IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v172y2019icp18-25.html
   My bibliography  Save this article

Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils

Author

Listed:
  • Zharova, P.A.
  • Chistyakov, A.V.
  • Shapovalov, S.S.
  • Pasynskii, A.A.
  • Tsodikov, M.V.

Abstract

The preparation of biodiesel from fatty materials HDO provides a very constructive idea to solve the global clean energy problem. The application of catalytic technology to convert oils into green liquid hydrocarbon fuel has great potential for industrial application. The main problem with the development of green diesel technology is the limited number of available non-food sources of fatty acid triglycerides. Also the researchers have made remarkable achievements in the field of catalyst, the stability of the catalyst is insufficient and the selectivity of large molecules of direct alkanes is low. These defects hinder the large-scale resource development of biodiesel. In current paper the potential of hydrodeoxygenation (HDO) of fatty materials and model esters was explored by enhancing the synergy of platinum and tin by using heterometallic (PPh4)3 [Pt (SnCl3)5 complex. Heterometallic (PPh4)3 [Pt (SnCl3)5] complex provides in its structure platinum and tin atoms linked by a metal–metal bond that causes the originality of catalytic performance. The performance of bimetallic Pt-Sn/Al2O3 catalyst, which is characterized by the Sn/Pt molar ratio of 5/1, has been studied at hydrogen pressure 50 atm and temperature 400–480 °C. HDO reaction of a number of fatty materials has been shown to proceed with the highest ever yield of direct hydrocarbons derived from alkoxy and acyl groups of the initial ester. Also it was investigated a performance in HDO reaction of mixture containing rapeseed oil oleic acid and water that simulate cooked oil that may be a prospective soure for green hydrocarbons in megalopolises. A structural studies of the catalyst showed that its high selectivity in HDO reaction of fatty materials provided by two important factors: impregnated particles size and formation of intermettallic species of PtSn3±σ. Finally, catalysts sustained activity and stability were tested during five turns of 24 h each.

