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Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization–Treated pulp and paper mill sludge

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  • Wang, Shule
  • Wen, Yuming
  • Hammarström, Henry
  • Jönsson, Pär Göran
  • Yang, Weihong

Abstract

Organic-rich pulp and paper mill sludge (PPMS) has the potential to become a renewable carbon source for producing alternatives to fossil-based product. In this work, PPMS treated by hydrothermal carbonization (HTC) was investigated based on its pyrolysis properties. The pyrolytic mechanism, kinetics data and product of the sample were studied using TG as well as pyrolysis tests in Py-GC/MS and a bench-scale reactor at 450, 550, and 650 °C. The results show that the thermal decomposition of feedstock is a two-stage reaction. The mean activation energy of the pyrolysis of HTC treated PPMS was estimated as 233.08 kJ/mol, which is higher than that of the pyrolysis of paper sludge reported before. The changes in enthalpies, entropies and Gibbs free energies from the reactants to the activated complex were estimated. The concentration of monocyclic aromatic hydrocarbons in the derived organic liquid fraction shows a positive correlation with the pyrolysis temperature. At 550 °C, the organic liquid fraction reached its highest yield at 13.7% with an oxygen level of 10.7 wt% and a higher heating value of 35.9 MJ/kg. The pyrolytic chars show that a molar ratio of O:C is less than 0.2, which shows potential for use as a carbon sink.

Suggested Citation

  • Wang, Shule & Wen, Yuming & Hammarström, Henry & Jönsson, Pär Göran & Yang, Weihong, 2021. "Pyrolysis behaviour, kinetics and thermodynamic data of hydrothermal carbonization–Treated pulp and paper mill sludge," Renewable Energy, Elsevier, vol. 177(C), pages 1282-1292.
    • Handle: RePEc:eee:renene:v:177:y:2021:i:c:p:1282-1292
    DOI: 10.1016/j.renene.2021.06.027
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    1. Slopiecka, Katarzyna & Bartocci, Pietro & Fantozzi, Francesco, 2012. "Thermogravimetric analysis and kinetic study of poplar wood pyrolysis," Applied Energy, Elsevier, vol. 97(C), pages 491-497.
    2. Persson, H. & Han, T. & Sandström, L. & Xia, W. & Evangelopoulos, P. & Yang, W., 2018. "Fractionation of liquid products from pyrolysis of lignocellulosic biomass by stepwise thermal treatment," Energy, Elsevier, vol. 154(C), pages 346-351.
    3. Naqvi, Salman Raza & Tariq, Rumaisa & Hameed, Zeeshan & Ali, Imtiaz & Naqvi, Muhammad & Chen, Wei-Hsin & Ceylan, Selim & Rashid, Harith & Ahmad, Junaid & Taqvi, Syed A. & Shahbaz, Muhammad, 2019. "Pyrolysis of high ash sewage sludge: Kinetics and thermodynamic analysis using Coats-Redfern method," Renewable Energy, Elsevier, vol. 131(C), pages 854-860.
    4. Bach, Quang-Vu & Skreiberg, Øyvind, 2016. "Upgrading biomass fuels via wet torrefaction: A review and comparison with dry torrefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 665-677.
    5. Lou, Rui & Wu, Shubin & Lv, Gaojin & Yang, Qing, 2012. "Energy and resource utilization of deinking sludge pyrolysis," Applied Energy, Elsevier, vol. 90(1), pages 46-50.
    6. Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    7. Ali Mohammadi & Maria Sandberg & G. Venkatesh & Samieh Eskandari & Tommy Dalgaard & Stephen Joseph & Karin Granström, 2019. "Environmental analysis of producing biochar and energy recovery from pulp and paper mill biosludge," Journal of Industrial Ecology, Yale University, vol. 23(5), pages 1039-1051, October.
    8. Yu, Yong Ho & Kim, Sang Done & Lee, Jong Min & Lee, Keun Hoo, 2002. "Kinetic studies of dehydration, pyrolysis and combustion of paper sludge," Energy, Elsevier, vol. 27(5), pages 457-469.
    9. Gao, Ying & Wang, Xian-Hua & Yang, Hai-Ping & Chen, Han-Ping, 2012. "Characterization of products from hydrothermal treatments of cellulose," Energy, Elsevier, vol. 42(1), pages 457-465.
    10. Sophonrat, Nanta & Sandström, Linda & Zaini, Ilman Nuran & Yang, Weihong, 2018. "Stepwise pyrolysis of mixed plastics and paper for separation of oxygenated and hydrocarbon condensates," Applied Energy, Elsevier, vol. 229(C), pages 314-325.
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    4. Jerzak, Wojciech & Wądrzyk, Mariusz & Kalemba-Rec, Izabela & Bieniek, Artur & Magdziarz, Aneta, 2023. "Release of chlorine during oat straw pyrolysis doped with char and ammonium chloride," Renewable Energy, Elsevier, vol. 215(C).
    5. Zhang, Jun & Li, Chengyu & Yuan, Haoran & Chen, Yong, 2022. "Enhancement of aromatics production via cellulose fast pyrolysis over Ru modified hierarchical zeolites," Renewable Energy, Elsevier, vol. 184(C), pages 280-290.
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