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Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat

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  • Shkatulov, Alexandr
  • Ryu, Junichi
  • Kato, Yukitaka
  • Aristov, Yury

Abstract

New composite material for storage and transformation of heat of a temperature range of 250–350 °C has been synthesized by precipitation of magnesium hydroxide Mg(OH)2 in the pores of expanded vermiculite. The hydroxide is stabilized inside the pores as irregular sticks of 1–3 μm in size across flats of the base and about 30 μm in length. The temperature of decomposition of the confined hydroxide is found to be by some 50 °C lower than that of the bulk one as revealed by both TG and DSC techniques. One possible reason of this finding is a significant acceleration of the decomposition reaction of the confined hydroxide as revealed from comparative kinetic tests in the temperature range of 260–300 °C. The maximal heat storage capacity is 540 kJ per kg of the composite with the hydroxide content of 67.4 mass. % that is larger than the heat of melting for promising phase change materials. Further study of the new composite material for storage of middle temperature heat could be of high interest to find out reasons of the decomposition temperature reduction in order to use this effect for harmonizing the reaction temperature with the temperature level of heat to be stored.

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  • Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:1028-1034
    DOI: 10.1016/j.energy.2012.04.045
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    1. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    2. Tian, Y. & Zhao, C.Y., 2011. "A numerical investigation of heat transfer in phase change materials (PCMs) embedded in porous metals," Energy, Elsevier, vol. 36(9), pages 5539-5546.
    3. Kato, Y. & Sasaki, Y. & Yoshizawa, Y., 2005. "Magnesium oxide/water chemical heat pump to enhance energy utilization of a cogeneration system," Energy, Elsevier, vol. 30(11), pages 2144-2155.
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    8. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.
    9. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).
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    14. Jiang, Feng & Zhang, Lingling & She, Xiaohui & Li, Chuan & Cang, Daqiang & Liu, Xianglei & Xuan, Yimin & Ding, Yulong, 2020. "Skeleton materials for shape-stabilization of high temperature salts based phase change materials: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    15. Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    16. Miliozzi, Adio & Chieruzzi, Manila & Torre, Luigi, 2019. "Experimental investigation of a cementitious heat storage medium incorporating a solar salt/diatomite composite phase change material," Applied Energy, Elsevier, vol. 250(C), pages 1023-1035.
    17. Jae Yong Lee & Taesu Yim & Hyouck Ju Kim & Sungkook Hong & Doo Won Seo & Hong Soo Kim, 2019. "Investigation on Long Term Operation of Thermochemical Heat Storage with MgO-Based Composite Honeycombs," Energies, MDPI, vol. 12(7), pages 1-18, April.
    18. Taesu Yim & Hong Soo Kim & Jae Yong Lee, 2018. "Cyclic Assessment of Magnesium Oxide with Additives as a Thermochemical Material to Improve the Mechanical Strength and Chemical Reaction," Energies, MDPI, vol. 11(9), pages 1-15, September.
    19. Emanuela Mastronardo & Yukitaka Kato & Lucio Bonaccorsi & Elpida Piperopoulos & Candida Milone, 2017. "Thermochemical Storage of Middle Temperature Wasted Heat by Functionalized C/Mg(OH) 2 Hybrid Materials," Energies, MDPI, vol. 10(1), pages 1-16, January.
    20. Yan, T. & Wang, R.Z. & Li, T.X., 2018. "Experimental investigation on thermochemical heat storage using manganese chloride/ammonia," Energy, Elsevier, vol. 143(C), pages 562-574.
    21. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    22. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
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