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Probing cycle stability and reversibility in thermochemical energy storage – CaC2O4·H2O as perfect match?

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  • Knoll, Christian
  • Müller, Danny
  • Artner, Werner
  • Welch, Jan M.
  • Werner, Andreas
  • Harasek, Michael
  • Weinberger, Peter

Abstract

The dehydration and subsequent rehydration of calcium oxalate monohydrate has yet to find application in thermochemical energy storage. Unlike for many other salt hydrates, complete reversibility of the dehydration-rehydration reaction was observed. Additionally, it was found that the rehydration temperature is strongly affected by the water vapour concentration: Full reversibility is not only achieved at room-temperature, but, depending on the water vapour concentration, at up to 200°C. This allows isothermal switching of the material between charging and discharging by a change of the H2O-partial pressure. Cycle stability of the material was tested by a long-term stress experiment involving 100 charging and discharging cycles. No signs of material fatigue or reactivity loss were found. In-situ powder X-ray diffraction showed complete rehydration of the material within 300s. The experimental findings indicate that the CaC2O4·H2O/CaC2O4 system is perfectly suited for technical application as a thermochemical energy storage medium.

Suggested Citation

  • Knoll, Christian & Müller, Danny & Artner, Werner & Welch, Jan M. & Werner, Andreas & Harasek, Michael & Weinberger, Peter, 2017. "Probing cycle stability and reversibility in thermochemical energy storage – CaC2O4·H2O as perfect match?," Applied Energy, Elsevier, vol. 187(C), pages 1-9.
    • Handle: RePEc:eee:appene:v:187:y:2017:i:c:p:1-9
    DOI: 10.1016/j.apenergy.2016.11.053
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    References listed on IDEAS

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    Cited by:

    1. Stengler, Jana & Linder, Marc, 2020. "Thermal energy storage combined with a temperature boost: An underestimated feature of thermochemical systems," Applied Energy, Elsevier, vol. 262(C).
    2. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.
    3. Donkers, P.A.J. & Sögütoglu, L.C. & Huinink, H.P. & Fischer, H.R. & Adan, O.C.G., 2017. "A review of salt hydrates for seasonal heat storage in domestic applications," Applied Energy, Elsevier, vol. 199(C), pages 45-68.
    4. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    5. Birkelbach, Felix & Deutsch, Markus & Werner, Andreas, 2020. "The effect of the reaction equilibrium on the kinetics of gas-solid reactions — A non-parametric modeling study," Renewable Energy, Elsevier, vol. 152(C), pages 300-307.

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