IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i11p4169-d832562.html
   My bibliography  Save this article

Simulation of the Thermal Runaway Onset in Li-Ion Cells—Influence of Cathode Materials and Operating Conditions

Author

Listed:
  • Martina Cianciullo

    (Department of Chemical, Materials and Environmental Engineering, “Sapienza” University of Rome, Via Eudossiana 18, 00184 Rome, Italy)

  • Giorgio Vilardi

    (Department of Chemical, Materials and Environmental Engineering, “Sapienza” University of Rome, Via Eudossiana 18, 00184 Rome, Italy)

  • Barbara Mazzarotta

    (Department of Chemical, Materials and Environmental Engineering, “Sapienza” University of Rome, Via Eudossiana 18, 00184 Rome, Italy)

  • Roberto Bubbico

    (Department of Chemical, Materials and Environmental Engineering, “Sapienza” University of Rome, Via Eudossiana 18, 00184 Rome, Italy)

Abstract

Li-ion batteries are already being used in several applications, from portable devices to the automotive industry, and they represent a promising option also for other critical uses, such as in the storage of energy from renewable sources. However, two of the main concerns that still hinder their massive introduction in these further areas, are their safety and reliability. Depending on cell characteristics and operating conditions, the heat generated within the cell can exceed that dissipated from its surface, and the cell will fail, possibly with catastrophic consequences. To identify the hazardous working conditions of a cell, a simulation model including the main exothermic reactions was set up to investigate the onset of thermal runaway in several Li-ion cell configurations under various operating conditions. The behavior of four different cathodes under thermal abuse and the influence of external factors such as the environmental temperature and the cooling system efficiency were assessed. It was found that among those investigated, the lithium iron phosphate cathode is characterized by a higher thermal stability and that an efficient superficial heat exchange can prevent thermal runaway in most of the cases.

