IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v241y2025ics0960148124023735.html

Co-catalytic pyrolysis of industrial hemp stem with rubber seed oil under calcined copper slag based on kinetic and thermodynamic

Author

Listed:
  • Du, Jinlong
  • Hu, Jianhang
  • Yang, Shiliang
  • Liu, Huili
  • Wang, Hua
  • Yang, Guiyan

Abstract

This work investigates the in situ co-catalytic pyrolysis of industrial hemp stem (IHS) with rubber seed oil (RSO) under calcined copper slag (CS). Evaluation of thermodynamics, kinetic, gases and pyrolysis oil release guide the design of pyrolysis reactors and the optimization of reaction conditions for catalytic pyrolysis, facilitating high-value disposal of biomass wastes. The catalytic pyrolysis kinetics of pseudo hemicellulose, pseudo cellulose, pseudo triglycerides and pseudo lignin are studied and the Eα are 134.47, 180.39, 183.12 and 291.70 kJ/mol respectively. TG-FTIR results indicate that the gaseous products consist mainly of C2 gas, CH4, CO2 and volatile small molecules containing C=O functional groups (such as acids and aldehydes). Pyrolysis oil from the co-catalytic pyrolysis of sample contain mainly phenolics, oxy-compounds (OCs), alkane, alkene and monocyclic aromatic hydrocarbons (MAHs). Phenolics are mainly produced by lignin cleavage. Besides, the unstable intermediates formed by thermal cracking are broken, dehydrated and recombined to form ketones and alcohols. This work can provide guidance on the harmless and resource utilization of waste copper slag as well as the pyrolysis upgrading of biomass to produce high value-added products.

