IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v300y2021ics0306261921008230.html
   My bibliography  Save this article

Bio-based process for the catalytic production of ethyl levulinate from cellulose

Author

Listed:
  • Kim, Juyeon
  • Han, Jeehoon

Abstract

This paper presents a bio-based process for the catalytic conversion of cellulose to ethyl levulinate and an analysis of its techno-economic feasibility. The said bio-based process relies as major feedstock on cellulose, which can be derived from lignocellulosic biomass. cellulose is converted to ethyl levulinate via a homogeneous catalytic reaction whereby dilute sulfuric acid in combination with Al salts is the catalyst and ethanol is the solvent and reactant. This approach affords high ethyl levulinate yields but requires complex procedures for used catalyst and solvent recycling. Based on experimental results on the homogeneous catalytic reaction and vapor–liquid equilibrium separation in the previous studies, a simulation was conducted that included process design, energy integration, and economic analysis. Results from this simulation indicated the proposed bio-based process to afford a minimum selling price of US$ 2,830 per ton of ethyl levulinate, which was highly dependent on an off-site supply of heating energy required for ethanol purification.11The short version of the paper was presented at ICAE2020, Dec 1–10, 2020. This paper is a substantial extension of the short version of the conference paper.

Suggested Citation

  • Kim, Juyeon & Han, Jeehoon, 2021. "Bio-based process for the catalytic production of ethyl levulinate from cellulose," Applied Energy, Elsevier, vol. 300(C).
  • Handle: RePEc:eee:appene:v:300:y:2021:i:c:s0306261921008230
    DOI: 10.1016/j.apenergy.2021.117430
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261921008230
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2021.117430?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Kim, Dongin & Han, Jeehoon, 2020. "Comprehensive analysis of two catalytic processes to produce formic acid from carbon dioxide," Applied Energy, Elsevier, vol. 264(C).
    2. Byun, Jaewon & Han, Jeehoon, 2016. "Process synthesis and analysis for catalytic conversion of lignocellulosic biomass to fuels: Separate conversion of cellulose and hemicellulose using 2-sec-butylphenol (SBP) solvent," Applied Energy, Elsevier, vol. 171(C), pages 483-490.
    3. Wang, Zhiwei & Li, Zaifeng & Lei, Tingzhou & Yang, Miao & Qi, Tian & Lin, Lu & Xin, Xiaofei & Ajayebi, Atta & Yang, Yantao & He, Xiaofeng & Yan, Xiaoyu, 2016. "Life cycle assessment of energy consumption and environmental emissions for cornstalk-based ethyl levulinate," Applied Energy, Elsevier, vol. 183(C), pages 170-181.
    4. Kim, Juyeon & Han, Jeehoon, 2018. "Simulation study of a strategy to produce gamma-valerolactone from ethyl levulinate," Energy, Elsevier, vol. 163(C), pages 986-991.
    5. Cho, Seong-Heon & Kim, Juyeon & Han, Jeehoon & Lee, Daewon & Kim, Hyung Ju & Kim, Yong Tae & Cheng, Xun & Xu, Ye & Lee, Jechan & Kwon, Eilhann E., 2019. "Bioalcohol production from acidogenic products via a two-step process: A case study of butyric acid to butanol," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kim, Juyeon & Byun, Jaewon & Han, Jeehoon, 2022. "Process integration and economics of gamma-valerolactone using a cellulose-derived ethyl levulinate intermediate and ethanol solvent," Energy, Elsevier, vol. 239(PA).
    2. Park, Hoyoung & Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible thermochemical process for methanol production from kenaf," Energy, Elsevier, vol. 230(C).
    3. Kwon, Oseok & Han, Jeehoon, 2021. "Supply chain management of butyric acid-derived butanol: Stochastic approach," Applied Energy, Elsevier, vol. 297(C).
