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Sodium modified fluorapatite as a sustainable solid bi-functional catalyst for biodiesel production from rapeseed oil

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  • Essamlali, Younes
  • Amadine, Othmane
  • Fihri, Aziz
  • Zahouily, Mohamed

Abstract

Transesterification of rapeseed oil with methanol was investigated over a heterogeneous catalysis system using sodium modified fluorapatite (Na/FAP) as a highly efficient, solid, bi-functional catalyst. Several parameters such as the impregnation ratio, calcination temperatures and catalyst loading were investigated and optimized for maximum biodiesel yield. The basic properties of the catalyst were estimated by phenol adsorption. The suitable reaction conditions for maximum biodiesel yield of 98% are the methanol to oil molar ratio of 10:1, temperature of 120 °C and reaction time of 8 h, with a 6 wt% of catalyst to oil weight ratio. The recycling studies have shown that the catalyst can be readily recovered and reused at least five consecutive cycles with significant loss of the activity. Several important physicochemical properties of the obtained biodiesel were evaluated and the results were compared with the standards for biodiesel specifications as described by EN14214. Results from waste cooking oil transesterification indicated that a FAME yield of 97% could be obtained by two-step transesterification process, thus giving rise to a potentially applicable possibility in biodiesel production from used cooking oil.

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  • Essamlali, Younes & Amadine, Othmane & Fihri, Aziz & Zahouily, Mohamed, 2019. "Sodium modified fluorapatite as a sustainable solid bi-functional catalyst for biodiesel production from rapeseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 1295-1307.
    • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:1295-1307
    DOI: 10.1016/j.renene.2018.08.103
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    1. Okoye, Patrick U. & Wang, Song & Khanday, Waheed Ahmad & Li, Sanxi & Tang, Tao & Zhang, Linnan, 2020. "Box-Behnken optimization of glycerol transesterification reaction to glycerol carbonate over calcined oil palm fuel ash derived catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2676-2687.
    2. Das, Bikashbindu & Mohanty, Kaustubha, 2019. "A review on advances in sustainable energy production through various catalytic processes by using catalysts derived from waste red mud," Renewable Energy, Elsevier, vol. 143(C), pages 1791-1811.
    3. Porcel, Meline Gurtat & de Mello, Bruna Tais Ferreira & Alves, Helton José & Schneider, Ricardo & da Silva, Camila & Borba, Carlos Eduardo, 2023. "Synthesis and characterization of KF/waste glass catalyst for use in the transesterification process under pressurized conditions," Renewable Energy, Elsevier, vol. 203(C), pages 56-67.
    4. de Freitas, Flávio A. & Mendonça, Igor R.S. & Barros, Silma de S. & Pessoa Jr., Wanison G.A. & Sá, Ingrity S.C. & Gato, Larissa B. & Silva, Edson P. & Farias, Marco A.S. & Nobre, Francisco X. & Maia, , 2022. "Biodiesel production from tucumã (Astrocaryum aculeatum Meyer) almond oil applying the electrolytic paste of spent batteries as a catalyst," Renewable Energy, Elsevier, vol. 191(C), pages 919-931.

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