IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v162y2020icp98-111.html
   My bibliography  Save this article

Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield

Author

Listed:
  • Laskar, Ikbal Bahar
  • Deshmukhya, Tuhin
  • Bhanja, Piyali
  • Paul, Bappi
  • Gupta, Rajat
  • Chatterjee, Sushovan

Abstract

We report herein, Soybean oil was shaped to biodiesel using CaO as heterogeneous catalyst and acetone as cosolvent by employing transesterification reaction at room temperature. In order to prepare active CaO catalyst, waste snail shell was calcined at 800 °C. The prepared catalyst was characterized by XRD, SEM, TEM, EDS, TGA, FTIR, XRF, CO2-TPD, XPS and BET. Biodiesel yield of 98% was achieved with the optimized reaction parameters such as acetone loading of 20 wt% of oil, reaction time of 2 h, catalyst loading of 3 wt% and oil to methanol molar ratio of 1/6. Catalyst can be reused up to 11th cycles. It was concluded from the results that this waste material derived heterogeneous catalyst can replace homogeneous catalyst.

Suggested Citation

  • Laskar, Ikbal Bahar & Deshmukhya, Tuhin & Bhanja, Piyali & Paul, Bappi & Gupta, Rajat & Chatterjee, Sushovan, 2020. "Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield," Renewable Energy, Elsevier, vol. 162(C), pages 98-111.
    • Handle: RePEc:eee:renene:v:162:y:2020:i:c:p:98-111
    DOI: 10.1016/j.renene.2020.08.011
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148120312428
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2020.08.011?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pandit, Priti R. & Fulekar, M.H., 2019. "Biodiesel production from microalgal biomass using CaO catalyst synthesized from natural waste material," Renewable Energy, Elsevier, vol. 136(C), pages 837-845.
    2. Farobie, Obie & Sasanami, Kazuma & Matsumura, Yukihiko, 2015. "A novel spiral reactor for biodiesel production in supercritical ethanol," Applied Energy, Elsevier, vol. 147(C), pages 20-29.
    3. Goembira, Fadjar & Saka, Shiro, 2015. "Advanced supercritical Methyl acetate method for biodiesel production from Pongamia pinnata oil," Renewable Energy, Elsevier, vol. 83(C), pages 1245-1249.
    4. Goli, Jibril & Sahu, Omprakash, 2018. "Development of heterogeneous alkali catalyst from waste chicken eggshell for biodiesel production," Renewable Energy, Elsevier, vol. 128(PA), pages 142-154.
    5. Yaakob, Zahira & Mohammad, Masita & Alherbawi, Mohammad & Alam, Zahangir & Sopian, Kamaruzaman, 2013. "Overview of the production of biodiesel from Waste cooking oil," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 184-193.
    6. Krishnamurthy, K.N. & Sridhara, S.N. & Ananda Kumar, C.S., 2020. "Optimization and kinetic study of biodiesel production from Hydnocarpus wightiana oil and dairy waste scum using snail shell CaO nano catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 280-296.
    7. Taherkhani, M. & Sadrameli, S.M., 2018. "An improvement and optimization study of biodiesel production from linseed via in-situ transesterification using a co-solvent," Renewable Energy, Elsevier, vol. 119(C), pages 787-794.
    8. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation," Renewable Energy, Elsevier, vol. 124(C), pages 144-154.
    9. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Haris Mahmood Khan & Tanveer Iqbal & Saima Yasin & Muhammad Irfan & Muhammad Mujtaba Abbas & Ibham Veza & Manzoore Elahi M. Soudagar & Anas Abdelrahman & Md. Abul Kalam, 2022. "Heterogeneous Catalyzed Biodiesel Production Using Cosolvent: A Mini Review," Sustainability, MDPI, vol. 14(9), pages 1-11, April.
    2. Lau, Pak-Chung & Kwong, Tsz-Lung & Yung, Ka-Fu, 2022. "Manganese glycerolate catalyzed simultaneous esterification and transesterification: The kinetic and mechanistic study, and application in biodiesel and bio-lubricants synthesis," Renewable Energy, Elsevier, vol. 189(C), pages 549-558.
    3. Yusuff, Adeyinka Sikiru & Gbadamosi, Afeez Olayinka & Atray, Neeraj, 2022. "Development of a zeolite supported CaO derived from chicken eggshell as active base catalyst for used cooking oil biodiesel production," Renewable Energy, Elsevier, vol. 197(C), pages 1151-1162.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Lani, Nurul Saadiah & Ngadi, Norzita & Inuwa, Ibrahim Mohammed, 2020. "New route for the synthesis of silica-supported calcium oxide catalyst in biodiesel production," Renewable Energy, Elsevier, vol. 156(C), pages 1266-1277.
