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Kinetic studies of two-stage sulphuric acid hydrolysis of sugarcane bagasse

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  • Kumar, Sachin
  • Dheeran, Pratibha
  • Singh, Surendra P.
  • Mishra, Indra M.
  • Adhikari, Dilip K.

Abstract

The present paper reports the two-stage hydrolysis of sugarcane bagasse to produce monomer sugars by using dilute and concentrated sulphuric acid. About 88% of the sugars present in bagasse could be recovered with a little formation of toxic compounds such as furfural/HMF. The sugar concentration in the first-stage of hydrolysis was obtained as xylose-rich solution of 49.7 g l−1 using 8% acid concentration at 100 °C and a solid to liquid ratio of 1:4, whereas, with the same solid to liquid ratio of 1:4, 73.4 g l−1 glucose-rich solution was obtained in the second-stage of hydrolysis by using 40% acid concentration at 80 °C. The acid hydrolysis of bagasse could be described by a first-order, two-step consecutive reaction model, where the polysaccharides first decompose into monomers through hydrolysis, and thereafter, decompose into various products in the second step. The proposed kinetic model correlates the experimental data satisfactorily.

Suggested Citation

  • Kumar, Sachin & Dheeran, Pratibha & Singh, Surendra P. & Mishra, Indra M. & Adhikari, Dilip K., 2015. "Kinetic studies of two-stage sulphuric acid hydrolysis of sugarcane bagasse," Renewable Energy, Elsevier, vol. 83(C), pages 850-858.
    • Handle: RePEc:eee:renene:v:83:y:2015:i:c:p:850-858
    DOI: 10.1016/j.renene.2015.05.033
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    References listed on IDEAS

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    1. Chen, Wei-Hsin & Tu, Yi-Jian & Sheen, Herng-Kuang, 2011. "Disruption of sugarcane bagasse lignocellulosic structure by means of dilute sulfuric acid pretreatment with microwave-assisted heating," Applied Energy, Elsevier, vol. 88(8), pages 2726-2734, August.
    2. Yoon, S.-Y. & Han, S.-H. & Shin, S.-J., 2014. "The effect of hemicelluloses and lignin on acid hydrolysis of cellulose," Energy, Elsevier, vol. 77(C), pages 19-24.
    3. Chen, Wei-Hsin & Ye, Song-Ching & Sheen, Herng-Kuang, 2012. "Hydrolysis characteristics of sugarcane bagasse pretreated by dilute acid solution in a microwave irradiation environment," Applied Energy, Elsevier, vol. 93(C), pages 237-244.
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    1. Rosen, Yan & Mamane, Hadas & Gerchman, Yoram, 2021. "Immersed ozonation of agro-wastes as an effective pretreatment method in bioethanol production," Renewable Energy, Elsevier, vol. 174(C), pages 382-390.
    2. Chang, Xiaogang & Bai, Yuchen & Wu, Ruchun & Liu, Dehua & Zhao, Xuebing, 2020. "Heterogeneity of lignocellulose must be considered for kinetic study: A case on formic acid fractionation of sugarcane bagasse with different pseudo-homogeneous kinetic models," Renewable Energy, Elsevier, vol. 162(C), pages 2246-2258.
    3. Azman, Nadia Farhana & Abdeshahian, Peyman & Kadier, Abudukeremu & Shukor, Hafiza & Al-Shorgani, Najeeb Kaid Nasser & Hamid, Aidil Abdul & Kalil, Mohd Sahaid, 2016. "Utilization of palm kernel cake as a renewable feedstock for fermentative hydrogen production," Renewable Energy, Elsevier, vol. 93(C), pages 700-708.

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