Suggested Citation

  • Du, Jinlong & Hu, Jianhang & Yang, Shiliang & Liu, Huili & Wang, Hua & Yang, Guiyan, 2025. "Co-catalytic pyrolysis of industrial hemp stem with rubber seed oil under calcined copper slag based on kinetic and thermodynamic," Renewable Energy, Elsevier, vol. 241(C).
    • Handle: RePEc:eee:renene:v:241:y:2025:i:c:s0960148124023735
    DOI: 10.1016/j.renene.2024.122305
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148124023735
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2024.122305?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Zhang, Chenting & Chao, Li & Zhang, Zhanming & Zhang, Lijun & Li, Qingyin & Fan, Huailin & Zhang, Shu & Liu, Qing & Qiao, Yingyun & Tian, Yuanyu & Wang, Yi & Hu, Xun, 2021. "Pyrolysis of cellulose: Evolution of functionalities and structure of bio-char versus temperature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    2. Li, Ruochen & Meng, Tianxin & Song, Gongxiang & Huang, Dexin & Hu, Song & Jiang, Long & Xu, Jun & Wang, Yi & Su, Sheng & Xiang, Jun, 2024. "A GIS-based assessment of the carbon emission reduction potential of the solar-enhanced char-cycling biomass pyrolysis process in China," Renewable Energy, Elsevier, vol. 237(PA).
    3. Hu, Lin & Xu, Mei-Ling & Wei, Xian-Yong & Yu, Changlin & Wu, Jingcheng & Wang, Haiyong & Liu, Tianlong, 2024. "Effect of ethanolysis on the structure evolution, pyrolysis kinetics, and volatile products of waste poplar sawdust," Energy, Elsevier, vol. 305(C).
    4. Magdziarz, Aneta & Jerzak, Wojciech & Wądrzyk, Mariusz & Sieradzka, Małgorzata, 2024. "Benefits from co-pyrolysis of biomass and refuse derived fuel for biofuels production: Experimental investigations," Renewable Energy, Elsevier, vol. 230(C).
    5. Bhowmick, Sundipan & Das, Swati & Kumar, Ravi Ranjan & Ghangrekar, Makarand M. & Sen, Ramkrishna, 2024. "A simple synthesis of bio-based cathode catalyst of microbial fuel cell with bio-oil recovery through pyrolysis of defatted yeast-biomass," Renewable Energy, Elsevier, vol. 237(PC).
    6. Jiang, Li-Qun & Fang, Zhen & Zhao, Zeng-Li & Zheng, An-Qing & Wang, Xiao-Bo & Li, Hai-Bin, 2019. "Levoglucosan and its hydrolysates via fast pyrolysis of lignocellulose for microbial biofuels: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 105(C), pages 215-229.
    7. Yang, Yantao & Jiang, Mingshen & Song, Lei & Shen, Yilin & Lei, Tingzhou & Cai, Junmeng, 2024. "Systematical analysis and application of distributed activation energy model (DAEM) with Weibull distribution for pyrolysis kinetics of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 237(PA).
    8. Yuan, Xinsong & He, Tao & Cao, Hongliang & Yuan, Qiaoxia, 2017. "Cattle manure pyrolysis process: Kinetic and thermodynamic analysis with isoconversional methods," Renewable Energy, Elsevier, vol. 107(C), pages 489-496.
    9. Tariq, Rumaisa & Mohd Zaifullizan, Yasmin & Salema, Arshad Adam & Abdulatif, Atiqah & Ken, Loke Shun, 2022. "Co-pyrolysis and co-combustion of orange peel and biomass blends: Kinetics, thermodynamic, and ANN application," Renewable Energy, Elsevier, vol. 198(C), pages 399-414.
    10. Nawaz, Ahmad & Razzak, Shaikh Abdur, 2024. "Co-pyrolysis of biomass and different plastic waste to reduce hazardous waste and subsequent production of energy products: A review on advancement, synergies, and future prospects," Renewable Energy, Elsevier, vol. 224(C).
    11. Anshu, Kumari & Kenttämaa, Hilkka I. & Thengane, Sonal K., 2024. "A comprehensive review on co-pyrolysis of lignocellulosic biomass and polystyrene," Renewable and Sustainable Energy Reviews, Elsevier, vol. 205(C).
    12. Bharti, Bhawana & Kandpal, Saurav & Sawarkar, Ashish N. & Patle, Dipesh S., 2024. "Holistic approach for sequential transesterification and pyrolysis of microalgal biomass: Kinetic and thermodynamic analysis of pyrolysis using model-free and model-based approaches," Renewable Energy, Elsevier, vol. 235(C).
    13. Lee, Hyung Won & Kim, Young-Min & Jae, Jungho & Lee, Soo Min & Jung, Sang-Chul & Park, Young-Kwon, 2019. "The use of calcined seashell for the prevention of char foaming/agglomeration and the production of high-quality oil during the pyrolysis of lignin," Renewable Energy, Elsevier, vol. 144(C), pages 147-152.
    14. Ong, Hwai Chyuan & Chen, Wei-Hsin & Farooq, Abid & Gan, Yong Yang & Lee, Keat Teong & Ashokkumar, Veeramuthu, 2019. "Catalytic thermochemical conversion of biomass for biofuel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    15. Liborio, Denisson O. & Arias, Santiago & Mumbach, Guilherme D. & Alves, José Luiz F. & da Silva, Jean C.G. & Silva, Jose Marcos F. & Frety, Roger & Pacheco, Jose Geraldo A., 2024. "Evaluating black wattle bark industrial residue as a new feedstock for bioenergy via pyrolysis and multicomponent kinetic modeling," Renewable Energy, Elsevier, vol. 228(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Dong, Xinjiang & Wang, Junzhi & Yang, Li & Liu, Fang & Zuo, Zongliang, 2025. "Mechanistic insights into copper slag as a thermal carrier and catalyst in lignite steam gasification: Experimental and DFT study," Energy, Elsevier, vol. 335(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fan, Yongsheng & Qin, Changsheng & Zhao, Keyu & Xiong, Yonglian & Shi, Yunxi, 2025. "Conversion of lignin with polystyrene into high-value aromatics through co-pyrolysis and post-plasma refining," Energy, Elsevier, vol. 318(C).
