IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v12y2019i2p230-d197252.html
   My bibliography  Save this article

Optimization of Biodiesel Production Using Nanomagnetic CaO-Based Catalysts with Subcritical Methanol Transesterification of Rubber Seed Oil

Author

Listed:
  • Veronica Winoto

    (Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand)

  • Nuttawan Yoswathana

    (Department of Chemical Engineering, Faculty of Engineering, Mahidol University, Nakhon Pathom 73170, Thailand)

Abstract

The molar ratio of methanol to rubber seed oil (RSO), catalyst loading, and the reaction time of RSO biodiesel production were optimized in this work. The response surface methodology, using the Box–Behnken design, was analyzed to determine the optimum fatty acid methyl ester (FAME) yield. The performance of various nanomagnetic CaO-based catalysts—KF/CaO-Fe 3 O 4 , KF/CaO-Fe 3 O 4 -Li (Li additives), and KF/CaO-Fe 3 O 4 -Al (Al additives)—were compared. Rubber seed biodiesel was produced via the transesterification process under subcritical methanol conditions with nanomagnetic catalysts. The experimental results indicated that the KF/CaO-Fe 3 O 4 -Al nanomagnetic catalyst produced the highest FAME yield of 86.79%. The optimum conditions were a 28:1 molar ratio of methanol to RSO, 1.5 wt % catalyst, and 49 min reaction time. Al additives of KF/CaO-Fe 3 O 4 nanomagnetic catalyst enhanced FAME yield without Al up to 18.17% and shortened the reaction time by up to 11 min.