    2. Ella Cebisa Linganiso & Boitumelo Tlhaole & Lindokuhle Precious Magagula & Silas Dziike & Linda Zikhona Linganiso & Tshwafo Elias Motaung & Nosipho Moloto & Zikhona Nobuntu Tetana, 2022. "Biodiesel Production from Waste Oils: A South African Outlook," Sustainability, MDPI, vol. 14(4), pages 1-21, February.
    3. P. Sujin & P. M. Diaz & Ajith J. Kings & L. R. Monisha Miriam, 2023. "Sustainable biodiesel production from Ceiba penandra, Mahua longifolia, and Azadirachta indica using CaO-TiO2 nano catalyst," Energy & Environment, , vol. 34(3), pages 640-662, May.
    4. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    5. Abu-Ghazala, Abdelmoniem H. & Abdelhady, Hosam H. & Mazhar, Amina A. & El-Deab, Mohamed S., 2022. "Valorization of hazard waste: Efficient utilization of white brick waste powder in the catalytic production of biodiesel from waste cooking oil via RSM optimization process," Renewable Energy, Elsevier, vol. 200(C), pages 1120-1133.
    6. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    7. Mendonça, Iasmin M. & Paes, Orlando A.R.L. & Maia, Paulo J.S. & Souza, Mayane P. & Almeida, Richardson A. & Silva, Cláudia C. & Duvoisin, Sérgio & de Freitas, Flávio A., 2019. "New heterogeneous catalyst for biodiesel production from waste tucumã peels (Astrocaryum aculeatum Meyer): Parameters optimization study," Renewable Energy, Elsevier, vol. 130(C), pages 103-110.
    8. Takeno, Mitsuo L. & Mendonça, Iasmin M. & Barros, Silma de S. & de Sousa Maia, Paulo J. & Pessoa Jr., Wanison A.G. & Souza, Mayane P. & Soares, Elzalina R. & Bindá, Rosane dos S. & Calderaro, Fábio L., 2021. "A novel CaO-based catalyst obtained from silver croaker (Plagioscion squamosissimus) stone for biodiesel synthesis: Waste valorization and process optimization," Renewable Energy, Elsevier, vol. 172(C), pages 1035-1045.
    9. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    10. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    11. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    12. Mandolesi de Araújo, Carlos Daniel & de Andrade, Claudia Cristina & de Souza e Silva, Erika & Dupas, Francisco Antonio, 2013. "Biodiesel production from used cooking oil: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 445-452.
    13. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2019. "Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil," Renewable Energy, Elsevier, vol. 143(C), pages 77-90.
    14. Karmakar, Bisheswar & Pal, Sucharita & Gopikrishna, Konga & Tiwari, Onkar Nath & Halder, Gopinath, 2022. "Injection of superheated C1 and C3 alcohols in non-edible Pongamia pinnata oil for semi-continuous uncatalyzed biodiesel synthesis," Renewable Energy, Elsevier, vol. 185(C), pages 850-861.
    15. Mohammad Anwar & Mohammad G. Rasul & Nanjappa Ashwath & Md Mofijur Rahman, 2018. "Optimisation of Second-Generation Biodiesel Production from Australian Native Stone Fruit Oil Using Response Surface Method," Energies, MDPI, vol. 11(10), pages 1-18, September.
    16. Nirmala, N. & Dawn, S.S., 2021. "Optimization of Chlorella variabilis. MK039712.1 lipid transesterification using Response Surface Methodology and analytical characterization of biodiesel," Renewable Energy, Elsevier, vol. 179(C), pages 1663-1673.
    17. Mostafaei, Mostafa & Javadikia, Hossein & Naderloo, Leila, 2016. "Modeling the effects of ultrasound power and reactor dimension on the biodiesel production yield: Comparison of prediction abilities between response surface methodology (RSM) and adaptive neuro-fuzzy," Energy, Elsevier, vol. 115(P1), pages 626-636.
    18. Miranda, Amanda Carvalho & da Silva Filho, Silvério Catureba & Tambourgi, Elias Basile & CurveloSantana, José Carlos & Vanalle, Rosangela Maria & Guerhardt, Flávio, 2018. "Analysis of the costs and logistics of biodiesel production from used cooking oil in the metropolitan region of Campinas (Brazil)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 373-379.
    19. Hao, Xiaohong & Suo, Hang & Zhang, Guanhua & Xu, Peixing & Gao, Xin & Du, Su, 2021. "Ultrasound-assisted enzymatic preparation of fatty acid ethyl ester in deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 937-947.
    20. Seffati, Kambiz & Esmaeili, Hossein & Honarvar, Bizhan & Esfandiari, Nadia, 2020. "AC/CuFe2O4@CaO as a novel nanocatalyst to produce biodiesel from chicken fat," Renewable Energy, Elsevier, vol. 147(P1), pages 25-34.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:162:y:2020:i:c:p:98-111. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.