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Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field

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  • Hanh, Hoang Duc
  • Dong, Nguyen The
  • Okitsu, Kenji
  • Nishimura, Rokuro
  • Maeda, Yasuaki

Abstract

The biodiesel production through transesterification of triolein with various alcohols such as methanol, ethanol, propanol, butanol, hexanol, octanol and decanol was investigated at molar ratio 6:1 (alcohol:triolein) and 25°C in the presence of base catalysts (NaOH and KOH) under ultrasonic irradiation (40kHz) and mechanical stirring (1800 rot/min) conditions. It was found that the rate of the alkyl ester formation under the ultrasonic irradiation condition was higher than that under the stirring condition. In addition, it was confirmed that the rate depended upon the kind of alcohols; as the number of carbon in alcohol increased, the rate of the ester formation tended to decrease. On the other hand, the secondary alcohols such as 2-propanol, 2-butanol, 2-hexanol, and 2-octanol showed little ester conversion, suggesting that the steric hindrance strongly affected the transesterification of triolein.

Suggested Citation

  • Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field," Renewable Energy, Elsevier, vol. 34(3), pages 766-768.
    • Handle: RePEc:eee:renene:v:34:y:2009:i:3:p:766-768
    DOI: 10.1016/j.renene.2008.04.007
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    References listed on IDEAS

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    1. Masakazu Toda & Atsushi Takagaki & Mai Okamura & Junko N. Kondo & Shigenobu Hayashi & Kazunari Domen & Michikazu Hara, 2005. "Biodiesel made with sugar catalyst," Nature, Nature, vol. 438(7065), pages 178-178, November.
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    1. Faraguna, Fabio & Racar, Marko & Jukić, Ante, 2019. "Test method for determination of different biodiesels (fatty acid alkyl esters) content in diesel fuel using FTIR-ATR," Renewable Energy, Elsevier, vol. 133(C), pages 1231-1235.
    2. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat Teong & Khayoon, Muataz Sh., 2012. "Intensification of biodiesel production via ultrasonic-assisted process: A critical review on fundamentals and recent development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4574-4587.
    3. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
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    5. A Shalmashi & F Khodadadi, 2019. "Ultrasound-assisted synthesis of biodiesel from peanut oil by using response surface methodology," Energy & Environment, , vol. 30(2), pages 272-291, March.
    6. Oh, Pin Pin & Lau, Harrison Lik Nang & Chen, Junghui & Chong, Mei Fong & Choo, Yuen May, 2012. "A review on conventional technologies and emerging process intensification (PI) methods for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5131-5145.
    7. Manh, Do-Van & Chen, Yi-Hung & Chang, Chia-Chi & Chang, Ching-Yuan & Hanh, Hoang-Duc & Chau, Nguyen-Hoai & Tuyen, Trinh-Van & Long, Pham-Quoc & Minh, Chau-Van, 2012. "Effects of blending composition of tung oil and ultrasonic irradiation intensity on the biodiesel production," Energy, Elsevier, vol. 48(1), pages 519-524.
    8. Veljković, Vlada B. & Avramović, Jelena M. & Stamenković, Olivera S., 2012. "Biodiesel production by ultrasound-assisted transesterification: State of the art and the perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(2), pages 1193-1209.
    9. Li, Qiang & Xu, Jingyang & Du, Wei & Li, Yang & Liu, Dehua, 2013. "Ethanol as the acyl acceptor for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 742-748.
    10. Ming-Chien Hsiao & Peir-Horng Liao & Kuo-Chou Yang & Nguyen Vu Lan & Shuhn-Shyurng Hou, 2022. "Enhanced Biodiesel Synthesis via a Homogenizer-Assisted Two-Stage Conversion Process Using Waste Edible Oil as Feedstock," Energies, MDPI, vol. 15(23), pages 1-15, November.
    11. Mia Gotovuša & Marko Racar & Lucija Konjević & Jelena Parlov Vuković & Fabio Faraguna, 2023. "The Influence of the Reaction Parameters on the Synthesis of Fatty Acid Octyl Esters and Investigation of Applications Properties of Its Blends with Mineral Diesel," Energies, MDPI, vol. 16(7), pages 1-17, March.
    12. Ming-Chien Hsiao & Peir-Horng Liao & Nguyen Vu Lan & Shuhn-Shyurng Hou, 2021. "Enhancement of Biodiesel Production from High-Acid-Value Waste Cooking Oil via a Microwave Reactor Using a Homogeneous Alkaline Catalyst," Energies, MDPI, vol. 14(2), pages 1-11, January.
    13. Ramachandran, K. & Suganya, T. & Nagendra Gandhi, N. & Renganathan, S., 2013. "Recent developments for biodiesel production by ultrasonic assist transesterification using different heterogeneous catalyst: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 410-418.
    14. José María Encinar & Ana Pardal & Nuria Sánchez & Sergio Nogales, 2018. "Biodiesel by Transesterification of Rapeseed Oil Using Ultrasound: A Kinetic Study of Base-Catalysed Reactions," Energies, MDPI, vol. 11(9), pages 1-13, August.
    15. da Costa Evangelista, João Paulo & Gondim, Amanda Duarte & Souza, Luiz Di & Araujo, Antonio Souza, 2016. "Alumina-supported potassium compounds as heterogeneous catalysts for biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 887-894.
    16. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.
    17. Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production by esterification of oleic acid with short-chain alcohols under ultrasonic irradiation condition," Renewable Energy, Elsevier, vol. 34(3), pages 780-783.
    18. Sara Almasi & Barat Ghobadian & Gholam Hassan Najafi & Talal Yusaf & Masoud Dehghani Soufi & Seyed Salar Hoseini, 2019. "Optimization of an Ultrasonic-Assisted Biodiesel Production Process from One Genotype of Rapeseed (TERI (OE) R-983) as a Novel Feedstock Using Response Surface Methodology," Energies, MDPI, vol. 12(14), pages 1-14, July.

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