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RSM-based comparative experimental study of sustainable biodiesel synthesis from different 2G feedstocks using magnetic nanocatalyst CaFe2O4

Author

Listed:
  • A. Saravanan

    (Ponjesly College of Engineering)

  • Ajith J. Kings

    (St. Xavier’s Catholic College of Engineering)

  • L. R. Monisha Miriam

    (Udaya School of Engineering)

  • R. S. Rimal Isaac

    (Noorul Islam Centre for Higher Education)

Abstract

Today’s demand of energy in the world of automobile provokes the researchers to strive for the easily available and cheapest renewable source of energy. Biodiesel has become one of the booming renewable sources in the world to mitigate the atmospheric pollution and the demand of fossil fuels. Oils are chosen based on their fatty acid content, availability and sustainability. A magnetic nanocatalyst CaFe2O4 has been employed in the transesterification process and is characterized by various progressive techniques to confirm its compatibility. The locally available, nonedible oils such as cotton seed oil, rubber seed oil and pungai seed oil have been taken for this experimental work for efficient and sustainable biodiesel production. Multi-variant central composite design has been employed to enhance the influencing process parameters in biodiesel conversion. Each feedstock produced more than 95% of the yield which consumed very little amount of methanol and catalyst in a short period of time. In order to ensure a quick reaction and smooth stirring, the temperature is kept at 70 °C (beyond the boiling point of the solvent). The chromatography analysis was used to describe the end product samples which revealed the right proportion of saturated and unsaturated fatty acids at the proper level, resulting in better oxidation stability and combustion properties. Moreover, density, viscosity, cetene number, iodine value and other essential properties were analysed and found to be within the standards specified by EN and ASTM for use in automotive applications without modifying the engine.

Suggested Citation

  • A. Saravanan & Ajith J. Kings & L. R. Monisha Miriam & R. S. Rimal Isaac, 2024. "RSM-based comparative experimental study of sustainable biodiesel synthesis from different 2G feedstocks using magnetic nanocatalyst CaFe2O4," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 26(2), pages 3097-3126, February.
    • Handle: RePEc:spr:endesu:v:26:y:2024:i:2:d:10.1007_s10668-022-02761-1
    DOI: 10.1007/s10668-022-02761-1
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    References listed on IDEAS

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    1. Hosseini, Shokoufe & Moradi, G.R. & Bahrami, Kiumars, 2019. "Synthesis of a novel stabilized basic ionic liquid through immobilization on boehmite nanoparticles: A robust nanocatalyst for biodiesel production from soybean oil," Renewable Energy, Elsevier, vol. 138(C), pages 70-78.
    2. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    3. Pandit, Priti R. & Fulekar, M.H., 2019. "Biodiesel production from microalgal biomass using CaO catalyst synthesized from natural waste material," Renewable Energy, Elsevier, vol. 136(C), pages 837-845.
    4. Krishnamurthy, K.N. & Sridhara, S.N. & Ananda Kumar, C.S., 2020. "Optimization and kinetic study of biodiesel production from Hydnocarpus wightiana oil and dairy waste scum using snail shell CaO nano catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 280-296.
    5. Deeba, Farha & Kumar, Bijender & Arora, Neha & Singh, Sauraj & Kumar, Anuj & Han, Sung Soo & Negi, Yuvraj S., 2020. "Novel bio-based solid acid catalyst derived from waste yeast residue for biodiesel production," Renewable Energy, Elsevier, vol. 159(C), pages 127-139.
    6. Sandouqa, Arwa & Al-Hamamre, Zayed, 2019. "Energy analysis of biodiesel production from jojoba seed oil," Renewable Energy, Elsevier, vol. 130(C), pages 831-842.
    7. Hoseini, S.S. & Najafi, G. & Ghobadian, B. & Mamat, R. & Ebadi, M.T. & Yusaf, Talal, 2019. "Characterization of biodiesel production (ultrasonic-assisted) from evening-primroses (Oenothera lamarckiana) as novel feedstock and its effect on CI engine parameters," Renewable Energy, Elsevier, vol. 130(C), pages 50-60.
    8. Su, Feng & Peng, Cheng & Li, Guan-Lin & Xu, Li & Yan, Yun-Jun, 2016. "Biodiesel production from woody oil catalyzed by Candida rugosa lipase in ionic liquid," Renewable Energy, Elsevier, vol. 90(C), pages 329-335.
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