IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v77y2014icp19-24.html
   My bibliography  Save this article

The effect of hemicelluloses and lignin on acid hydrolysis of cellulose

Author

Listed:
  • Yoon, S.-Y.
  • Han, S.-H.
  • Shin, S.-J.

Abstract

In acid hydrolysis of plant biomass, polysaccharides are converted to monosaccharides, which is basic raw material for biorefinery for fermentation based process. These monosaccharides, however, are not stable in acidic reaction medium, and are converted to organic acids via furans. Impact of hemicelluloses and lignin on acid hydrolysis of cellulose was investigated to focus on monosaccharide production with different degrees of cellulose purity. Two-step concentrated sulphuric acid process was applied to biomass for monosaccharide conversion. Kinetics of cellulose hydrolysis was analysed using 1H NMR spectroscopy. Higher reaction temperature in secondary hydrolysis caused severe degradation of the monosaccharides. In pure and holocellulose, further reaction of glucose in acidic reaction medium produced formic acid and levulinic acid. However, lignocellulosic biomass generated much less formic acid and levulinic acid under the same reaction condition. Humin (or pseudo-lignin) was also formed by the condensation of lignin and furans from monosaccharides in acidic reaction condition. Thus, the fermentation inhibitors, furans and formic acid, were generated in low quantities by lignocellulosic biomass than by delignified biomass such as pure cellulose or holocellulose.