    2. Du, Jinlong & Hu, Jianhang & Tan, Cheng & Yang, Shiliang & Liu, Huili & Wang, Hua, 2025. "Comprehensive investigation of co-pyrolysis of rubber seed oil and industrial hemp stems: thermogravimetric analysis based on artificial neural networks; synergistic effect and pyrolysis product," Energy, Elsevier, vol. 330(C).
    3. Haiyu Meng & Heng Yang & Zhiqiang Wu & Danting Li & Zhe Wang & Dongqi Wang & Hui Wang & Huaien Li & Jiake Li, 2024. "Co-Pyrolysis of Mushroom Residue Blended with Pine Sawdust/Wheat Straw for Sustainable Utilization of Biomass Wastes: Thermal Characteristics, Kinetic/Thermodynamic Analysis, and Structure Evolution of Co-Pyrolytic Char," Sustainability, MDPI, vol. 16(15), pages 1-30, August.
    4. Li, Fenghai & Zhao, Chaoyue & Guo, Qianqian & Li, Yang & Fan, Hongli & Guo, Mingxi & Wu, Lishun & Huang, Jiejie & Fang, Yitian, 2020. "Exploration in ash-deposition (AD) behavior modification of low-rank coal by manure addition," Energy, Elsevier, vol. 208(C).
    5. Jayne Lois San Juan & Carlo James Caligan & Maria Mikayla Garcia & Jericho Mitra & Andres Philip Mayol & Charlle Sy & Aristotle Ubando & Alvin Culaba, 2020. "Multi-Objective Optimization of an Integrated Algal and Sludge-Based Bioenergy Park and Wastewater Treatment System," Sustainability, MDPI, vol. 12(18), pages 1-22, September.
    6. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    7. Sahoo, Abhisek & Kumar, Sachin & Mohanty, Kaustubha, 2021. "Kinetic and thermodynamic analysis of Putranjiva roxburghii (putranjiva) and Cassia fistula (amaltas) non-edible oilseeds using thermogravimetric analyzer," Renewable Energy, Elsevier, vol. 165(P1), pages 261-277.
    8. Ferraz de Campos, Victor Arruda & Silva, Valter Bruno & Cardoso, João Sousa & Brito, Paulo S. & Tuna, Celso Eduardo & Silveira, José Luz, 2021. "A review of waste management in Brazil and Portugal: Waste-to-energy as pathway for sustainable development," Renewable Energy, Elsevier, vol. 178(C), pages 802-820.
    9. Abbaspour, Nastaran & Szlęk, Andrzej & Winter, Franz & Korus, Agnieszka, 2025. "Kinetics of model tar decomposition over activated biochar from a heavy metal-contaminated area," Renewable Energy, Elsevier, vol. 253(C).
    10. Jiang, Chunlong & Lin, Qizhao & Wang, Chengxin & Jiang, Xuedan & Bi, Haobo & Bao, Lin, 2020. "Experimental study of the ignition and combustion characteristics of cattle manure under different environmental conditions," Energy, Elsevier, vol. 197(C).
    11. Muhammad U. Hanif & Mohammed Zwawi & Sergio C. Capareda & Hamid Iqbal & Mohammed Algarni & Bassem F. Felemban & Ali Bahadar & Adeel Waqas, 2020. "Product Distribution and Characteristics of Pyrolyzing Microalgae ( Nannochloropsis oculata ), Cotton Gin Trash, and Cattle Manure as a Cobiomass," Energies, MDPI, vol. 13(4), pages 1-10, February.
    12. Li, Chao & Li, Yuannian & Jiang, Yuchen & Zhang, Lijun & Zhang, Shu & Ding, Kuan & Li, Bin & Wang, Shuang & Hu, Xun, 2023. "Staged pyrolysis of biomass to probe the evolution of fractions of bio-oil," Energy, Elsevier, vol. 263(PD).
    13. Ge, Shengbo & Yek, Peter Nai Yuh & Cheng, Yoke Wang & Xia, Changlei & Wan Mahari, Wan Adibah & Liew, Rock Keey & Peng, Wanxi & Yuan, Tong-Qi & Tabatabaei, Meisam & Aghbashlo, Mortaza & Sonne, Christia, 2021. "Progress in microwave pyrolysis conversion of agricultural waste to value-added biofuels: A batch to continuous approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    14. Aragón-Briceño, C.I. & Pozarlik, A.K. & Bramer, E.A. & Niedzwiecki, Lukasz & Pawlak-Kruczek, H. & Brem, G., 2021. "Hydrothermal carbonization of wet biomass from nitrogen and phosphorus approach: A review," Renewable Energy, Elsevier, vol. 171(C), pages 401-415.
    15. Li, Jiawei & Fan, Subo & Zhang, Xuyang & Chen, Zhichao & Qiao, Yanyu & Yuan, Zhenhua & Zeng, Lingyan & Li, Zhengqi, 2022. "Physicochemical structure, combustion characteristics and SiO2 properties of entrained flow gasification ash," Energy, Elsevier, vol. 251(C).
    16. Mayank Patel & Nick Hill & Charles A. Mullen & Sampath Gunukula & William J. DeSisto, 2020. "Fast Pyrolysis of Lignin Pretreated with Magnesium Formate and Magnesium Hydroxide," Energies, MDPI, vol. 13(19), pages 1-10, September.
    17. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    18. Luo, Miaoling & Shao, Shanshan & Cao, Yu & Li, Xiaohua & Wu, Shiliang, 2025. "A study on the characteristics and kinetic of co-catalytic pyrolysis with rape straw and ABS waste plastics," Renewable Energy, Elsevier, vol. 242(C).
    19. Anna Trubetskaya, 2022. "Reactivity Effects of Inorganic Content in Biomass Gasification: A Review," Energies, MDPI, vol. 15(9), pages 1-36, April.
    20. Liu, Hui & Liu, Jingyong & Huang, Hongyi & Evrendilek, Fatih & Wen, Shaoting & Li, Weixin, 2021. "Optimizing bioenergy and by-product outputs from durian shell pyrolysis," Renewable Energy, Elsevier, vol. 164(C), pages 407-418.

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:241:y:2025:i:c:s0960148124023735. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.