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The effect of the reaction equilibrium on the kinetics of gas-solid reactions — A non-parametric modeling study

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  • Birkelbach, Felix
  • Deutsch, Markus
  • Werner, Andreas

Abstract

The viability of thermochemical energy storage for a given application is often determined by the reaction kinetics under process conditions. For high exergetic efficiency the process needs to operate in close proximity to the reaction equilibrium. Thus, accurate kinetic models that include the effect of the reaction equilibrium are required.

Suggested Citation

  • Birkelbach, Felix & Deutsch, Markus & Werner, Andreas, 2020. "The effect of the reaction equilibrium on the kinetics of gas-solid reactions — A non-parametric modeling study," Renewable Energy, Elsevier, vol. 152(C), pages 300-307.
    • Handle: RePEc:eee:renene:v:152:y:2020:i:c:p:300-307
    DOI: 10.1016/j.renene.2020.01.033
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    References listed on IDEAS

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    1. Saman Setoodeh Jahromy & Felix Birkelbach & Christian Jordan & Clemens Huber & Michael Harasek & Andreas Werner & Franz Winter, 2019. "Impact of Partial Pressure, Conversion, and Temperature on the Oxidation Reaction Kinetics of Cu 2 O to CuO in Thermochemical Energy Storage," Energies, MDPI, vol. 12(3), pages 1-15, February.
    2. Donkers, P.A.J. & Sögütoglu, L.C. & Huinink, H.P. & Fischer, H.R. & Adan, O.C.G., 2017. "A review of salt hydrates for seasonal heat storage in domestic applications," Applied Energy, Elsevier, vol. 199(C), pages 45-68.
    3. Kato, Y. & Sasaki, Y. & Yoshizawa, Y., 2005. "Magnesium oxide/water chemical heat pump to enhance energy utilization of a cogeneration system," Energy, Elsevier, vol. 30(11), pages 2144-2155.
    4. Knoll, Christian & Müller, Danny & Artner, Werner & Welch, Jan M. & Werner, Andreas & Harasek, Michael & Weinberger, Peter, 2017. "Probing cycle stability and reversibility in thermochemical energy storage – CaC2O4·H2O as perfect match?," Applied Energy, Elsevier, vol. 187(C), pages 1-9.
    5. Solé, Aran & Martorell, Ingrid & Cabeza, Luisa F., 2015. "State of the art on gas–solid thermochemical energy storage systems and reactors for building applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 47(C), pages 386-398.
    6. Clayton, Christopher K. & Whitty, Kevin J., 2014. "Measurement and modeling of decomposition kinetics for copper oxide-based chemical looping with oxygen uncoupling," Applied Energy, Elsevier, vol. 116(C), pages 416-423.
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    1. Cabeza, Luisa F. & de Gracia, Alvaro & Zsembinszki, Gabriel & Borri, Emiliano, 2021. "Perspectives on thermal energy storage research," Energy, Elsevier, vol. 231(C).
    2. Stengler, Jana & Bürger, Inga & Linder, Marc, 2020. "Thermodynamic and kinetic investigations of the SrBr2 hydration and dehydration reactions for thermochemical energy storage and heat transformation," Applied Energy, Elsevier, vol. 277(C).

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