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Functionalized chitosan-derived porous carbon as a promising catalyst in one-pot conversion of soybean oil to biodiesel

Author

Listed:
  • Tie, Xinlong
  • Li, Yun
  • Yuan, Kai
  • Tan, Zhengxin
  • Liu, Yitian
  • Liu, Jiang
  • Wang, Hongyan
  • Zhang, Chengjia
  • Wan, Yuanzhe
  • Zou, Chong
  • Wang, Tielin
  • Feng, Weiliang
  • Duan, Xiaoling

Abstract

Biodiesel production has traditionally been converted using homogeneous acidic or basic catalysts, but both have limitations. In this paper, a functionalized recyclable porous chitosan-based composite catalyst (ZNC) was developed using activator activation during the catalyst preparation process. XRD, SEM, BET, TGA, and FT-IR were used to confirm the successful synthesis of the catalyst. Activators have been found to affect the growth of the skeleton, providing a great porous texture for the carbon skeleton, which can greatly improve the catalytic performance. As expected, the exposed metal sites and functionalized nitrogen of ZNC materials play a key role in the conversion of soybean oil during the preparation of biodiesel. The higher biodiesel yield (95.33 %) was obtained at the defined condition (calcination temperature = 750 °C, calcination time = 5 h, ZnCl2 concentration = 30 %, NH3·H2O concentration = 30 %, reaction temperature = 60 °C, reaction time = 6 h, catalyst loading = 1 wt%, methanol/oil molar ratio = 6:1). The catalyst has higher catalytic.

Suggested Citation

  • Tie, Xinlong & Li, Yun & Yuan, Kai & Tan, Zhengxin & Liu, Yitian & Liu, Jiang & Wang, Hongyan & Zhang, Chengjia & Wan, Yuanzhe & Zou, Chong & Wang, Tielin & Feng, Weiliang & Duan, Xiaoling, 2025. "Functionalized chitosan-derived porous carbon as a promising catalyst in one-pot conversion of soybean oil to biodiesel," Renewable Energy, Elsevier, vol. 245(C).
    • Handle: RePEc:eee:renene:v:245:y:2025:i:c:s0960148125005336
    DOI: 10.1016/j.renene.2025.122871
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