IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v146y2020icp280-296.html
   My bibliography  Save this article

Optimization and kinetic study of biodiesel production from Hydnocarpus wightiana oil and dairy waste scum using snail shell CaO nano catalyst

Author

Listed:
  • Krishnamurthy, K.N.
  • Sridhara, S.N.
  • Ananda Kumar, C.S.

Abstract

The present study is an effort to optimize the production of biodiesel from dairy scum and Hydnocarpus wightiana oil using Snail shell CaO nanocatalyst for transesterification. Response surface methodology is used to optimize the reaction parameter that affects the transesterification process for the biodiesel yield. The CaO nanocatalyst was characterized by powder X-ray diffraction, Scanning Electron Microscopy, Energy-Dispersive X-ray Spectroscopy, Brunauer-Emmett-Teller, Fourier Transformer Infrared Spectroscopy, Thermo Gravimetric/Differential Thermal Analysis and Atomic Force Microscopy. The maximum biodiesel yield for Scum Oil Methyl Ester and Hydnocarpus wightiana Oil Methyl Ester was (96.929%) and (98.93%) at the optimized condition: Methanol to oil molar ratio 12.7:1 and 12.4:1, catalyst dosage of 0.866 wt.% and 0.892 wt.%, reaction temperature 58.56°C and 61.6°C and reaction time 119.684 min and 145.154 min respectively. A comprehensive kinetic study for the transesterification reaction was performed at different temperatures (50-65°C) for the methanolysis of SO and HWO catalyzed by CaO nanoparticles. A pseudo-first order kinetic reaction was established and the activation energy (Ea) and frequency factor (A) for SO and HWO to be 67.21kJmol-1 & 5.182×108 min-1 & 73.15 kJmol-1 & 4.59×109 min-1 respectively. Recovered CaO nanocatalyst is reused for 5 times with substantial loss in biodiesel yield.

