowdru Chandrashekarappa & Olusegun David Samuel & Oguzhan Der & Ali Ercetin, 2023. "Experimental Investigation of Compression Ignition Engine Combustion, Performance, and Emission Characteristics of Ternary Blends with Higher Alcohols (1-Heptanol and n -Octanol)," Energies, MDPI, vol. 16(18), pages 1-25, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:11:p:4333-:d:1156006. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.