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Environmentally-Benign Dimethyl Carbonate-Mediated Production of Chemicals and Biofuels from Renewable Bio-Oil

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  • Keon Hee Kim

    (Department of Chemical Engineering, Kyung Hee University, Gyeonggi-do 17104, Korea)

  • Eun Yeol Lee

    (Department of Chemical Engineering, Kyung Hee University, Gyeonggi-do 17104, Korea)

Abstract

Due to the increasing emission of carbon dioxide (CO 2 ), the development of fuels and chemicals based on renewable resources has attracted much attention. Bio-oil, as a carbon rich material, has been considered as a feedstock for biodiesel production. In conventional methanol-mediated transesterification of bio-oil for biodiesel production, significant amounts of glycerol are being generated as a byproduct. In order to overcome these issues, dimethyl carbonate (DMC) has been recently used as an alternative acyl acceptor to avoid the generation of glycerol. DMC is an environmentally-benign chemical reagent and reactive solvent due to safety, health, and environmental benefits. Moreover, DMC can be produced from CO 2 . Co-production of biodiesel and chemicals such as glycerol carbonate is possible as the concept of zero-waste utilization of bio-oil. Value-added chemicals can be synthesized using DMC as a reagent. This paper provides a review on the physical and chemical properties of DMC as a solvent, as well as the production methods for DMC. DMC-mediated production of various chemicals and fuels in both chemical and enzymatic processes are discussed together with their pros and cons.

Suggested Citation

  • Keon Hee Kim & Eun Yeol Lee, 2017. "Environmentally-Benign Dimethyl Carbonate-Mediated Production of Chemicals and Biofuels from Renewable Bio-Oil," Energies, MDPI, vol. 10(11), pages 1-15, November.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:11:p:1790-:d:117906
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    2. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    3. Guan-Bang Chen & Jia-Wen Li & Hsien-Tsung Lin & Fang-Hsien Wu & Yei-Chin Chao, 2018. "A Study of the Production and Combustion Characteristics of Pyrolytic Oil from Sewage Sludge Using the Taguchi Method," Energies, MDPI, vol. 11(9), pages 1-17, August.

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