Suggested Citation

  • Martina Cianciullo & Giorgio Vilardi & Barbara Mazzarotta & Roberto Bubbico, 2022. "Simulation of the Thermal Runaway Onset in Li-Ion Cells—Influence of Cathode Materials and Operating Conditions," Energies, MDPI, vol. 15(11), pages 1-24, June.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:11:p:4169-:d:832562
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/11/4169/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/11/4169/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Xu, Bin & Lee, Jinwoo & Kwon, Daeil & Kong, Lingxi & Pecht, Michael, 2021. "Mitigation strategies for Li-ion battery thermal runaway: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    2. Soares, F.J. & Carvalho, L. & Costa, I.C. & Iria, J.P. & Bodet, J.-M. & Jacinto, G. & Lecocq, A. & Roessner, J. & Caillard, B. & Salvi, O., 2015. "The STABALID project: Risk analysis of stationary Li-ion batteries for power system applications," Reliability Engineering and System Safety, Elsevier, vol. 140(C), pages 142-175.
    3. Zhang, Liwen & Zhao, Peng & Xu, Meng & Wang, Xia, 2020. "Computational identification of the safety regime of Li-ion battery thermal runaway," Applied Energy, Elsevier, vol. 261(C).
    4. Menale, Carla & D'Annibale, Francesco & Mazzarotta, Barbara & Bubbico, Roberto, 2019. "Thermal management of lithium-ion batteries: An experimental investigation," Energy, Elsevier, vol. 182(C), pages 57-71.
    5. Gert Berckmans & Maarten Messagie & Jelle Smekens & Noshin Omar & Lieselot Vanhaverbeke & Joeri Van Mierlo, 2017. "Cost Projection of State of the Art Lithium-Ion Batteries for Electric Vehicles Up to 2030," Energies, MDPI, vol. 10(9), pages 1-20, September.
    6. Waag, Wladislaw & Käbitz, Stefan & Sauer, Dirk Uwe, 2013. "Experimental investigation of the lithium-ion battery impedance characteristic at various conditions and aging states and its influence on the application," Applied Energy, Elsevier, vol. 102(C), pages 885-897.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Carla Menale & Stefano Constà & Vincenzo Sglavo & Livia Della Seta & Roberto Bubbico, 2022. "Experimental Investigation of Overdischarge Effects on Commercial Li-Ion Cells," Energies, MDPI, vol. 15(22), pages 1-16, November.
    2. Edoardo Locorotondo & Fabio Corti & Luca Pugi & Lorenzo Berzi & Alberto Reatti & Giovanni Lutzemberger, 2021. "Design of a Wireless Charging System for Online Battery Spectroscopy," Energies, MDPI, vol. 14(1), pages 1-17, January.
    3. Di Giorgio, Paolo & Di Ilio, Giovanni & Jannelli, Elio & Conte, Fiorentino Valerio, 2022. "Innovative battery thermal management system based on hydrogen storage in metal hydrides for fuel cell hybrid electric vehicles," Applied Energy, Elsevier, vol. 315(C).
    4. Tom Verstraten & Md Sazzad Hosen & Maitane Berecibar & Bram Vanderborght, 2023. "Selecting Suitable Battery Technologies for Untethered Robot," Energies, MDPI, vol. 16(13), pages 1-21, June.
    5. Marc Wentker & Matthew Greenwood & Jens Leker, 2019. "A Bottom-Up Approach to Lithium-Ion Battery Cost Modeling with a Focus on Cathode Active Materials," Energies, MDPI, vol. 12(3), pages 1-18, February.
    6. Mohammed, Abubakar Gambo & Elfeky, Karem Elsayed & Wang, Qiuwang, 2022. "Recent advancement and enhanced battery performance using phase change materials based hybrid battery thermal management for electric vehicles," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    7. Farmann, Alexander & Waag, Wladislaw & Sauer, Dirk Uwe, 2016. "Application-specific electrical characterization of high power batteries with lithium titanate anodes for electric vehicles," Energy, Elsevier, vol. 112(C), pages 294-306.
    8. Yashraj Tripathy & Andrew McGordon & Anup Barai, 2020. "Improving Accessible Capacity Tracking at Low Ambient Temperatures for Range Estimation of Battery Electric Vehicles," Energies, MDPI, vol. 13(8), pages 1-18, April.
    9. Thorne, Rebecca Jayne & Hovi, Inger Beate & Figenbaum, Erik & Pinchasik, Daniel Ruben & Amundsen, Astrid Helene & Hagman, Rolf, 2021. "Facilitating adoption of electric buses through policy: Learnings from a trial in Norway," Energy Policy, Elsevier, vol. 155(C).
    10. Yun Bao & Yuansheng Chen, 2021. "Lithium-Ion Battery Real-Time Diagnosis with Direct Current Impedance Spectroscopy," Energies, MDPI, vol. 14(15), pages 1-16, July.
    11. Zhu, Tao & Wills, Richard G.A. & Lot, Roberto & Ruan, Haijun & Jiang, Zhihao, 2021. "Adaptive energy management of a battery-supercapacitor energy storage system for electric vehicles based on flexible perception and neural network fitting," Applied Energy, Elsevier, vol. 292(C).
    12. Thanh-Tung Nguyen & Abdul Basit Khan & Younghwi Ko & Woojin Choi, 2020. "An Accurate State of Charge Estimation Method for Lithium Iron Phosphate Battery Using a Combination of an Unscented Kalman Filter and a Particle Filter," Energies, MDPI, vol. 13(17), pages 1-15, September.
    13. Qiaohua Fang & Xuezhe Wei & Haifeng Dai, 2019. "A Remaining Discharge Energy Prediction Method for Lithium-Ion Battery Pack Considering SOC and Parameter Inconsistency," Energies, MDPI, vol. 12(6), pages 1-24, March.
    14. Hsieh, I-Yun Lisa & Pan, Menghsuan Sam & Chiang, Yet-Ming & Green, William H., 2019. "Learning only buys you so much: Practical limits on battery price reduction," Applied Energy, Elsevier, vol. 239(C), pages 218-224.
    15. Huang, Deyang & Chen, Ziqiang & Zhou, Shiyao, 2021. "Model prediction-based battery-powered heating method for series-connected lithium-ion battery pack working at extremely cold temperatures," Energy, Elsevier, vol. 216(C).
    16. Hsieh, I-Yun Lisa & Pan, Menghsuan Sam & Green, William H., 2020. "Transition to electric vehicles in China: Implications for private motorization rate and battery market," Energy Policy, Elsevier, vol. 144(C).
    17. Horn, Michael & MacLeod, Jennifer & Liu, Meinan & Webb, Jeremy & Motta, Nunzio, 2019. "Supercapacitors: A new source of power for electric cars?," Economic Analysis and Policy, Elsevier, vol. 61(C), pages 93-103.
    18. Thomas F. Landinger & Guenter Schwarzberger & Guenter Hofer & Matthias Rose & Andreas Jossen, 2021. "Power Line Communications for Automotive High Voltage Battery Systems: Channel Modeling and Coexistence Study with Battery Monitoring," Energies, MDPI, vol. 14(7), pages 1-26, March.
    19. Yingjie Chen & Geng Yang & Xu Liu & Zhichao He, 2019. "A Time-Efficient and Accurate Open Circuit Voltage Estimation Method for Lithium-Ion Batteries," Energies, MDPI, vol. 12(9), pages 1-20, May.
    20. Cox, Brian & Bauer, Christian & Mendoza Beltran, Angelica & van Vuuren, Detlef P. & Mutel, Christopher L., 2020. "Life cycle environmental and cost comparison of current and future passenger cars under different energy scenarios," Applied Energy, Elsevier, vol. 269(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:11:p:4169-:d:832562. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.