IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v171y2016icp37-45.html
   My bibliography  Save this article

Preparation of paraffin/porous TiO2 foams with enhanced thermal conductivity as PCM, by covering the TiO2 surface with a carbon layer

Author

Listed:
  • Li, Yali
  • Li, Jinhong
  • Deng, Yong
  • Guan, Weimin
  • Wang, Xiang
  • Qian, Tingting

Abstract

In the present study, porous TiO2 foams (PTF) were prepared by particle-stabilized emulsion method. The samples having solid contents ranging from 20wt.% to 35wt.% were prepared and successfully impregnated with paraffin without using a surfactant. SEM images showed that the prepared PTFs had three-dimensional interpenetrating structures with good porosities. The pore structure and morphology of PTF was markedly influenced by the solid content. With increase in solid content, porosity decreased, along with a decrease in the homologous encapsulation ratio of paraffin. Differential scanning calorimetry (DSC) evaluated the thermal properties of the paraffin/PTF (PTFP) composites. DSC results showed that with a solid content of 20wt.%, the paraffin adsorption reached 62vol.% and latent heat of the composite PCM was 94.05J/g after 200 melting/freezing cycles. TGA results showed that the form-stable composite PCMs had good thermal stabilities. In order to further enhance the thermal conductivity and improve the adsorption capacity of PTF, sucrose was added to the emulsion and carbonized in situ to form carbon/PTF (PTFC). This could also be successfully impregnated with paraffin to obtain the form-stable composite paraffin/PTFC (PTFCP). The TEM images and results of XPS analysis confirmed that the surfaces of TiO2 particles were covered with a 2nm thick carbon film (C/TiO2). The thermal conductivity of PTFCP increased from 0.302W/mK to 1.059W/mK compared to PTFP, along with a further improvement in adsorption capacity. Furthermore, the results of FT-IR analysis and thermal cyclic tests showed that the form-stable composite PCMs had good chemical stability and thermal reliability after 200melting/freezing cycles. Therefore, the prepared form-stable composite PCMs having excellent pore structures, thermal properties, thermal reliabilities, and chemical stabilities are promising PCM candidates for heat energy storage applications.

