IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v16y2025i1d10.1038_s41467-025-62771-1.html
   My bibliography  Save this article

Reaction-induced regioselective reconstruction of Ni-doped Ce(OH)3/CeO2 enables exceptional activity and selectivity for reverse water-shift reaction

Author

Listed:
  • Wenbin Li

    (Northwestern Polytechnical University)

  • Bing Liu

    (Jiangnan University)

  • Qing Guo

    (Northwestern Polytechnical University)

  • Wenjie Guo

    (Northwestern Polytechnical University)

  • Sai Zhang

    (Northwestern Polytechnical University
    Research & Development Institute of Northwestern Polytechnical University in Shenzhen)

  • Yongquan Qu

    (Northwestern Polytechnical University)

Abstract

Reconstruction of catalysts by reaction environments represents a viable approach to create highly performed active sites. Herein, we develop a reaction-induced regioselective reconstruction of Ni-doped Ce(OH)3/CeO2 nanorods to form dual-active sites composed of carburized Ni clusters and frustrated Lewis pairs (FLPs), delivering exceptional activity, selectivity and stability for reverse water-gas shift reaction. Ni aggregation in the Ce(OH)3 region, coupled with in-situ carbonization by catalytically generated CO during reaction, induces the formation of the carburized Ni clusters, which effectively promoted H2 dissociation. Additionally, Ni doping in the CeO2 region and Ce(OH)3-to-CeO2 phase transition introduce more oxygen vacancies and thereby generated FLPs in CeO2, which facilitate CO2 adsorption and subsequent hydrogenation by spilled *H species from the carburized Ni clusters. Weak CO adsorption on both the carburized Ni clusters and FLPs significantly suppresses the methanation side-reaction. This reaction-induced regioselective reconstruction strategy provides a new avenue for designing highly performed catalysts.

