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Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps

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  • Mastronardo, E.
  • Bonaccorsi, L.
  • Kato, Y.
  • Piperopoulos, E.
  • Lanza, M.
  • Milone, C.

Abstract

Newly developed hybrid materials made of magnesium hydroxide and carbon nanotubes were proposed as heat storage medium for MgO/H2O/Mg(OH)2 chemical heat pumps. Samples were synthesized by deposition-precipitation method varying the Mg(OH)2 load (32–52wt.%) and the type of carbon nanotubes, pristine or functionalized. The performances of the synthesized materials were evaluated by thermogravimetric analysis, which simulates the chemical heat pump cycle. The presence of the carbonaceous material positively affected the reaction performances, so that the hybrid materials showed improved heat storage/output capacity and faster heat output rate compared to pure Mg(OH)2. The functionalization treatment and a proper Mg(OH)2 load were fundamental to better the dispersibility of Mg(OH)2 into the carbon nanotubes bundles which in turn enhanced the thermochemical performance of the active material, fully exploiting for the first time its maximum potential heat storage capacity, that is ∼1300kJ/kgMg(OH)2, thus bringing the development of this technology to a level closer to its industrial application.

Suggested Citation

  • Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.
    • Handle: RePEc:eee:appene:v:181:y:2016:i:c:p:232-243
    DOI: 10.1016/j.apenergy.2016.08.041
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    1. Forman, Clemens & Muritala, Ibrahim Kolawole & Pardemann, Robert & Meyer, Bernd, 2016. "Estimating the global waste heat potential," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1568-1579.
    2. Paskevicius, M. & Sheppard, D.A. & Williamson, K. & Buckley, C.E., 2015. "Metal hydride thermal heat storage prototype for concentrating solar thermal power," Energy, Elsevier, vol. 88(C), pages 469-477.
    3. Bauer, Thomas & Pfleger, Nicole & Breidenbach, Nils & Eck, Markus & Laing, Doerte & Kaesche, Stefanie, 2013. "Material aspects of Solar Salt for sensible heat storage," Applied Energy, Elsevier, vol. 111(C), pages 1114-1119.
    4. Brückner, Sarah & Liu, Selina & Miró, Laia & Radspieler, Michael & Cabeza, Luisa F. & Lävemann, Eberhard, 2015. "Industrial waste heat recovery technologies: An economic analysis of heat transformation technologies," Applied Energy, Elsevier, vol. 151(C), pages 157-167.
    5. Nagel, Thomas & Beckert, Steffen & Lehmann, Christoph & Gläser, Roger & Kolditz, Olaf, 2016. "Multi-physical continuum models of thermochemical heat storage and transformation in porous media and powder beds—A review," Applied Energy, Elsevier, vol. 178(C), pages 323-345.
    6. Zhang, P. & Ma, F. & Xiao, X., 2016. "Thermal energy storage and retrieval characteristics of a molten-salt latent heat thermal energy storage system," Applied Energy, Elsevier, vol. 173(C), pages 255-271.
    7. Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    8. Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    9. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Milone, C., 2016. "Efficiency improvement of heat storage materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 162(C), pages 31-39.
    10. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    11. Abedin, Ali Haji & Rosen, Marc A., 2012. "Assessment of a closed thermochemical energy storage using energy and exergy methods," Applied Energy, Elsevier, vol. 93(C), pages 18-23.
    12. Fais, Birgit & Sabio, Nagore & Strachan, Neil, 2016. "The critical role of the industrial sector in reaching long-term emission reduction, energy efficiency and renewable targets," Applied Energy, Elsevier, vol. 162(C), pages 699-712.
    13. Oluleye, Gbemi & Jobson, Megan & Smith, Robin & Perry, Simon J., 2016. "Evaluating the potential of process sites for waste heat recovery," Applied Energy, Elsevier, vol. 161(C), pages 627-646.
    14. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    15. Ma, Q. & Luo, L. & Wang, R.Z. & Sauce, G., 2009. "A review on transportation of heat energy over long distance: Exploratory development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1532-1540, August.
    16. Prieto, Cristina & Cooper, Patrick & Fernández, A. Inés & Cabeza, Luisa F., 2016. "Review of technology: Thermochemical energy storage for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 909-929.
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    3. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).
    4. Jae Yong Lee & Taesu Yim & Hyouck Ju Kim & Sungkook Hong & Doo Won Seo & Hong Soo Kim, 2019. "Investigation on Long Term Operation of Thermochemical Heat Storage with MgO-Based Composite Honeycombs," Energies, MDPI, vol. 12(7), pages 1-18, April.
    5. Taesu Yim & Hong Soo Kim & Jae Yong Lee, 2018. "Cyclic Assessment of Magnesium Oxide with Additives as a Thermochemical Material to Improve the Mechanical Strength and Chemical Reaction," Energies, MDPI, vol. 11(9), pages 1-15, September.
    6. Emanuela Mastronardo & Yukitaka Kato & Lucio Bonaccorsi & Elpida Piperopoulos & Candida Milone, 2017. "Thermochemical Storage of Middle Temperature Wasted Heat by Functionalized C/Mg(OH) 2 Hybrid Materials," Energies, MDPI, vol. 10(1), pages 1-16, January.
    7. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    8. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.

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