Suggested Citation

  • Krishnamurthy, K.N. & Sridhara, S.N. & Ananda Kumar, C.S., 2020. "Optimization and kinetic study of biodiesel production from Hydnocarpus wightiana oil and dairy waste scum using snail shell CaO nano catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 280-296.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:280-296
    DOI: 10.1016/j.renene.2019.06.161
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119310018
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.06.161?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hu, Shengyang & Guan, Yanping & Wang, Yun & Han, Heyou, 2011. "Nano-magnetic catalyst KF/CaO-Fe3O4 for biodiesel production," Applied Energy, Elsevier, vol. 88(8), pages 2685-2690, August.
    2. Feyzi, Mostafa & Norouzi, Leila, 2016. "Preparation and kinetic study of magnetic Ca/Fe3O4@SiO2 nanocatalysts for biodiesel production," Renewable Energy, Elsevier, vol. 94(C), pages 579-586.
    3. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    4. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
    5. Krishnamurthy, K.N. & Sridhara, S.N. & Ananda Kumar, C.S., 2018. "Synthesis and optimization of Hydnocarpus wightiana and dairy waste scum as feed stock for biodiesel production by using response surface methodology," Energy, Elsevier, vol. 153(C), pages 1073-1086.
    6. Veljković, Vlada B. & Stamenković, Olivera S. & Tasić, Marija B., 2014. "The wastewater treatment in the biodiesel production with alkali-catalyzed transesterification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 40-60.
    7. Tang, Ying & Meng, Mei & Zhang, Jie & Lu, Yong, 2011. "Efficient preparation of biodiesel from rapeseed oil over modified CaO," Applied Energy, Elsevier, vol. 88(8), pages 2735-2739, August.
    8. Kaur, Mandeep & Ali, Amjad, 2011. "Lithium ion impregnated calcium oxide as nano catalyst for the biodiesel production from karanja and jatropha oils," Renewable Energy, Elsevier, vol. 36(11), pages 2866-2871.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Simsek, Suleyman & Uslu, Samet & Simsek, Hatice, 2022. "Proportional impact prediction model of animal waste fat-derived biodiesel by ANN and RSM technique for diesel engine," Energy, Elsevier, vol. 239(PD).
    2. Liu, Ying & Yan, Hanzhao & Liu, Jia & Dong, Wanglai & Cao, Zhi & Hu, Xingbang & Zhou, Zheng, 2020. "Acidic deep eutectic solvents with long carbon chains as catalysts and reaction media for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1842-1853.
    3. Suresh, T. & Sivarajasekar, N. & Balasubramani, K., 2021. "Enhanced ultrasonic assisted biodiesel production from meat industry waste (pig tallow) using green copper oxide nanocatalyst: Comparison of response surface and neural network modelling," Renewable Energy, Elsevier, vol. 164(C), pages 897-907.
    4. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    5. Takeno, Mitsuo L. & Mendonça, Iasmin M. & Barros, Silma de S. & de Sousa Maia, Paulo J. & Pessoa Jr., Wanison A.G. & Souza, Mayane P. & Soares, Elzalina R. & Bindá, Rosane dos S. & Calderaro, Fábio L., 2021. "A novel CaO-based catalyst obtained from silver croaker (Plagioscion squamosissimus) stone for biodiesel synthesis: Waste valorization and process optimization," Renewable Energy, Elsevier, vol. 172(C), pages 1035-1045.
    6. Oraegbunam, Jennifer Chinazor & Oladipo, Babatunde & Falowo, Olayomi Abiodun & Betiku, Eriola, 2020. "Clean sandbox (Hura crepitans) oil methyl esters synthesis: A kinetic and thermodynamic study through pH monitoring approach," Renewable Energy, Elsevier, vol. 160(C), pages 526-537.
    7. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    8. P. Sujin & P. M. Diaz & Ajith J. Kings & L. R. Monisha Miriam, 2023. "Sustainable biodiesel production from Ceiba penandra, Mahua longifolia, and Azadirachta indica using CaO-TiO2 nano catalyst," Energy & Environment, , vol. 34(3), pages 640-662, May.
    9. Kodgire, Pravin & Sharma, Anvita & Kachhwaha, Surendra Singh, 2023. "Optimization and kinetics of biodiesel production of Ricinus communis oil and used cottonseed cooking oil employing synchronised ‘ultrasound + microwave’ and heterogeneous CaO catalyst," Renewable Energy, Elsevier, vol. 212(C), pages 320-332.
    10. Maryam Tanveer Akhtar & Mushtaq Ahmad & Maliha Asma & Mamoona Munir & Muhammad Zafar & Shazia Sultana & M. A. Mujtaba & Abdullah Mohamed & Md Abul Kalam, 2022. "Efficient Production of Wild and Non-Edible Brassica juncea (L.) Czern. Seed Oil into High-Quality Biodiesel via Novel, Green and Recyclable NiSO 4 Nano-Catalyst," Sustainability, MDPI, vol. 14(16), pages 1-26, August.
