IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v59y2016icp887-894.html
   My bibliography  Save this article

Alumina-supported potassium compounds as heterogeneous catalysts for biodiesel production: A review

Author

Listed:
  • da Costa Evangelista, João Paulo
  • Gondim, Amanda Duarte
  • Souza, Luiz Di
  • Araujo, Antonio Souza

Abstract

Alumina-supported potassium oxides are promising catalysts for the transesterification reaction of vegetable oils for biodiesel production. Various potassium compounds Al2O3-supported were prepared via impregnation method. Potassium oxide (K2O) is a good candidate for a solid base catalyst from an economical point of view. In the present work, we reviewed K2O catalyst for the vegetable oil transesterification based on a variety of related research papers. The potassium compounds supported in catalysts, KOH/Al2O3, KNO3/Al2O3, KI/Al2O3, KF/Al2O3 and K2CO3/Al2O3, were optimized through various reaction parameters, such as: amount of catalyst, molar ratio of oil to alcohol, reaction time and temperature. Yields and conversions from various catalytic systems applied for biodiesel production were also compared. Among the catalysts studied, the KF/Al2O3 showed higher catalytic activity and a small amount of catalyst requirement in the transesterification reaction, indicating that it can be applied as a potential catalyst in the industry.

Suggested Citation

  • da Costa Evangelista, João Paulo & Gondim, Amanda Duarte & Souza, Luiz Di & Araujo, Antonio Souza, 2016. "Alumina-supported potassium compounds as heterogeneous catalysts for biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 887-894.
    • Handle: RePEc:eee:rensus:v:59:y:2016:i:c:p:887-894
    DOI: 10.1016/j.rser.2016.01.061
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032116000915
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2016.01.061?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ahmad, A.L. & Yasin, N.H. Mat & Derek, C.J.C. & Lim, J.K., 2011. "Microalgae as a sustainable energy source for biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 584-593, January.
    2. Trakarnpruk, Wimonrat & Porntangjitlikit, Suriya, 2008. "Palm oil biodiesel synthesized with potassium loaded calcined hydrotalcite and effect of biodiesel blend on elastomer properties," Renewable Energy, Elsevier, vol. 33(7), pages 1558-1563.
    3. Noiroj, Krisada & Intarapong, Pisitpong & Luengnaruemitchai, Apanee & Jai-In, Samai, 2009. "A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil," Renewable Energy, Elsevier, vol. 34(4), pages 1145-1150.
    4. Jang, Myung Gwi & Kim, Deog Keun & Park, Soon Chul & Lee, Jin Suk & Kim, Seung Wook, 2012. "Biodiesel production from crude canola oil by two-step enzymatic processes," Renewable Energy, Elsevier, vol. 42(C), pages 99-104.
    5. Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field," Renewable Energy, Elsevier, vol. 34(3), pages 766-768.
    6. Islam, Aminul & Taufiq-Yap, Yun Hin & Ravindra, Pogaku & Teo, Siow Hwa & Sivasangar, S. & Chan, Eng-Seng, 2015. "Biodiesel synthesis over millimetric γ-Al2O3/KI catalyst," Energy, Elsevier, vol. 89(C), pages 965-973.
    7. Yin, Xiulian & Ma, Haile & You, Qinghong & Wang, Zhenbin & Chang, Jinke, 2012. "Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil," Applied Energy, Elsevier, vol. 91(1), pages 320-325.
    8. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Babu, D. & Karvembu, R. & Anand, R., 2018. "Impact of split injection strategy on combustion, performance and emissions characteristics of biodiesel fuelled common rail direct injection assisted diesel engine," Energy, Elsevier, vol. 165(PB), pages 577-592.
    2. Essamlali, Younes & Amadine, Othmane & Fihri, Aziz & Zahouily, Mohamed, 2019. "Sodium modified fluorapatite as a sustainable solid bi-functional catalyst for biodiesel production from rapeseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 1295-1307.
    3. Othman, Mohd Fahmi & Adam, Abdullah & Najafi, G. & Mamat, Rizalman, 2017. "Green fuel as alternative fuel for diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 694-709.
    4. Zhang, Yujiao & Niu, Shengli & Hao, Yanan & Liu, Sitong & Liu, Jisen & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2023. "Preparation of SrZrAl multiple oxide catalyst for produce biodiesel from acidified palm oil," Renewable Energy, Elsevier, vol. 207(C), pages 116-127.
    5. Galadima, Ahmad & Muraza, Oki, 2018. "Hydrothermal liquefaction of algae and bio-oil upgrading into liquid fuels: Role of heterogeneous catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1037-1048.