    4. Kwon, Oseok & Kim, Juyeon & Han, Jeehoon, 2022. "Organic waste derived biodiesel supply chain network: Deterministic multi-period planning model," Applied Energy, Elsevier, vol. 305(C).
    5. Byun, Jaewon & Han, Jeehoon, 2021. "Economically feasible production of green methane from vegetable and fruit-rich food waste," Energy, Elsevier, vol. 235(C).
    6. Byun, Jaewon & Han, Jeehoon, 2020. "Economic feasible strategy of cellulosic biofuels: Co-production of pentanediols," Energy, Elsevier, vol. 193(C).
    7. Kwon, Oseok & Han, Jeehoon, 2021. "Waste-to-bioethanol supply chain network: A deterministic model," Applied Energy, Elsevier, vol. 300(C).
    8. Oner, Oytun & Khalilpour, Kaveh, 2022. "Evaluation of green hydrogen carriers: A multi-criteria decision analysis tool," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    9. Tsai, Tsung-Yu & Lo, Yung-Chung & Dong, Cheng-Di & Nagarajan, Dillirani & Chang, Jo-Shu & Lee, Duu-Jong, 2020. "Biobutanol production from lignocellulosic biomass using immobilized Clostridium acetobutylicum," Applied Energy, Elsevier, vol. 277(C).
    10. Dorota Burchart-Korol & Magdalena Gazda-Grzywacz & Katarzyna Zarębska, 2020. "Research and Prospects for the Development of Alternative Fuels in the Transport Sector in Poland: A Review," Energies, MDPI, vol. 13(11), pages 1-16, June.
    11. Byun, Jaewon & Han, Jeehoon, 2019. "Catalytic conversion of corn stover for 〈gamma〉-valerolactone production by two different solvent strategies: Techno-economic assessment," Energy, Elsevier, vol. 175(C), pages 546-553.
    12. Jung, Sungyup & Lee, Jechan & Moon, Deok Hyun & Kim, Ki-Hyun & Kwon, Eilhann E., 2021. "Upgrading biogas into syngas through dry reforming," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    13. Onwudili, Jude A. & Nouwe Edou, Danielle J., 2022. "Process modelling and economic evaluation of biopropane production from aqueous butyric acid feedstock," Renewable Energy, Elsevier, vol. 184(C), pages 80-90.
    14. Han, Jeehoon & Byun, Jaewon & Kwon, Oseok & Lee, Jechan, 2022. "Climate variability and food waste treatment: Analysis for bioenergy sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    15. Xu, Jikun & Hou, Huijie & Hu, Jingping & Liu, Bingchuan, 2018. "Coupling of hydrothermal and ionic liquid pretreatments for sequential biorefinery of Tamarix austromongolica," Applied Energy, Elsevier, vol. 229(C), pages 745-755.
    16. Quanguo Zhang & Youzhou Jiao & Chao He & Roger Ruan & Jianjun Hu & Jingzheng Ren & Sara Toniolo & Danping Jiang & Chaoyang Lu & Yameng Li & Yi Man & Huan Zhang & Zhiping Zhang & Chenxi Xia & Yi Wang &, 2024. "Biological fermentation pilot-scale systems and evaluation for commercial viability towards sustainable biohydrogen production," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    17. Heeyoung Choi & Jeehoon Han & Jechan Lee, 2021. "Renewable Butanol Production via Catalytic Routes," IJERPH, MDPI, vol. 18(22), pages 1-14, November.
    18. Kim, Juyeon & Han, Jeehoon, 2018. "Simulation study of a strategy to produce gamma-valerolactone from ethyl levulinate," Energy, Elsevier, vol. 163(C), pages 986-991.
    19. Nicolás M. Clauser & Giselle González & Carolina M. Mendieta & Julia Kruyeniski & María C. Area & María E. Vallejos, 2021. "Biomass Waste as Sustainable Raw Material for Energy and Fuels," Sustainability, MDPI, vol. 13(2), pages 1-21, January.
    20. Jung, Sungyup & Kim, Jung-Hun & Jeon, Young Jae & Park, Young-Kwon & Kwon, Eilhann E., 2020. "Synergistic use of carbon dioxide in catalytic pyrolysis of chlorella vulgaris over Ni and Co catalysts," Energy, Elsevier, vol. 211(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:300:y:2021:i:c:s0306261921008230. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.