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Characterization of Hybrid-nano/Paraffin Organic Phase Change Material for Thermal Energy Storage Applications in Solar Thermal Systems

Author

Listed:
  • Manoj Kumar Pasupathi

    (Department of Mechanical Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, India)

  • Karthick Alagar

    (Department of Electrical and Electronics Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, India)

  • Michael Joseph Stalin P

    (Department of Mechanical Engineering, Audisankara College of Engineering & Technology, Gudur 524101, India)

  • Matheswaran M.M

    (Department of Mechanical Engineering, Jansons Institute of Technology, Coimbatore 641659, India)

  • Ghosh Aritra

    (Environment and Sustainability Institute, University of Exeter, Penryn, Cornwall TR10 9FE, UK
    College of Engineering, Mathematics and Physical Sciences, Renewable Energy, University of Exeter, Cornwall TR10 9FE, UK
    Renewable Energy, Stella Turk Building, University of Exeter, Penryn, Cornwall TR10 9FE, UK)

Abstract

In this work, the experimental investigations were piloted to study the influence of hybrid nanoparticles containing SiO 2 and CeO 2 nanoparticles on thermo-physical characteristics of the paraffin-based phase change material (PCM). Initially, the hybrid nanoparticles were prepared by blending equal mass of SiO 2 and CeO 2 nanoparticles. The hybrid-nano/paraffin (HnP) samples were prepared by cautiously dispersing 0, 0.5, 1.0, and 2.0 percentage mass of hybrid nanoparticles inside the paraffin, respectively. The synthesized samples were examined under different instruments such as field emission scanning electron microscope (FESEM), Fourier transform infrared spectrometer (FTIR), differential scanning calorimetry (DSC), thermogravimetric analyzer (TGA), and thermal properties analyzer to ascertain the influence of hybrid nanoparticles on thermo-physical characteristics of the prepared samples. The obtained experimental results proved that the hybrid nanoparticles were uniformly diffused in the paraffin matrix without affecting the chemical arrangement of paraffin molecules. Prominently, the relative thermal stability and relative thermal conductivity of the paraffin were synergistically enriched up to 115.49% and 165.56%, respectively, when dispersing hybrid nanoparticles within paraffin. Furthermore, the hybrid nanoparticles appropriately amended the melting and crystallization point of the paraffin to reduce its supercooling, and the maximum reduction in supercooling was ascertained as 35.81%. The comprehensive studies indicated that the paraffin diffused with SiO 2 and CeO 2 hybrid nanoparticles at 1.0 mass percentage would yield a better outcome compared to the next higher mass fractions without much diminishing the latent heat of paraffin. Hence, it is recommended to utilize the hybrid-nano/paraffin with 1.0 mass fraction of the aforementioned hybrid nanoparticles for effectively augmenting the thermal energy capacity of low-temperature solar thermal systems.

Suggested Citation

  • Manoj Kumar Pasupathi & Karthick Alagar & Michael Joseph Stalin P & Matheswaran M.M & Ghosh Aritra, 2020. "Characterization of Hybrid-nano/Paraffin Organic Phase Change Material for Thermal Energy Storage Applications in Solar Thermal Systems," Energies, MDPI, vol. 13(19), pages 1-15, September.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:19:p:5079-:d:421135
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    References listed on IDEAS

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    5. Muhammad Saqib & Rafal Andrzejczyk, 2023. "A review of phase change materials and heat enhancement methodologies," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 12(3), May.
    6. Jawad Sarwar & Muhammad Rizwan Shad & Arshmah Hasnain & Farman Ali & Konstantinos E. Kakosimos & Aritra Ghosh, 2021. "Performance Analysis and Comparison of a Concentrated Photovoltaic System with Different Phase Change Materials," Energies, MDPI, vol. 14(10), pages 1-17, May.
    7. Aritra Ghosh, 2022. "Recent Advances in Renewable Energy and Clean Energy," Energies, MDPI, vol. 15(9), pages 1-2, April.
    8. Miqdam T. Chaichan & Maytham T. Mahdi & Hussein A. Kazem & Ali H. A. Al-Waeli & Mohammed A. Fayad & Ahmed A. Al-Amiery & Wan Nor Roslam Wan Isahak & Abdul Amir H. Kadhum & Mohd S. Takriff, 2022. "Modified Nano-Fe 2 O 3 -Paraffin Wax for Efficient Photovoltaic/Thermal System in Severe Weather Conditions," Sustainability, MDPI, vol. 14(19), pages 1-23, September.
    9. B. Kalidasan & A. K. Pandey & Saidur Rahman & Aman Yadav & M. Samykano & V. V. Tyagi, 2022. "Graphene–Silver Hybrid Nanoparticle based Organic Phase Change Materials for Enhanced Thermal Energy Storage," Sustainability, MDPI, vol. 14(20), pages 1-16, October.
    10. Kassianne Tofani & Saeed Tiari, 2021. "Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review," Energies, MDPI, vol. 14(13), pages 1-34, June.

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