    11. Laskar, Ikbal Bahar & Deshmukhya, Tuhin & Bhanja, Piyali & Paul, Bappi & Gupta, Rajat & Chatterjee, Sushovan, 2020. "Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield," Renewable Energy, Elsevier, vol. 162(C), pages 98-111.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    2. Ambat, Indu & Srivastava, Varsha & Sillanpää, Mika, 2018. "Recent advancement in biodiesel production methodologies using various feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 356-369.
    3. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.
    4. Qian, Kun & Shen, Xiang & Wang, Yanxin & Gao, Qiang & Ding, Hongwei, 2015. "In-situ transesterification of Jatropha oil over an efficient solid alkali using low leaching component supported on industrial silica gel," Energy, Elsevier, vol. 93(P2), pages 2251-2257.
    5. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    6. Long, Yun-Duo & Fang, Zhen & Su, Tong-Chao & Yang, Qing, 2014. "Co-production of biodiesel and hydrogen from rapeseed and Jatropha oils with sodium silicate and Ni catalysts," Applied Energy, Elsevier, vol. 113(C), pages 1819-1825.
    7. Yatish, K.V. & Lalithamba, H.S. & Suresh, R. & Latha, H.K.E., 2020. "Ochrocarpus longifolius assisted green synthesis of CaTiO3 nanoparticle for biodiesel production and its kinetic study," Renewable Energy, Elsevier, vol. 147(P1), pages 310-321.
    8. Hussein, Ahmed Kadhim, 2015. "Applications of nanotechnology in renewable energies—A comprehensive overview and understanding," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 460-476.
    9. Banković–Ilić, Ivana B. & Miladinović, Marija R. & Stamenković, Olivera S. & Veljković, Vlada B., 2017. "Application of nano CaO–based catalysts in biodiesel synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 746-760.
    10. Yatish, K.V. & Prakash, R. Mithun & Ningaraju, C. & Sakar, M. & GeethaBalakrishna, R. & Lalithamba, H.S., 2021. "Terminalia chebula as a novel green source for the synthesis of copper oxide nanoparticles and as feedstock for biodiesel production and its application on diesel engine," Energy, Elsevier, vol. 215(PB).
    11. Harsha Hebbar, H.R. & Math, M.C. & Yatish, K.V., 2018. "Optimization and kinetic study of CaO nano-particles catalyzed biodiesel production from Bombax ceiba oil," Energy, Elsevier, vol. 143(C), pages 25-34.
    12. Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2012. "Biodiesel production from non-edible plant oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(6), pages 3621-3647.
    13. Meher, L.C. & Churamani, C.P. & Arif, Md. & Ahmed, Z. & Naik, S.N., 2013. "Jatropha curcas as a renewable source for bio-fuels—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 397-407.
    14. Samuel Santos & Luís Nobre & João Gomes & Jaime Puna & Rosa Quinta-Ferreira & João Bordado, 2019. "Soybean Oil Transesterification for Biodiesel Production with Micro-Structured Calcium Oxide (CaO) from Natural Waste Materials as a Heterogeneous Catalyst," Energies, MDPI, vol. 12(24), pages 1-10, December.
    15. Fan, Mingming & Huang, Jianglei & Yang, Jing & Zhang, Pingbo, 2013. "Biodiesel production by transesterification catalyzed by an efficient choline ionic liquid catalyst," Applied Energy, Elsevier, vol. 108(C), pages 333-339.
    16. Shelare, Sagar D. & Belkhode, Pramod N. & Nikam, Keval Chandrakant & Jathar, Laxmikant D. & Shahapurkar, Kiran & Soudagar, Manzoore Elahi M. & Veza, Ibham & Khan, T.M. Yunus & Kalam, M.A. & Nizami, Ab, 2023. "Biofuels for a sustainable future: Examining the role of nano-additives, economics, policy, internet of things, artificial intelligence and machine learning technology in biodiesel production," Energy, Elsevier, vol. 282(C).
    17. Gupta, Anilkumar R. & Rathod, Virendra K., 2018. "Calcium diglyceroxide catalyzed biodiesel production from waste cooking oil in the presence of microwave: Optimization and kinetic studies," Renewable Energy, Elsevier, vol. 121(C), pages 757-767.
    18. Nahas, Lea & Dahdah, Eliane & Aouad, Samer & El Khoury, Bilal & Gennequin, Cedric & Abi Aad, Edmond & Estephane, Jane, 2023. "Highly efficient scallop seashell-derived catalyst for biodiesel production from sunflower and waste cooking oils: Reaction kinetics and effect of calcination temperature studies," Renewable Energy, Elsevier, vol. 202(C), pages 1086-1095.
    19. Siwina, Siraprapha & Leesing, Ratanaporn, 2021. "Bioconversion of durian (Durio zibethinus Murr.) peel hydrolysate into biodiesel by newly isolated oleaginous yeast Rhodotorula mucilaginosa KKUSY14," Renewable Energy, Elsevier, vol. 163(C), pages 237-245.
    20. Malhotra, Rashi & Ali, Amjad, 2019. "5-Na/ZnO doped mesoporous silica as reusable solid catalyst for biodiesel production via transesterification of virgin cottonseed oil," Renewable Energy, Elsevier, vol. 133(C), pages 606-619.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:146:y:2020:i:c:p:280-296. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.