Suggested Citation

  • Zharova, P.A. & Chistyakov, A.V. & Shapovalov, S.S. & Pasynskii, A.A. & Tsodikov, M.V., 2019. "Original Pt-Sn/Al2O3 catalyst for selective hydrodeoxygenation of vegetable oils," Energy, Elsevier, vol. 172(C), pages 18-25.
    • Handle: RePEc:eee:energy:v:172:y:2019:i:c:p:18-25
    DOI: 10.1016/j.energy.2019.01.084
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219300866
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.01.084?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wang, Bing & Duan, Pei-Gao & Xu, Yu-Ping & Wang, Feng & Shi, Xian-Lei & Fu, Jie & Lu, Xiu-Yang, 2017. "Co-hydrotreating of algae and used engine oil for the direct production of gasoline and diesel fuels or blending components," Energy, Elsevier, vol. 136(C), pages 151-162.
    2. Hoseinpour, Marziyeh & Sadrnia, Hassan & Tabasizadeh, Mohammad & Ghobadian, Barat, 2017. "Energy and exergy analyses of a diesel engine fueled with diesel, biodiesel-diesel blend and gasoline fumigation," Energy, Elsevier, vol. 141(C), pages 2408-2420.
    3. Hsu, Keng-Hao & Wang, Wei-Cheng & Liu, Yu-Cheng, 2018. "Experimental studies and techno-economic analysis of hydro-processed renewable diesel production in Taiwan," Energy, Elsevier, vol. 164(C), pages 99-111.
    4. Yang, Jia & Li, Xin & Hu, Hongying & Zhang, Xue & Yu, Yin & Chen, Yongsheng, 2011. "Growth and lipid accumulation properties of a freshwater microalga, Chlorella ellipsoidea YJ1, in domestic secondary effluents," Applied Energy, Elsevier, vol. 88(10), pages 3295-3299.
    5. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
    6. Mishra, Purna Chandra & Nayak, Swarup Kumar, 2018. "Pre-and post-mixed hybrid biodiesel blends as alternative energy fuels-an experimental case study on turbo-charged direct injection diesel engine," Energy, Elsevier, vol. 160(C), pages 910-923.
    7. Hu, Zhiquan & Zheng, Yang & Yan, Feng & Xiao, Bo & Liu, Shiming, 2013. "Bio-oil production through pyrolysis of blue-green algae blooms (BGAB): Product distribution and bio-oil characterization," Energy, Elsevier, vol. 52(C), pages 119-125.
    8. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    9. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    10. Narula, Vishal & Thakur, Aman & Uniyal, Ankit & Kalra, Shashvat & Jain, Siddharth, 2017. "Process parameter optimization of low temperature transesterification of algae-Jatropha Curcas oil blend," Energy, Elsevier, vol. 119(C), pages 983-988.
    11. Arun, Naveenji & Sharma, Rajesh V. & Dalai, Ajay K., 2015. "Green diesel synthesis by hydrodeoxygenation of bio-based feedstocks: Strategies for catalyst design and development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 240-255.
    12. Heilmann, Steven M. & Jader, Lindsey R. & Harned, Laurie A. & Sadowsky, Michael J. & Schendel, Frederick J. & Lefebvre, Paul A. & von Keitz, Marc G. & Valentas, Kenneth J., 2011. "Hydrothermal carbonization of microalgae II. Fatty acid, char, and algal nutrient products," Applied Energy, Elsevier, vol. 88(10), pages 3286-3290.
    13. Singh, Devendra & Subramanian, K.A. & Bal, Rajaram & Singh, S.P. & Badola, R., 2018. "Combustion and emission characteristics of a light duty diesel engine fueled with hydro-processed renewable diesel," Energy, Elsevier, vol. 154(C), pages 498-507.
    14. Yang, Po-Ming & Lin, Yuan-Chung & Lin, Kuang C. & Jhang, Syu-Ruei & Chen, Shang-Cyuan & Wang, Chia-Chi & Lin, Ying-Chi, 2015. "Comparison of carbonyl compound emissions from a diesel engine generator fueled with blends of n-butanol, biodiesel and diesel," Energy, Elsevier, vol. 90(P1), pages 266-273.
    15. Yan, Wei-Hong & Wang, Kai & Duan, Pei-Gao & Wang, Bing & Wang, Feng & Shi, Xian-Lei & Xu, Yu-Ping, 2017. "Catalytic hydropyrolysis and co-hydropyrolysis of algae and used engine oil for the production of hydrocarbon-rich fuel," Energy, Elsevier, vol. 133(C), pages 1153-1162.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Joshi, Girdhar & Pandey, Jitendra K. & Rana, Sravendra & Rawat, Devendra S., 2017. "Challenges and opportunities for the application of biofuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 850-866.
    2. Azizi, Kolsoom & Keshavarz Moraveji, Mostafa & Abedini Najafabadi, Hamed, 2018. "A review on bio-fuel production from microalgal biomass by using pyrolysis method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3046-3059.
    3. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2011. "Membrane biodiesel production and refining technology: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 5051-5062.
    4. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    5. Patel, Madhumita & Kumar, Amit, 2016. "Production of renewable diesel through the hydroprocessing of lignocellulosic biomass-derived bio-oil: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1293-1307.
    6. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    7. Gollakota, A.R.K. & Kishore, Nanda & Gu, Sai, 2018. "A review on hydrothermal liquefaction of biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1378-1392.
    8. Ho, Calvin K. & McAuley, Kimberley B. & Peppley, Brant A., 2019. "Biolubricants through renewable hydrocarbons: A perspective for new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    9. No, Soo-Young, 2011. "Inedible vegetable oils and their derivatives for alternative diesel fuels in CI engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 131-149, January.
    10. Suganya, T. & Varman, M. & Masjuki, H.H. & Renganathan, S., 2016. "Macroalgae and microalgae as a potential source for commercial applications along with biofuels production: A biorefinery approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 909-941.
    11. Arun, J. & Raghu, R. & Suhail Madhar Hanif, S. & Thilak, P.G. & Sridhar, D. & Nirmala, N. & Dawn, S.S. & Sivaramakrishnan, R. & Chi, Nguyen Thuy Lan & Pugazhendhi, Arivalagan, 2022. "A comparative review on photo and mixotrophic mode of algae cultivation: Thermochemical processing of biomass, necessity of bio-oil upgrading, challenges and future roadmaps," Applied Energy, Elsevier, vol. 325(C).
    12. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.
    13. Mat Yasin, Mohd Hafizil & Mamat, Rizalman & Najafi, G. & Ali, Obed Majeed & Yusop, Ahmad Fitri & Ali, Mohd Hafiz, 2017. "Potentials of palm oil as new feedstock oil for a global alternative fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1034-1049.
    14. Đurišić-Mladenović, Nataša & Kiss, Ferenc & Škrbić, Biljana & Tomić, Milan & Mićić, Radoslav & Predojević, Zlatica, 2018. "Current state of the biodiesel production and the indigenous feedstock potential in Serbia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 280-291.
    15. Miao, Caixia & Zhou, Guilin & Chen, Shuang & Xie, Hongmei & Zhang, Xianming, 2020. "Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate," Renewable Energy, Elsevier, vol. 153(C), pages 1439-1454.
    16. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part I," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1427-1445.
    17. Zhong, Wenjun & Tamilselvan, P. & Wang, Qian & He, Zhixia & Feng, Huan & Yu, Xiong, 2018. "Experimental study of spray characteristics of diesel/hydrogenated catalytic biodiesel blended fuels under inert and reacting conditions," Energy, Elsevier, vol. 153(C), pages 349-358.
    18. Hansen, Samuel & Mirkouei, Amin & Diaz, Luis A., 2020. "A comprehensive state-of-technology review for upgrading bio-oil to renewable or blended hydrocarbon fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 118(C).
    19. Pragya, Namita & Pandey, Krishan K., 2016. "Life cycle assessment of green diesel production from microalgae," Renewable Energy, Elsevier, vol. 86(C), pages 623-632.
    20. Soriano, J.A. & García-Contreras, R. & Gómez, A. & Mata, C., 2019. "Comparative study of the effect of a new renewable paraffinic fuel on the combustion process of a light-duty diesel engine," Energy, Elsevier, vol. 189(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:172:y:2019:i:c:p:18-25. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.