Suggested Citation

  • Veronica Winoto & Nuttawan Yoswathana, 2019. "Optimization of Biodiesel Production Using Nanomagnetic CaO-Based Catalysts with Subcritical Methanol Transesterification of Rubber Seed Oil," Energies, MDPI, vol. 12(2), pages 1-13, January.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:2:p:230-:d:197252
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/12/2/230/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/12/2/230/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.
    2. Roschat, Wuttichai & Siritanon, Theeranun & Yoosuk, Boonyawan & Sudyoadsuk, Taweesak & Promarak, Vinich, 2017. "Rubber seed oil as potential non-edible feedstock for biodiesel production using heterogeneous catalyst in Thailand," Renewable Energy, Elsevier, vol. 101(C), pages 937-944.
    3. Harsha Hebbar, H.R. & Math, M.C. & Yatish, K.V., 2018. "Optimization and kinetic study of CaO nano-particles catalyzed biodiesel production from Bombax ceiba oil," Energy, Elsevier, vol. 143(C), pages 25-34.
    4. Marina Corral Bobadilla & Roberto Fernández Martínez & Rubén Lostado Lorza & Fátima Somovilla Gómez & Eliseo P. Vergara González, 2018. "Optimizing Biodiesel Production from Waste Cooking Oil Using Genetic Algorithm-Based Support Vector Machines," Energies, MDPI, vol. 11(11), pages 1-19, November.
    5. Kaur, Mandeep & Ali, Amjad, 2011. "Lithium ion impregnated calcium oxide as nano catalyst for the biodiesel production from karanja and jatropha oils," Renewable Energy, Elsevier, vol. 36(11), pages 2866-2871.
    6. Chukwuma Onumaegbu & Abed Alaswad & Cristina Rodriguez & Abdul G. Olabi, 2018. "Optimization of Pre-Treatment Process Parameters to Generate Biodiesel from Microalga," Energies, MDPI, vol. 11(4), pages 1-16, March.
    7. Siriwardhana, Manjula & Opathella, G.K.C. & Jha, M.K., 2009. "Bio-diesel: Initiatives, potential and prospects in Thailand: A review," Energy Policy, Elsevier, vol. 37(2), pages 554-559, February.
    8. Mohammad I. Jahirul & Wenyong Koh & Richard J. Brown & Wijitha Senadeera & Ian O'Hara & Lalehvash Moghaddam, 2014. "Biodiesel Production from Non-Edible Beauty Leaf ( Calophyllum inophyllum ) Oil: Process Optimization Using Response Surface Methodology (RSM)," Energies, MDPI, vol. 7(8), pages 1-15, August.
    9. Go, Alchris Woo & Tran Nguyen, Phuong Lan & Huynh, Lien Huong & Liu, Ying-Tsung & Sutanto, Sylviana & Ju, Yi-Hsu, 2014. "Catalyst free esterification of fatty acids with methanol under subcritical condition," Energy, Elsevier, vol. 70(C), pages 393-400.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Arridina Susan Silitonga & Teuku Meurah Indra Mahlia & Abd Halim Shamsuddin & Hwai Chyuan Ong & Jassinnee Milano & Fitranto Kusumo & Abdi Hanra Sebayang & Surya Dharma & Husin Ibrahim & Hazlina Husin , 2019. "Optimization of Cerbera manghas Biodiesel Production Using Artificial Neural Networks Integrated with Ant Colony Optimization," Energies, MDPI, vol. 12(20), pages 1-21, October.
    2. Anderson Breno Souza & Alvaro Antonio Villa Ochoa & José Ângelo Peixoto da Costa & Gustavo de Novaes Pires Leite & Héber Claudius Nunes Silva & Andrezza Carolina Carneiro Tómas & David Campos Barbosa , 2023. "A Review of Tropical Organic Materials for Biodiesel as a Substitute Energy Source in Internal Combustion Engines: A Viable Solution?," Energies, MDPI, vol. 16(9), pages 1-25, April.
    3. Dan Dobrotă & Gabriela Dobrotă, 2019. "Reducing of Energy Consumption by Improving the Reclaiming Technology in Autoclave of a Rubber Wastes," Energies, MDPI, vol. 12(8), pages 1-18, April.
    4. Aisien, Felix Aibuedefe & Aisien, Eki Tina, 2023. "Modeling and optimization of transesterification of rubber seed oil using sulfonated CaO derived from giant African land snail (Achatina fulica) catalyst by response surface methodology," Renewable Energy, Elsevier, vol. 207(C), pages 137-146.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shelare, Sagar D. & Belkhode, Pramod N. & Nikam, Keval Chandrakant & Jathar, Laxmikant D. & Shahapurkar, Kiran & Soudagar, Manzoore Elahi M. & Veza, Ibham & Khan, T.M. Yunus & Kalam, M.A. & Nizami, Ab, 2023. "Biofuels for a sustainable future: Examining the role of nano-additives, economics, policy, internet of things, artificial intelligence and machine learning technology in biodiesel production," Energy, Elsevier, vol. 282(C).
    2. Olatundun, Esther Adedayo & Borokini, Omowumi Oluwatumininu & Betiku, Eriola, 2020. "Cocoa pod husk-plantain peel blend as a novel green heterogeneous catalyst for renewable and sustainable honne oil biodiesel synthesis: A case of biowastes-to-wealth," Renewable Energy, Elsevier, vol. 166(C), pages 163-175.
    3. Ambat, Indu & Srivastava, Varsha & Sillanpää, Mika, 2018. "Recent advancement in biodiesel production methodologies using various feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 356-369.