Suggested Citation

  • Li, Yali & Li, Jinhong & Deng, Yong & Guan, Weimin & Wang, Xiang & Qian, Tingting, 2016. "Preparation of paraffin/porous TiO2 foams with enhanced thermal conductivity as PCM, by covering the TiO2 surface with a carbon layer," Applied Energy, Elsevier, vol. 171(C), pages 37-45.
    • Handle: RePEc:eee:appene:v:171:y:2016:i:c:p:37-45
    DOI: 10.1016/j.apenergy.2016.03.010
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191630321X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.03.010?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Memon, Shazim Ali & Cui, Hongzhi & Lo, Tommy Y. & Li, Qiusheng, 2015. "Development of structural–functional integrated concrete with macro-encapsulated PCM for thermal energy storage," Applied Energy, Elsevier, vol. 150(C), pages 245-257.
    2. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    3. Li, Min & Wu, Zhishen & Tan, Jinmiao, 2012. "Properties of form-stable paraffin/silicon dioxide/expanded graphite phase change composites prepared by sol–gel method," Applied Energy, Elsevier, vol. 92(C), pages 456-461.
    4. Ferrer, Gerard & Solé, Aran & Barreneche, Camila & Martorell, Ingrid & Cabeza, Luisa F., 2015. "Review on the methodology used in thermal stability characterization of phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 665-685.
    5. Fan, Liwu & Khodadadi, J.M., 2011. "Thermal conductivity enhancement of phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 24-46, January.
    6. Mehrali, Mohammad & Latibari, Sara Tahan & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Preparation and properties of highly conductive palmitic acid/graphene oxide composites as thermal energy storage materials," Energy, Elsevier, vol. 58(C), pages 628-634.
    7. Xiao, X. & Zhang, P. & Li, M., 2013. "Preparation and thermal characterization of paraffin/metal foam composite phase change material," Applied Energy, Elsevier, vol. 112(C), pages 1357-1366.
    8. Xu, Biwan & Li, Zongjin, 2013. "Paraffin/diatomite composite phase change material incorporated cement-based composite for thermal energy storage," Applied Energy, Elsevier, vol. 105(C), pages 229-237.
    9. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    10. Li, Min, 2013. "A nano-graphite/paraffin phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 106(C), pages 25-30.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tu, Yubin & Zhu, Wei & Lu, Tianqi & Deng, Yuan, 2017. "A novel thermoelectric harvester based on high-performance phase change material for space application," Applied Energy, Elsevier, vol. 206(C), pages 1194-1202.
    2. Yousefi, Ali & Tang, Waiching & Khavarian, Mehrnoush & Fang, Cheng, 2021. "Development of novel form-stable phase change material (PCM) composite using recycled expanded glass for thermal energy storage in cementitious composite," Renewable Energy, Elsevier, vol. 175(C), pages 14-28.
    3. Zhao, Siyi & Li, Jinhong & Wu, Yifan & Song, Shuang & Liu, Lijie, 2021. "Three-dimensional interconnected porous TiO2 ceramics for high-temperature thermal storage," Renewable Energy, Elsevier, vol. 178(C), pages 701-708.
    4. Maleki, Mahdi & Imani, Abolhassan & Ahmadi, Rouhollah & Banna Motejadded Emrooz, Hosein & Beitollahi, Ali, 2020. "Low-cost carbon foam as a practical support for organic phase change materials in thermal management," Applied Energy, Elsevier, vol. 258(C).
    5. Qiu, Lin & Ouyang, Yuxin & Feng, Yanhui & Zhang, Xinxin, 2019. "Review on micro/nano phase change materials for solar thermal applications," Renewable Energy, Elsevier, vol. 140(C), pages 513-538.
    6. Wang, Lu & Kong, Xiangfei & Ren, Jianlin & Fan, Man & Li, Han, 2022. "Novel hybrid composite phase change materials with high thermal performance based on aluminium nitride and nanocapsules," Energy, Elsevier, vol. 238(PB).
    7. Cui, Wei & Li, Xiangxuan & Li, Xinyi & Lu, Lin & Ma, Ting & Wang, Qiuwang, 2022. "Combined effects of nanoparticles and ultrasonic field on thermal energy storage performance of phase change materials with metal foam," Applied Energy, Elsevier, vol. 309(C).
    8. Zhu, Wei & Tu, Yubin & Deng, Yuan, 2018. "Multi-parameter optimization design of thermoelectric harvester based on phase change material for space generation," Applied Energy, Elsevier, vol. 228(C), pages 873-880.
    9. Meng, Z.N. & Zhang, P., 2017. "Experimental and numerical investigation of a tube-in-tank latent thermal energy storage unit using composite PCM," Applied Energy, Elsevier, vol. 190(C), pages 524-539.
    10. Zhang, Yuang & Wang, Lingjuan & Tang, Bingtao & Lu, Rongwen & Zhang, Shufen, 2016. "Form-stable phase change materials with high phase change enthalpy from the composite of paraffin and cross-linking phase change structure," Applied Energy, Elsevier, vol. 184(C), pages 241-246.
    11. Gu, Xiaobin & Liu, Peng & Bian, Liang & He, Huichao, 2019. "Enhanced thermal conductivity of palmitic acid/mullite phase change composite with graphite powder for thermal energy storage," Renewable Energy, Elsevier, vol. 138(C), pages 833-841.
    12. Dong, Kaixin & Sheng, Nan & Zou, Deqiu & Wang, Cheng & Shimono, Kenji & Akiyama, Tomohiro & Nomura, Takahiro, 2020. "A high-thermal-conductivity, high-durability phase-change composite using a carbon fibre sheet as a supporting matrix," Applied Energy, Elsevier, vol. 264(C).
    13. Manoj Kumar Pasupathi & Karthick Alagar & Michael Joseph Stalin P & Matheswaran M.M & Ghosh Aritra, 2020. "Characterization of Hybrid-nano/Paraffin Organic Phase Change Material for Thermal Energy Storage Applications in Solar Thermal Systems," Energies, MDPI, vol. 13(19), pages 1-15, September.
