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Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment

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  • Shahbeig, Hossein
  • Nosrati, Mohsen

Abstract

In this study, a comprehensive investigation was conducted to use municipal sewage sludge (MSS) as a promising feedstock for bioenergy production via pyrolysis process. Using thermogravimetric analysis (TGA), MSS was subjected to thermal decomposition experiments at four different heating rates of 5, 10, 30 and 50 °C/min. TGA curves were divided into three distinctive stages, namely drying zone (T ≤ 200 °C), active pyrolysis zone (200 < T < 600 °C), and char decomposition zone (T ≥ 600 °C). Moreover, the data were used to analyze thermo-kinetic parameters through Flynn-Wall-Ozawa (FWO), Kissenger-Akahira-Sunose (KAS), and Starink methods, where the average values of Ea (126.62–136.92 kJ/mol), Gibbs free energy (159.19–159.61 kJ/mol), and calculated high heating value (HHV, 16.47 ± 0.03 MJ/kg) showed the considerable bioenergy potential of the low-cost biomass. The low difference between Ea and ΔH (~ 5 kJ/mol) showed that product formation was favorable during pyrolysis. In addition, for the first time, the comparative study of the results predicted from support vector regression (SVR) model and the experimental data, showed a satisfactory agreement (R2 > 0.9999) and accurate results regarding different train-test data categories. Further employed was Pyrolysis–Gas Chromatography/Mass Spectroscopy (Py-GC/MS) at 700 °C to characterize the potential chemical products, which indicated the presence of a range of aromatic and aliphatic hydrocarbons, nitrogen-containing compounds, alcohol, furans and sulfur compounds. Finally, three alternative scenarios associated with the planned project were presented and techno-socio-economic assessment (TSEA) of the alternative scenarios were evaluated, for the first time, by means of economic indexes and considering social aspects. Net present value (NPV) of all alternative scenarios of the pyrolysis plant over the 20-year plant lifetime was positive compared to the base case, indicating that the project was feasible. Sensitivity analysis of the optimistic scenario showed that the profitability of pyrolysis plant was highly dependent on bio-oil selling price and total production cost.

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  • Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    • Handle: RePEc:eee:rensus:v:119:y:2020:i:c:s1364032119307750
    DOI: 10.1016/j.rser.2019.109567
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