Suggested Citation

  • Yoon, S.-Y. & Han, S.-H. & Shin, S.-J., 2014. "The effect of hemicelluloses and lignin on acid hydrolysis of cellulose," Energy, Elsevier, vol. 77(C), pages 19-24.
    • Handle: RePEc:eee:energy:v:77:y:2014:i:c:p:19-24
    DOI: 10.1016/j.energy.2014.01.104
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214001261
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.01.104?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yüksel, Fikret & Yüksel, Bedri, 2004. "The use of ethanol–gasoline blend as a fuel in an SI engine," Renewable Energy, Elsevier, vol. 29(7), pages 1181-1191.
    2. Lund, Henrik, 2007. "Renewable energy strategies for sustainable development," Energy, Elsevier, vol. 32(6), pages 912-919.
    3. Ojeda, Karina & Sánchez, Eduardo & Kafarov, Viatcheslav, 2011. "Sustainable ethanol production from lignocellulosic biomass – Application of exergy analysis," Energy, Elsevier, vol. 36(4), pages 2119-2128.
    4. Mack, J. Hunter & Aceves, Salvador M. & Dibble, Robert W., 2009. "Demonstrating direct use of wet ethanol in a homogeneous charge compression ignition (HCCI) engine," Energy, Elsevier, vol. 34(6), pages 782-787.
    5. Tran, Luc Sy & Sirjean, Baptiste & Glaude, Pierre-Alexandre & Fournet, René & Battin-Leclerc, Frédérique, 2012. "Progress in detailed kinetic modeling of the combustion of oxygenated components of biofuels," Energy, Elsevier, vol. 43(1), pages 4-18.
    6. Han, S.-H. & Cho, D.H. & Kim, Y.H. & Shin, S.-J., 2013. "Biobutanol production from 2-year-old willow biomass by acid hydrolysis and acetone–butanol–ethanol fermentation," Energy, Elsevier, vol. 61(C), pages 13-17.
    7. Cardona Alzate, C.A. & Sánchez Toro, O.J., 2006. "Energy consumption analysis of integrated flowsheets for production of fuel ethanol from lignocellulosic biomass," Energy, Elsevier, vol. 31(13), pages 2447-2459.
    8. Baltz, Richard A. & Burcham, Andy F. & Sitton, Oliver C. & Book, Neil L., 1982. "The recycle of sulfuric acid and xylose in the prehydrolysis of corn stover," Energy, Elsevier, vol. 7(3), pages 259-265.
    9. Katinonkul, Watcharee & Lee, Jin-Suk & Ha, Sung Ho & Park, Ji-Yeon, 2012. "Enhancement of enzymatic digestibility of oil palm empty fruit bunch by ionic-liquid pretreatment," Energy, Elsevier, vol. 47(1), pages 11-16.
    10. Irimescu, Adrian, 2011. "Fuel conversion efficiency of a port injection engine fueled with gasoline–isobutanol blends," Energy, Elsevier, vol. 36(5), pages 3030-3035.
    11. Felix, Erika & Tilley, David R., 2009. "Integrated energy, environmental and financial analysis of ethanol production from cellulosic switchgrass," Energy, Elsevier, vol. 34(4), pages 410-436.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tu, Ren & Sun, Yan & Wu, Yujian & Fan, Xudong & Cheng, Shuchao & Jiang, Enchen & Xu, Xiwei, 2021. "A new index for hydrochar based on fixed carbon content to predict its structural properties and thermal behavior," Energy, Elsevier, vol. 229(C).
    2. Byun, Jaewon & Han, Jeehoon, 2019. "Catalytic conversion of corn stover for 〈gamma〉-valerolactone production by two different solvent strategies: Techno-economic assessment," Energy, Elsevier, vol. 175(C), pages 546-553.
    3. Asina, FNU & Brzonova, Ivana & Kozliak, Evguenii & Kubátová, Alena & Ji, Yun, 2017. "Microbial treatment of industrial lignin: Successes, problems and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1179-1205.
    4. Kang, Shimin & Fu, Jinxia & Zhang, Gang, 2018. "From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 340-362.
    5. Yoon, Su-Young & Kim, Byung-Ro & Han, Sim-Hee & Shin, Soo-Jeong, 2015. "Different response between woody core and bark of goat willow (Salix caprea L.) to concentrated phosphoric acid pretreatment followed by enzymatic saccharification," Energy, Elsevier, vol. 81(C), pages 21-26.
    6. Zhou, Ziyuan & Liu, Dehua & Zhao, Xuebing, 2021. "Conversion of lignocellulose to biofuels and chemicals via sugar platform: An updated review on chemistry and mechanisms of acid hydrolysis of lignocellulose," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    7. Kumar, Sachin & Dheeran, Pratibha & Singh, Surendra P. & Mishra, Indra M. & Adhikari, Dilip K., 2015. "Kinetic studies of two-stage sulphuric acid hydrolysis of sugarcane bagasse," Renewable Energy, Elsevier, vol. 83(C), pages 850-858.
    8. Antonio Manuel Pérez-Merchán & Gabriela Rodríguez-Carballo & Benjamín Torres-Olea & Cristina García-Sancho & Pedro Jesús Maireles-Torres & Josefa Mérida-Robles & Ramón Moreno-Tost, 2022. "Recent Advances in Mechanochemical Pretreatment of Lignocellulosic Biomass," Energies, MDPI, vol. 15(16), pages 1-34, August.
    9. Zhao, Weijie & Li, Yingwen & Song, Changhua & Liu, Sijie & Li, Xuehui & Long, Jinxing, 2017. "Intensified levulinic acid/ester production from cassava by one-pot cascade prehydrolysis and delignification," Applied Energy, Elsevier, vol. 204(C), pages 1094-1100.
