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Catalytic conversion of corn stover for 〈gamma〉-valerolactone production by two different solvent strategies: Techno-economic assessment

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  • Byun, Jaewon
  • Han, Jeehoon

Abstract

This study compares two processes to produce γ-valerolactone from lignocellulosic biomass: Process A is single processing of cellulose by using lignin-derived propyl guaiacol solvent; Process B is simultaneous processing of cellulose and hemicellulose by using γ-valerolactone solvent derived from cellulose and hemicellulose. Large-scale processes that integrate conversion and separation technologies are assembled based on experimental data, and daily GVL productions are 98 tonnes (Process A) and 375 tonnes (Process B). A heat-exchanger network is designed to reduce heating requirements, and the energy efficiencies are 13.3% (Process A) and 37.3% (Process B). Techno-economic assessment is conducted to identify the economic feasibility. The minimum selling price of γ-valerolactone for Process A (US$ 2.36/kg) and Process B (US$ 0.88/kg) are comparable with market price. The difference in the minimum selling prices is mainly caused by effective utilization of the hemicellulose in lignocellulose biomass in Process B. Sensitivity analyses present that changes in key parameters could not reverse the minimum selling price of γ-valerolactone between the two strategies, but the conversion of xylose to value-added chemical in Process A makes this possible. This study shows that development of conversion technologies to effectively utilize the hemicellulose in lignocellulosic biomass is critical to improve process economics.

Suggested Citation

  • Byun, Jaewon & Han, Jeehoon, 2019. "Catalytic conversion of corn stover for 〈gamma〉-valerolactone production by two different solvent strategies: Techno-economic assessment," Energy, Elsevier, vol. 175(C), pages 546-553.
    • Handle: RePEc:eee:energy:v:175:y:2019:i:c:p:546-553
    DOI: 10.1016/j.energy.2019.03.070
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    References listed on IDEAS

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    1. Yoon, S.-Y. & Han, S.-H. & Shin, S.-J., 2014. "The effect of hemicelluloses and lignin on acid hydrolysis of cellulose," Energy, Elsevier, vol. 77(C), pages 19-24.
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    Cited by:

    1. Nicolás M. Clauser & Giselle González & Carolina M. Mendieta & Julia Kruyeniski & María C. Area & María E. Vallejos, 2021. "Biomass Waste as Sustainable Raw Material for Energy and Fuels," Sustainability, MDPI, vol. 13(2), pages 1-21, January.
    2. Lee, Cornelius Basil Tien Loong & Wu, Ta Yeong, 2021. "A review on solvent systems for furfural production from lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    3. Li, Wen-Chao & Zhang, Sen-Jia & Xu, Tao & Sun, Mei-Qing & Zhu, Jia-Qing & Zhong, Cheng & Li, Bing-Zhi & Yuan, Ying-Jin, 2020. "Fractionation of corn stover by two-step pretreatment for production of ethanol, furfural, and lignin," Energy, Elsevier, vol. 195(C).
    4. Bangalore Ashok, Rahul Prasad & Oinas, Pekka & Forssell, Susanna, 2022. "Techno-economic evaluation of a biorefinery to produce γ-valerolactone (GVL), 2-methyltetrahydrofuran (2-MTHF) and 5-hydroxymethylfurfural (5-HMF) from spruce," Renewable Energy, Elsevier, vol. 190(C), pages 396-407.

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