IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-47591-z.html
   My bibliography  Save this article

Frustrated Lewis pair catalyst realizes efficient green diesel production

Author

Listed:
  • De-Chang Li

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Zhengyi Pan

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Zhengbin Tian

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory)

  • Qian Zhang

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Xiaohui Deng

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory)

  • Heqing Jiang

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Guang-Hui Wang

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

Abstract

Hydrotreating renewable oils over sulfided metal catalysts is commercially applied to produce green diesel, but it requires a continuous sulfur replenishment to maintain catalyst activity, which inevitably results in sulfur contamination and increases production costs. We report a robust P-doped NiAl-oxide catalyst with frustrated Lewis pairs (i.e., P atom bonded with the O atom acts as an electron donor, while the spatially separated Ni atom acts as an electron acceptor) that allows efficient green diesel production without sulfur replenishment. The catalyst runs more than 500 h at a weight hourly space velocity (WHSV) of 28.3 h−1 without deactivation (methyl laurate as a model compound), and is able to completely convert a real feedstock of soybean oil to diesel-range hydrocarbons with selectivity >90% during 500 h of operation. This work is expected to open up a new avenue for designing non-sulfur catalysts that can make the green diesel production greener.

Suggested Citation

  • De-Chang Li & Zhengyi Pan & Zhengbin Tian & Qian Zhang & Xiaohui Deng & Heqing Jiang & Guang-Hui Wang, 2024. "Frustrated Lewis pair catalyst realizes efficient green diesel production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47591-z
    DOI: 10.1038/s41467-024-47591-z
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-47591-z
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-47591-z?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Giuseppe Di Vito Nolfi & Katia Gallucci & Leucio Rossi, 2021. "Green Diesel Production by Catalytic Hydrodeoxygenation of Vegetables Oils," IJERPH, MDPI, vol. 18(24), pages 1-28, December.
    2. Sai Zhang & Zheng-Qing Huang & Yuanyuan Ma & Wei Gao & Jing Li & Fangxian Cao & Lin Li & Chun-Ran Chang & Yongquan Qu, 2017. "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    3. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    4. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Stefania Lucantonio & Andrea Di Giuliano & Leucio Rossi & Katia Gallucci, 2023. "Green Diesel Production via Deoxygenation Process: A Review," Energies, MDPI, vol. 16(2), pages 1-44, January.
    2. Jie Yin & Jing Jin & Zhouyang Yin & Liu Zhu & Xin Du & Yong Peng & Pinxian Xi & Chun-Hua Yan & Shouheng Sun, 2023. "The built-in electric field across FeN/Fe3N interface for efficient electrochemical reduction of CO2 to CO," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    4. Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.
    5. Keon Hee Kim & Eun Yeol Lee, 2017. "Environmentally-Benign Dimethyl Carbonate-Mediated Production of Chemicals and Biofuels from Renewable Bio-Oil," Energies, MDPI, vol. 10(11), pages 1-15, November.
    6. Laura Aguado-Deblas & Jesús Hidalgo-Carrillo & Felipa M. Bautista & Diego Luna & Carlos Luna & Juan Calero & Alejandro Posadillo & Antonio A. Romero & Rafael Estevez, 2020. "Diethyl Ether as an Oxygenated Additive for Fossil Diesel/Vegetable Oil Blends: Evaluation of Performance and Emission Quality of Triple Blends on a Diesel Engine," Energies, MDPI, vol. 13(7), pages 1-16, March.
    7. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    8. Nils Kretzschmar & Markus Seifert & Oliver Busse & Jan J. Weigand, 2022. "Prediction of Retention Indices and Response Factors of Oxygenates for GC-FID by Multilinear Regression," Data, MDPI, vol. 7(9), pages 1-12, September.
    9. Nor, Nurazira Mohd & Salih, Nadia & Salimon, Jumat, 2022. "Optimization and lubrication properties of Malaysian crude palm oil fatty acids based neopentyl glycol diester green biolubricant," Renewable Energy, Elsevier, vol. 200(C), pages 942-956.
    10. Miao, Caixia & Zhou, Guilin & Chen, Shuang & Xie, Hongmei & Zhang, Xianming, 2020. "Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate," Renewable Energy, Elsevier, vol. 153(C), pages 1439-1454.
    11. Abraham Casas & Ángel Pérez & María Jesús Ramos, 2023. "Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality," Energies, MDPI, vol. 16(17), pages 1-16, August.
    12. Rafael Estevez & Laura Aguado-Deblas & Alejandro Posadillo & Beatriz Hurtado & Felipa M. Bautista & José M. Hidalgo & Carlos Luna & Juan Calero & Antonio A. Romero & Diego Luna, 2019. "Performance and Emission Quality Assessment in a Diesel Engine of Straight Castor and Sunflower Vegetable Oils, in Diesel/Gasoline/Oil Triple Blends," Energies, MDPI, vol. 12(11), pages 1-13, June.
    13. Shulin Liu & Minghua Dong & Yuxuan Wu & Sen Luan & Yu Xin & Juan Du & Shaopeng Li & Huizhen Liu & Buxing Han, 2022. "Solid surface frustrated Lewis pair constructed on layered AlOOH for hydrogenation reaction," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Valentyna Kukharets & Dalia Juočiūnienė & Taras Hutsol & Olena Sukmaniuk & Jonas Čėsna & Savelii Kukharets & Piotr Piersa & Szymon Szufa & Iryna Horetska & Alona Shevtsova, 2023. "An Algorithm for Managerial Actions on the Rational Use of Renewable Sources of Energy: Determination of the Energy Potential of Biomass in Lithuania," Energies, MDPI, vol. 16(1), pages 1-17, January.
    15. Szabados, György & Bereczky, Ákos, 2018. "Experimental investigation of physicochemical properties of diesel, biodiesel and TBK-biodiesel fuels and combustion and emission analysis in CI internal combustion engine," Renewable Energy, Elsevier, vol. 121(C), pages 568-578.
    16. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
    17. Simões, S.S. & Ribeiro, J.S. & Celante, D. & Brondani, L.N. & Castilhos, F., 2020. "Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction," Renewable Energy, Elsevier, vol. 146(C), pages 719-726.
    18. Hao Yan & Bowen Liu & Xin Zhou & Fanyu Meng & Mingyue Zhao & Yue Pan & Jie Li & Yining Wu & Hui Zhao & Yibin Liu & Xiaobo Chen & Lina Li & Xiang Feng & De Chen & Honghong Shan & Chaohe Yang & Ning Yan, 2023. "Enhancing polyol/sugar cascade oxidation to formic acid with defect rich MnO2 catalysts," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    19. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    20. Julio Berbel & Alejandro Posadillo, 2018. "Review and Analysis of Alternatives for the Valorisation of Agro-Industrial Olive Oil By-Products," Sustainability, MDPI, vol. 10(1), pages 1-9, January.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47591-z. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.