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Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate

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  • Miao, Caixia
  • Zhou, Guilin
  • Chen, Shuang
  • Xie, Hongmei
  • Zhang, Xianming

Abstract

Cu was introduced into Ni/γ-Al2O3 to prepare mesoporous NixCuy/γ-Al2O3 catalysts with different Ni and Cu contents. H2-TPR, XRD, BET, H2-TPD, and in-situ XPS were used to study the physicochemical properties of the prepared NixCuy/γ-Al2O3 catalysts. The catalytic performances of NixCuy/γ-Al2O3 catalysts were evaluated by methyl laurate catalytic hydrodeoxygenation (HDO) reaction. The NixCuyO/γ-Al2O3 precursors can be reduced to Ni0, Cu0, and NiCu alloy active species by H2 at 420°C. Formed NiCu alloy can effectively promote the electronic effect between Ni and Cu, and enhance the adsorption and activation abilities of the corresponding catalyst for the reactant molecules. The Ni active sites preferentially catalyzes the decarbonylation/carboxyl (DCO) reaction in the deoxygenation of methyl laurate, while the HDO pathway is predominant on the Cu active sites. The deoxygenation pathway obviously changes from DCO to HDO at the mole ratio of Ni/Cu lower than 3/7, and the main deoxygenation products change from C11 to C12 alkane. At the H2/Oil ratio of 500N, the space velocity (SV) of 1.5 h−1, H2 pressure(P) of 2 MPa, and the reaction temperature of 380°C, the Ni3Cu7/γ-Al2O3 catalyst shows the best methyl laurate DCO properties. And methyl laurate conversion and the main deoxygenation products C11 alkane selectivity can reach 98.3 and 87.4%, respectively. Moreover, Ni3Cu7/γ-Al2O3 catalyst also exhibits good stability.

Suggested Citation

  • Miao, Caixia & Zhou, Guilin & Chen, Shuang & Xie, Hongmei & Zhang, Xianming, 2020. "Synergistic effects between Cu and Ni species in NiCu/γ-Al2O3 catalysts for hydrodeoxygenation of methyl laurate," Renewable Energy, Elsevier, vol. 153(C), pages 1439-1454.
  • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1439-1454
    DOI: 10.1016/j.renene.2020.02.099
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    References listed on IDEAS

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    1. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
    2. Chen, Shuang & Miao, Caixia & Luo, Yan & Zhou, Guilin & Xiong, Kun & Jiao, Zhaojie & Zhang, Xianming, 2018. "Study of catalytic hydrodeoxygenation performance of Ni catalysts: Effects of prepared method," Renewable Energy, Elsevier, vol. 115(C), pages 1109-1117.
    3. Zhang, Le & Liu, Ronghou & Yin, Renzhan & Mei, Yuanfei, 2013. "Upgrading of bio-oil from biomass fast pyrolysis in China: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 66-72.
    4. Arun, Naveenji & Sharma, Rajesh V. & Dalai, Ajay K., 2015. "Green diesel synthesis by hydrodeoxygenation of bio-based feedstocks: Strategies for catalyst design and development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 48(C), pages 240-255.
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    2. Wang, Yuzhen & Wang, Ying & Fang, Changqing & Zheng, Xing & Xu, Donghai, 2022. "Effect of Ce in Ni10Cex/γ-Al2O3 for the in situ hydrodeoxidation of Tetra Pak bio-oil during hydrothermal liquefaction," Energy, Elsevier, vol. 248(C).

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