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Biodiesel production by esterification of oleic acid with short-chain alcohols under ultrasonic irradiation condition

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  • Hanh, Hoang Duc
  • Dong, Nguyen The
  • Okitsu, Kenji
  • Nishimura, Rokuro
  • Maeda, Yasuaki

Abstract

Production of fatty acid ethyl ester (FAEE) from oleic acid (FFA) with short-chain alcohols (ethanol, propanol, and butanol) under ultrasonic irradiation was investigated in this work. Batch esterification of oleic acid was carried out to study the effect of: test temperatures of 10–60°C, molar ratios of alcohol to oleic acid of 1:1–10:1, quantity of catalysts of 0.5–10% (wt of sulfuric acid/wt of oleic acid) and irradiation times of 10h. The optimum condition for the esterification process was molar ratio of alcohol to oleic acid at 3:1 with 5wt% of H2SO4 at 60°C with an irradiation time of 2h.

Suggested Citation

  • Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production by esterification of oleic acid with short-chain alcohols under ultrasonic irradiation condition," Renewable Energy, Elsevier, vol. 34(3), pages 780-783.
    • Handle: RePEc:eee:renene:v:34:y:2009:i:3:p:780-783
    DOI: 10.1016/j.renene.2008.04.001
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    1. Hanh, Hoang Duc & Dong, Nguyen The & Okitsu, Kenji & Nishimura, Rokuro & Maeda, Yasuaki, 2009. "Biodiesel production through transesterification of triolein with various alcohols in an ultrasonic field," Renewable Energy, Elsevier, vol. 34(3), pages 766-768.
    2. Srivastava, Anjana & Prasad, Ram, 2000. "Triglycerides-based diesel fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(2), pages 111-133, June.
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    2. Veljković, Vlada B. & Avramović, Jelena M. & Stamenković, Olivera S., 2012. "Biodiesel production by ultrasound-assisted transesterification: State of the art and the perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(2), pages 1193-1209.
    3. Naderloo, Leila & Javadikia, Hossein & Mostafaei, Mostafa, 2017. "Modeling the energy ratio and productivity of biodiesel with different reactor dimensions and ultrasonic power using ANFIS," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 56-64.
    4. Kanjaikaew, Utaiwan & Tongurai, Chakrit & Chongkhong, Sininart & Prasertsit, Kulchanat, 2018. "Two-step esterification of palm fatty acid distillate in ethyl ester production: Optimization and sensitivity analysis," Renewable Energy, Elsevier, vol. 119(C), pages 336-344.
    5. Motasemi, F. & Ani, F.N., 2012. "A review on microwave-assisted production of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4719-4733.
    6. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat Teong & Khayoon, Muataz Sh., 2012. "Intensification of biodiesel production via ultrasonic-assisted process: A critical review on fundamentals and recent development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4574-4587.
    7. Barros, Suellen D.T. & Coelho, Aline V. & Lachter, Elizabeth R. & San Gil, Rosane A.S. & Dahmouche, Karim & Pais da Silva, Maria Isabel & Souza, Andrea L.F., 2013. "Esterification of lauric acid with butanol over mesoporous materials," Renewable Energy, Elsevier, vol. 50(C), pages 585-589.
    8. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    9. Soumaya Bouguerra Neji & Mahmoud Trabelsi & Mohamed H. Frikha, 2009. "Esterification of Fatty Acids with Short-Chain Alcohols over Commercial Acid Clays in a Semi-Continuous Reactor," Energies, MDPI, vol. 2(4), pages 1-11, November.
    10. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    11. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.

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