Suggested Citation

  • Wenbin Li & Bing Liu & Qing Guo & Wenjie Guo & Sai Zhang & Yongquan Qu, 2025. "Reaction-induced regioselective reconstruction of Ni-doped Ce(OH)3/CeO2 enables exceptional activity and selectivity for reverse water-shift reaction," Nature Communications, Nature, vol. 16(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-62771-1
    DOI: 10.1038/s41467-025-62771-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-025-62771-1
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-025-62771-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Sai Zhang & Zheng-Qing Huang & Yuanyuan Ma & Wei Gao & Jing Li & Fangxian Cao & Lin Li & Chun-Ran Chang & Yongquan Qu, 2017. "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    2. Sai Zhang & Yuxuan Liu & Mingkai Zhang & Yuanyuan Ma & Jun Hu & Yongquan Qu, 2022. "Sustainable production of hydrogen with high purity from methanol and water at low temperatures," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    3. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    4. Hui Xin & Rongtan Li & Le Lin & Rentao Mu & Mingrun Li & Dan Li & Qiang Fu & Xinhe Bao, 2024. "Reverse water gas-shift reaction product driven dynamic activation of molybdenum nitride catalyst surface," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Long Xiang & Xie, Mei Na & Zhao, Pan Pan & Wang, Feng Xiang & Hu, Peng & Wang, Dong Xiang, 2018. "A novel isobaric adiabatic compressed air energy storage (IA-CAES) system on the base of volatile fluid," Applied Energy, Elsevier, vol. 210(C), pages 198-210.
    2. De-Chang Li & Zhengyi Pan & Zhengbin Tian & Qian Zhang & Xiaohui Deng & Heqing Jiang & Guang-Hui Wang, 2024. "Frustrated Lewis pair catalyst realizes efficient green diesel production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Wang, Yubao & Huang, Xiaozhou & Huang, Zhendong, 2024. "Energy-related uncertainty and Chinese stock market returns," Finance Research Letters, Elsevier, vol. 62(PB).
    4. Chen, Xuejun & Yang, Yongming & Cui, Zhixin & Shen, Jun, 2019. "Vibration fault diagnosis of wind turbines based on variational mode decomposition and energy entropy," Energy, Elsevier, vol. 174(C), pages 1100-1109.
    5. Muhammad Habib Ur Rehman & Luigi Coppola & Ernestino Lufrano & Isabella Nicotera & Cataldo Simari, 2023. "Enhancing Water Retention, Transport, and Conductivity Performance in Fuel Cell Applications: Nafion-Based Nanocomposite Membranes with Organomodified Graphene Oxide Nanoplatelets," Energies, MDPI, vol. 16(23), pages 1-11, November.
    6. Pin Li & Jinsuo Zhang, 2019. "Is China’s Energy Supply Sustainable? New Research Model Based on the Exponential Smoothing and GM(1,1) Methods," Energies, MDPI, vol. 12(2), pages 1-30, January.
    7. Hao Yan & Bowen Liu & Xin Zhou & Fanyu Meng & Mingyue Zhao & Yue Pan & Jie Li & Yining Wu & Hui Zhao & Yibin Liu & Xiaobo Chen & Lina Li & Xiang Feng & De Chen & Honghong Shan & Chaohe Yang & Ning Yan, 2023. "Enhancing polyol/sugar cascade oxidation to formic acid with defect rich MnO2 catalysts," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Sung-Fu Hung & Aoni Xu & Xue Wang & Fengwang Li & Shao-Hui Hsu & Yuhang Li & Joshua Wicks & Eduardo González Cervantes & Armin Sedighian Rasouli & Yuguang C. Li & Mingchuan Luo & Dae-Hyun Nam & Ning W, 2022. "A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    9. Zheng, Bobo & Xu, Jiuping & Ni, Ting & Li, Meihui, 2015. "Geothermal energy utilization trends from a technological paradigm perspective," Renewable Energy, Elsevier, vol. 77(C), pages 430-441.
    10. Mao, Guozhu & Zou, Hongyang & Chen, Guanyi & Du, Huibin & Zuo, Jian, 2015. "Past, current and future of biomass energy research: A bibliometric analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1823-1833.
    11. Luo, Rongrong & Wang, Liuwei & Yu, Wei & Shao, Feilong & Shen, Haikuo & Xie, Huaqing, 2023. "High energy storage density titanium nitride-pentaerythritol solid–solid composite phase change materials for light-thermal-electric conversion," Applied Energy, Elsevier, vol. 331(C).
    12. Ewa C. E. Rönnebro & Greg Whyatt & Michael Powell & Matthew Westman & Feng (Richard) Zheng & Zhigang Zak Fang, 2015. "Metal Hydrides for High-Temperature Power Generation," Energies, MDPI, vol. 8(8), pages 1-25, August.
    13. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    14. Chang, Chih-Chang & Huang, Wei-Hao & Mai, Van-Phung & Tsai, Jia-Shiuan & Yang, Ruey-Jen, 2021. "Experimental investigation into energy harvesting of NaCl droplet flow over graphene supported by silicon dioxide," Energy, Elsevier, vol. 229(C).
    15. Chen, Hao & Wang, Huanran & Li, Ruixiong & Sun, Hao & Ge, Gangqiang & Ling, Lanning, 2022. "Experimental and analytical investigation of near-isothermal pumped hydro-compressed air energy storage system," Energy, Elsevier, vol. 249(C).
    16. Wang, Jiayu, 2016. "Do light vehicle emissions standards promote environmental goals in Australia?," Conference papers 332692, Purdue University, Center for Global Trade Analysis, Global Trade Analysis Project.
    17. Géremi Gilson Dranka & Paula Ferreira, 2020. "Electric Vehicles and Biofuels Synergies in the Brazilian Energy System," Energies, MDPI, vol. 13(17), pages 1-22, August.
    18. Ondraczek, Janosch, 2014. "Are we there yet? Improving solar PV economics and power planning in developing countries: The case of Kenya," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 604-615.
    19. Caspeta, Luis & Caro-Bermúdez, Mario A. & Ponce-Noyola, Teresa & Martinez, Alfredo, 2014. "Enzymatic hydrolysis at high-solids loadings for the conversion of agave bagasse to fuel ethanol," Applied Energy, Elsevier, vol. 113(C), pages 277-286.
    20. Mingda Liu & Zhichao Zhang & Chenyu Li & Sen Jin & Kunlei Zhu & Shoushan Fan & Jia Li & Kai Liu, 2025. "High-entropy alloyed single-atom Pt for methanol oxidation electrocatalysis," Nature Communications, Nature, vol. 16(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-62771-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.