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Biodiesel synthesis from Mesua ferrea oil using waste shell derived carbon catalyst

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  • Bora, Akash Pratim
  • Dhawane, Sumit H.
  • Anupam, Kumar
  • Halder, Gopinath

Abstract

The present study investigates the feasibility of synthesis of environmentally benign heterogeneous carbonaceous catalyst and biodiesel production from a single source i.e. Mesua ferrea Linn (MFL) seeds. The study primarily focuses on the optimisation of biodiesel synthesis process considering four parameters viz. reaction time, temperature, catalyst loading and methanol to oil ratio (M/O). The parametric influence on the free fatty acid (FFA) conversion has been studied to evaluate the most significant parameters. The contribution factor and analysis of variance results reveal that temperature is the most significant parameter influencing the FFA conversion followed by reaction time and catalyst content. The optimum conditions observed for maximum FFA conversion of 95.57% were: temperature 55 °C, time 2 h, catalyst content 10 wt% and M/O 6:1. The physico-chemical properties of the produced Mesua ferrea oil methyl ester (MFOME) were analysed following ASTM standard methods and found to be within limit; and compatible with the conventional diesel. Thus, the study suggests that the MFL seeds could be a promising source for the synthesis of an effective heterogeneous catalyst; and eco-friendly energy efficient sustainable fuel through the concept of green chemistry by converting waste into valuable commodity towards mitigation of increased energy demand.

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  • Bora, Akash Pratim & Dhawane, Sumit H. & Anupam, Kumar & Halder, Gopinath, 2018. "Biodiesel synthesis from Mesua ferrea oil using waste shell derived carbon catalyst," Renewable Energy, Elsevier, vol. 121(C), pages 195-204.
    • Handle: RePEc:eee:renene:v:121:y:2018:i:c:p:195-204
    DOI: 10.1016/j.renene.2018.01.036
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    References listed on IDEAS

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    2. Bora, Akash Pratim & Konda, Lutukurthi D.N.V.V. & Pasupuleti, Srinivas & Durbha, Krishna Sandilya, 2022. "Synthesis of MgO/MgSO4 nanocatalyst by thiourea–nitrate solution combustion for biodiesel production from waste cooking oil," Renewable Energy, Elsevier, vol. 190(C), pages 474-486.
    3. Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.
    4. Gohain, Minakshi & Bardhan, Pritam & Laskar, Khairujjaman & Sarmah, Saswati & Mandal, Manabendra & Bora, Utpal & Chandra Kalita, Mohan & Goud, Vaibhav Vasant & Deka, Dhanapati, 2020. "Rhodotorula mucilaginosa: A source of heterogeneous catalyst for biodiesel production from yeast single cell oil and waste cooking oil," Renewable Energy, Elsevier, vol. 160(C), pages 220-230.

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