    4. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.
    5. Iftikhar Ahmad & Adil Sana & Manabu Kano & Izzat Iqbal Cheema & Brenno C. Menezes & Junaid Shahzad & Zahid Ullah & Muzammil Khan & Asad Habib, 2021. "Machine Learning Applications in Biofuels’ Life Cycle: Soil, Feedstock, Production, Consumption, and Emissions," Energies, MDPI, vol. 14(16), pages 1-27, August.
    6. Katagi, Kariyappa S. & Munnolli, Ravindra S. & Hosamani, Kallappa M., 2011. "Unique occurrence of unusual fatty acid in the seed oil of Aegle marmelos Corre: Screening the rich source of seed oil for bio-energy production," Applied Energy, Elsevier, vol. 88(5), pages 1797-1802, May.
    7. Ruth Chinyere Anyanwu & Cristina Rodriguez & Andy Durrant & Abdul Ghani Olabi, 2022. "Evaluation of Growth Rate and Biomass Productivity of Scenedesmus quadricauda and Chlorella vulgaris under Different LED Wavelengths and Photoperiods," Sustainability, MDPI, vol. 14(10), pages 1-13, May.
    8. Pandey, Vimal Chandra & Singh, Kripal & Singh, Jay Shankar & Kumar, Akhilesh & Singh, Bajrang & Singh, Rana P., 2012. "Jatropha curcas: A potential biofuel plant for sustainable environmental development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2870-2883.
    9. Liu, Ju-Zhao & Cui, Qi & Kang, Yu-Fei & Meng, Yao & Gao, Ming-Zhu & Efferth, Thomas & Fu, Yu-Jie, 2019. "Euonymus maackii Rupr. Seed oil as a new potential non-edible feedstock for biodiesel," Renewable Energy, Elsevier, vol. 133(C), pages 261-267.
    10. Sannagoudar Basanagoudar, Arun & Maleki, Basir & Prakash Ravikumar, Mithun & Mounesh, & Kuppe, Pramoda & Kalanakoppal Venkatesh, Yatish, 2024. "Exploitation of Annona reticulata leaf extract for the synthesis of CeO2 nanoparticles as catalyst for the production of biodiesel using seed oil thereof," Energy, Elsevier, vol. 298(C).
    11. Reddy, M. Sarveshwar & Sharma, Nikhil & Agarwal, Avinash Kumar, 2016. "Effect of straight vegetable oil blends and biodiesel blends on wear of mechanical fuel injection equipment of a constant speed diesel engine," Renewable Energy, Elsevier, vol. 99(C), pages 1008-1018.
    12. Laureano Costarrosa & David Eduardo Leiva-Candia & Antonio José Cubero-Atienza & Juan José Ruiz & M. Pilar Dorado, 2018. "Optimization of the Transesterification of Waste Cooking Oil with Mg-Al Hydrotalcite Using Response Surface Methodology," Energies, MDPI, vol. 11(2), pages 1-9, January.
    13. Sarah Oluwabunmi Bitire & Emeka Charles Nwanna & Tien-Chien Jen, 2023. "The impact of CuO nanoparticles as fuel additives in biodiesel-blend fuelled diesel engine: A review," Energy & Environment, , vol. 34(7), pages 2259-2289, November.
    14. Qian, Kun & Shen, Xiang & Wang, Yanxin & Gao, Qiang & Ding, Hongwei, 2015. "In-situ transesterification of Jatropha oil over an efficient solid alkali using low leaching component supported on industrial silica gel," Energy, Elsevier, vol. 93(P2), pages 2251-2257.
    15. Ganesan, Shangeetha & Nadarajah, Sivajothi & Chee, Xin Yeng & Khairuddean, Melati & Teh, Geok Bee, 2020. "Esterification of free fatty acids using ammonium ferric sulphate-calcium silicate as a heterogeneous catalyst," Renewable Energy, Elsevier, vol. 153(C), pages 1406-1417.
    16. Yatish, K.V. & Lalithamba, H.S. & Suresh, R. & Latha, H.K.E., 2020. "Ochrocarpus longifolius assisted green synthesis of CaTiO3 nanoparticle for biodiesel production and its kinetic study," Renewable Energy, Elsevier, vol. 147(P1), pages 310-321.
    17. Nitièma-Yefanova, Svitlana & Coniglio, Lucie & Schneider, Raphaël & Nébié, Roger H.C. & Bonzi-Coulibaly, Yvonne L., 2016. "Ethyl biodiesel production from non-edible oils of Balanites aegyptiaca, Azadirachta indica, and Jatropha curcas seeds – Laboratory scale development," Renewable Energy, Elsevier, vol. 96(PA), pages 881-890.
    18. Chen, Ying-Chen & Lin, Dai-Ying & Chen, Bing-Hung, 2019. "Metasilicate-based catalyst prepared from natural diatomaceous earth for biodiesel production," Renewable Energy, Elsevier, vol. 138(C), pages 1042-1050.
    19. Li, Hui & Liu, Fengsheng & Ma, Xiaoling & Cui, Ping & Guo, Min & Li, Yan & Gao, Yan & Zhou, Shoujun & Yu, Mingzhi, 2020. "An efficient basic heterogeneous catalyst synthesis of magnetic mesoporous Fe@C support SrO for transesterification," Renewable Energy, Elsevier, vol. 149(C), pages 816-827.
    20. Aghel, Babak & Mohadesi, Majid & Ansari, Ahmadreza & Maleki, Mahmoud, 2019. "Pilot-scale production of biodiesel from waste cooking oil using kettle limescale as a heterogeneous catalyst," Renewable Energy, Elsevier, vol. 142(C), pages 207-214.

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:12:y:2019:i:2:p:230-:d:197252. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.