    14. Tang, Jia & Yang, Mu & Yu, Fang & Chen, Xingyu & Tan, Li & Wang, Ge, 2017. "1-Octadecanol@hierarchical porous polymer composite as a novel shape-stability phase change material for latent heat thermal energy storage," Applied Energy, Elsevier, vol. 187(C), pages 514-522.
    15. Golestaneh, Seyyed Iman & Karimi, Gholamreza & Babapoor, Aziz & Torabi, Farshid, 2018. "Thermal performance of co-electrospun fatty acid nanofiber composites in the presence of nanoparticles," Applied Energy, Elsevier, vol. 212(C), pages 552-564.
    16. Tang, Yaojie & Su, Di & Huang, Xiang & Alva, Guruprasad & Liu, Lingkun & Fang, Guiyin, 2016. "Synthesis and thermal properties of the MA/HDPE composites with nano-additives as form-stable PCM with improved thermal conductivity," Applied Energy, Elsevier, vol. 180(C), pages 116-129.
    17. Nomura, Takahiro & Zhu, Chunyu & Nan, Sheng & Tabuchi, Kazuki & Wang, Shuangfeng & Akiyama, Tomohiro, 2016. "High thermal conductivity phase change composite with a metal-stabilized carbon-fiber network," Applied Energy, Elsevier, vol. 179(C), pages 1-6.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, P. & Xiao, X. & Ma, Z.W., 2016. "A review of the composite phase change materials: Fabrication, characterization, mathematical modeling and application to performance enhancement," Applied Energy, Elsevier, vol. 165(C), pages 472-510.
    2. Parameshwaran, R. & Deepak, K. & Saravanan, R. & Kalaiselvam, S., 2014. "Preparation, thermal and rheological properties of hybrid nanocomposite phase change material for thermal energy storage," Applied Energy, Elsevier, vol. 115(C), pages 320-330.
    3. Feng, Daili & Feng, Yanhui & Qiu, Lin & Li, Pei & Zang, Yuyang & Zou, Hanying & Yu, Zepei & Zhang, Xinxin, 2019. "Review on nanoporous composite phase change materials: Fabrication, characterization, enhancement and molecular simulation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 578-605.
    4. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    5. Johra, Hicham & Heiselberg, Per, 2017. "Influence of internal thermal mass on the indoor thermal dynamics and integration of phase change materials in furniture for building energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 19-32.
    6. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
    7. Xu, Biwan & Ma, Hongyan & Lu, Zeyu & Li, Zongjin, 2015. "Paraffin/expanded vermiculite composite phase change material as aggregate for developing lightweight thermal energy storage cement-based composites," Applied Energy, Elsevier, vol. 160(C), pages 358-367.
    8. Yuan, Yanping & Zhang, Nan & Li, Tianyu & Cao, Xiaoling & Long, Weiyue, 2016. "Thermal performance enhancement of palmitic-stearic acid by adding graphene nanoplatelets and expanded graphite for thermal energy storage: A comparative study," Energy, Elsevier, vol. 97(C), pages 488-497.
    9. Abdelwaheb Trigui & Makki Abdelmouleh, 2023. "Improving the Heat Transfer of Phase Change Composites for Thermal Energy Storage by Adding Copper: Preparation and Thermal Properties," Sustainability, MDPI, vol. 15(3), pages 1-19, January.
    10. Gutierrez, Andrea & Ushak, Svetlana & Galleguillos, Hector & Fernandez, Angel & Cabeza, Luisa F. & Grágeda, Mario, 2015. "Use of polyethylene glycol for the improvement of the cycling stability of bischofite as thermal energy storage material," Applied Energy, Elsevier, vol. 154(C), pages 616-621.
    11. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    12. Palacios, Anabel & Cong, Lin & Navarro, M.E. & Ding, Yulong & Barreneche, Camila, 2019. "Thermal conductivity measurement techniques for characterizing thermal energy storage materials – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 32-52.
    13. Nomura, Takahiro & Tabuchi, Kazuki & Zhu, Chunyu & Sheng, Nan & Wang, Shuangfeng & Akiyama, Tomohiro, 2015. "High thermal conductivity phase change composite with percolating carbon fiber network," Applied Energy, Elsevier, vol. 154(C), pages 678-685.
    14. Xu, Biwan & Li, Zongjin, 2014. "Paraffin/diatomite/multi-wall carbon nanotubes composite phase change material tailor-made for thermal energy storage cement-based composites," Energy, Elsevier, vol. 72(C), pages 371-380.
    15. Li, Xiangyu & Chen, Huisu & Li, Huiqiang & Liu, Lin & Lu, Zeyu & Zhang, Tao & Duan, Wen Hui, 2015. "Integration of form-stable paraffin/nanosilica phase change material composites into vacuum insulation panels for thermal energy storage," Applied Energy, Elsevier, vol. 159(C), pages 601-609.
    16. Ramakrishnan, Sayanthan & Sanjayan, Jay & Wang, Xiaoming & Alam, Morshed & Wilson, John, 2015. "A novel paraffin/expanded perlite composite phase change material for prevention of PCM leakage in cementitious composites," Applied Energy, Elsevier, vol. 157(C), pages 85-94.
    17. Ramakrishnan, Sayanthan & Wang, Xiaoming & Sanjayan, Jay & Wilson, John, 2017. "Thermal performance assessment of phase change material integrated cementitious composites in buildings: Experimental and numerical approach," Applied Energy, Elsevier, vol. 207(C), pages 654-664.
    18. Memon, Shazim Ali, 2014. "Phase change materials integrated in building walls: A state of the art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 870-906.
    19. Ma, Zhenjun & Lin, Wenye & Sohel, M. Imroz, 2016. "Nano-enhanced phase change materials for improved building performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 1256-1268.
    20. Mishra, Amit Kumar & Lahiri, B.B. & Philip, John, 2020. "Carbon black nano particle loaded lauric acid-based form-stable phase change material with enhanced thermal conductivity and photo-thermal conversion for thermal energy storage," Energy, Elsevier, vol. 191(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:171:y:2016:i:c:p:37-45. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.