    6. Muñoz, Robinson & González, Aixa & Valdebenito, Fabiola & Ciudad, Gustavo & Navia, Rodrigo & Pecchi, Gina & Azócar, Laura, 2020. "Fly ash as a new versatile acid-base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1931-1939.
    7. Li, Xin & Luo, Xingyi & Jin, Yangbin & Li, Jinyan & Zhang, Hongdan & Zhang, Aiping & Xie, Jun, 2018. "Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3762-3797.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.
    2. Qian, Kun & Shen, Xiang & Wang, Yanxin & Gao, Qiang & Ding, Hongwei, 2015. "In-situ transesterification of Jatropha oil over an efficient solid alkali using low leaching component supported on industrial silica gel," Energy, Elsevier, vol. 93(P2), pages 2251-2257.
    3. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat Teong & Khayoon, Muataz Sh., 2012. "Intensification of biodiesel production via ultrasonic-assisted process: A critical review on fundamentals and recent development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4574-4587.
    4. Tariq, Muhammad & Ali, Saqib & Khalid, Nasir, 2012. "Activity of homogeneous and heterogeneous catalysts, spectroscopic and chromatographic characterization of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6303-6316.
    5. Andreas Vonortas & Nikolaos Papayannakos, 2014. "Comparative analysis of biodiesel versus green diesel," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 3(1), pages 3-23, January.
    6. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
    7. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    8. Veiga, Paula Moraes & Luna, Aderval Severino & de Figueiredo Portilho, Marcio & de Oliveira Veloso, Cláudia & Henriques, Cristiane Assumpção, 2014. "Zn,Al-catalysts for heterogeneous biodiesel production: Basicity and process optimization," Energy, Elsevier, vol. 75(C), pages 453-462.
    9. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    10. Peng-Lim, Boey & Ganesan, Shangeetha & Maniam, Gaanty Pragas & Khairuddean, Melati, 2012. "Sequential conversion of high free fatty acid oils into biodiesel using a new catalyst system," Energy, Elsevier, vol. 46(1), pages 132-139.
    11. Haseeb, A.S.M.A. & Jun, T.S. & Fazal, M.A. & Masjuki, H.H., 2011. "Degradation of physical properties of different elastomers upon exposure to palm biodiesel," Energy, Elsevier, vol. 36(3), pages 1814-1819.
    12. Jaiyen, Siyada & Naree, Thikumporn & Ngamcharussrivichai, Chawalit, 2015. "Comparative study of natural dolomitic rock and waste mixed seashells as heterogeneous catalysts for the methanolysis of palm oil to biodiesel," Renewable Energy, Elsevier, vol. 74(C), pages 433-440.
    13. Hoseini, S.S. & Najafi, G. & Ghobadian, B. & Mamat, R. & Ebadi, M.T. & Yusaf, Talal, 2019. "Characterization of biodiesel production (ultrasonic-assisted) from evening-primroses (Oenothera lamarckiana) as novel feedstock and its effect on CI engine parameters," Renewable Energy, Elsevier, vol. 130(C), pages 50-60.
    14. Al-Jammal, Noor & Al-Hamamre, Zayed & Alnaief, Mohammad, 2016. "Manufacturing of zeolite based catalyst from zeolite tuft for biodiesel production from waste sunflower oil," Renewable Energy, Elsevier, vol. 93(C), pages 449-459.
    15. Haseeb, A.S.M.A. & Masjuki, H.H. & Siang, C.T. & Fazal, M.A., 2010. "Compatibility of elastomers in palm biodiesel," Renewable Energy, Elsevier, vol. 35(10), pages 2356-2361.
    16. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    17. Cao, Yan & Doustgani, Amir & Salehi, Abozar & Nemati, Mohammad & Ghasemi, Amir & Koohshekan, Omid, 2020. "The economic evaluation of establishing a plant for producing biodiesel from edible oil wastes in oil-rich countries: Case study Iran," Energy, Elsevier, vol. 213(C).
    18. Bharathiraja, B. & Chakravarthy, M. & Ranjith Kumar, R. & Yogendran, D. & Yuvaraj, D. & Jayamuthunagai, J. & Praveen Kumar, R. & Palani, S., 2015. "Aquatic biomass (algae) as a future feed stock for bio-refineries: A review on cultivation, processing and products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 634-653.
    19. Mandolesi de Araújo, Carlos Daniel & de Andrade, Claudia Cristina & de Souza e Silva, Erika & Dupas, Francisco Antonio, 2013. "Biodiesel production from used cooking oil: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 445-452.
    20. Thomassen, Gwenny & Van Dael, Miet & Lemmens, Bert & Van Passel, Steven, 2017. "A review of the sustainability of algal-based biorefineries: Towards an integrated assessment framework," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P2), pages 876-887.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:59:y:2016:i:c:p:887-894. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.