    10. Liu, Yunyun & Xu, Jingliang & Zhang, Yu & Yuan, Zhenhong & He, Minchao & Liang, Cuiyi & Zhuang, Xinshu & Xie, Jun, 2015. "Sequential bioethanol and biogas production from sugarcane bagasse based on high solids fed-batch SSF," Energy, Elsevier, vol. 90(P1), pages 1199-1205.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liu, Kaimin & Fu, Jianqin & Deng, Banglin & Yang, Jing & Tang, Qijun & Liu, Jingping, 2014. "The influences of pressure and temperature on laminar flame propagations of n-butanol, iso-octane and their blends," Energy, Elsevier, vol. 73(C), pages 703-715.
    2. Tan, Inn Shi & Lee, Keat Teong, 2014. "Enzymatic hydrolysis and fermentation of seaweed solid wastes for bioethanol production: An optimization study," Energy, Elsevier, vol. 78(C), pages 53-62.
    3. Han, S.-H. & Cho, D.H. & Kim, Y.H. & Shin, S.-J., 2013. "Biobutanol production from 2-year-old willow biomass by acid hydrolysis and acetone–butanol–ethanol fermentation," Energy, Elsevier, vol. 61(C), pages 13-17.
    4. Dias, Marina O.S. & Junqueira, Tassia L. & Jesus, Charles D.F. & Rossell, Carlos E.V. & Maciel Filho, Rubens & Bonomi, Antonio, 2012. "Improving second generation ethanol production through optimization of first generation production process from sugarcane," Energy, Elsevier, vol. 43(1), pages 246-252.
    5. Yang, Bing-Yuan & Cheng, Ming-Hsun & Ko, Chun-Han & Wang, Ya-Nan & Chen, Wen-Hua & Hwang, Wen-Song & Yang, Yuan-Po & Chen, Hsin-Tai & Chang, Fang-Chih, 2014. "Potential bioethanol production from Taiwanese chenopods (Chenopodium formosanum)," Energy, Elsevier, vol. 76(C), pages 59-65.
    6. Liu, Fang & Chen, Guanyi & Yan, Beibei & Ma, Wenchao & Cheng, Zhanjun & Hou, Li'an, 2017. "Exergy analysis of a new lignocellulosic biomass-based polygeneration system," Energy, Elsevier, vol. 140(P1), pages 1087-1095.
    7. Deng, Banglin & Fu, Jianqin & Zhang, Daming & Yang, Jing & Feng, Renhua & Liu, Jingping & Li, Ke & Liu, Xiaoqiang, 2013. "The heat release analysis of bio-butanol/gasoline blends on a high speed SI (spark ignition) engine," Energy, Elsevier, vol. 60(C), pages 230-241.
    8. Velásquez-Arredondo, H.I. & Ruiz-Colorado, A.A. & De Oliveira, S., 2010. "Ethanol production process from banana fruit and its lignocellulosic residues: Energy analysis," Energy, Elsevier, vol. 35(7), pages 3081-3087.
    9. Goh, Chun Sheng & Lee, Keat Teong, 2010. "Palm-based biofuel refinery (PBR) to substitute petroleum refinery: An energy and emergy assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 2986-2995, December.
    10. Kyriakopoulos, Grigorios L. & Arabatzis, Garyfallos & Tsialis, Panagiotis & Ioannou, Konstantinos, 2018. "Electricity consumption and RES plants in Greece: Typologies of regional units," Renewable Energy, Elsevier, vol. 127(C), pages 134-144.
    11. Piotr Siemiątkowski & Patryk Tomaszewski & Joanna Marszałek-Kawa & Janusz Gierszewski, 2020. "The Financing of Renewable Energy Sources and the Level of Sustainable Development of Poland’s Provinces in the Area of Environmental Order," Energies, MDPI, vol. 13(21), pages 1-19, October.
    12. Fanelli, Emanuele & Viggiano, Annarita & Braccio, Giacobbe & Magi, Vinicio, 2014. "On laminar flame speed correlations for H2/CO combustion in premixed spark ignition engines," Applied Energy, Elsevier, vol. 130(C), pages 166-180.
    13. Østergaard, P.A. & Lund, H. & Thellufsen, J.Z. & Sorknæs, P. & Mathiesen, B.V., 2022. "Review and validation of EnergyPLAN," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    14. Bahri, Bahram & Shahbakhti, Mahdi & Aziz, Azhar Abdul, 2017. "Real-time modeling of ringing in HCCI engines using artificial neural networks," Energy, Elsevier, vol. 125(C), pages 509-518.
    15. Keun-Seob Choi & Jeong-Dong Lee & Chulwoo Baek, 2016. "Growth of De Alio and De Novo firms in the new and renewable energy industry," Industry and Innovation, Taylor & Francis Journals, vol. 23(4), pages 295-312, May.
    16. Göransson, Lisa & Goop, Joel & Unger, Thomas & Odenberger, Mikael & Johnsson, Filip, 2014. "Linkages between demand-side management and congestion in the European electricity transmission system," Energy, Elsevier, vol. 69(C), pages 860-872.
    17. Tomasz Jałowiec & Henryk Wojtaszek, 2021. "Analysis of the RES Potential in Accordance with the Energy Policy of the European Union," Energies, MDPI, vol. 14(19), pages 1-33, September.
    18. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    19. Tomislav Malvić & Uroš Barudžija & Borivoje Pašić & Josip Ivšinović, 2021. "Small Unconventional Hydrocarbon Gas Reservoirs as Challenging Energy Sources, Case Study from Northern Croatia," Energies, MDPI, vol. 14(12), pages 1-16, June.
    20. Geraili, A. & Sharma, P. & Romagnoli, J.A., 2014. "Technology analysis of integrated biorefineries through process simulation and hybrid optimization," Energy, Elsevier, vol. 73(C), pages 145-159.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:77:y:2014:i:c:p:19-24. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.