IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v70y2014icp612-617.html
   My bibliography  Save this article

Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability

Author

Listed:
  • Wang, Kai
  • Li, Liwei
  • Zhang, Tiezhu
  • Liu, Zaifei

Abstract

Nitrogen-doped graphene is prepared by a solid microwave method with EDA (ethylenediamine) as the nitrogen source. The experimental results reveal that nitrogen atoms from the grafted EDA molecules on the surface of graphene are successfully doped into the lattices. The NGS (nitrogen-doped graphene nanosheets) sample exhibits outstanding specific capacitances of 197 and 151 F g−1 at the current densities of 0.5 and 5 A g−1 in 6.0 mol L−1 KOH aqueous electrolyte, respectively. Furthermore, the sample also displays more superior rate capacity, which can possess high specific capacitance retention of 77% and 70% at the high current densities of 5 and 40 A g−1, respectively. In addition, a capacity fading lower than 2% after 5000 cycles of charging and discharging is obtained, indicating its long-term electrochemical stability.

Suggested Citation

  • Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    • Handle: RePEc:eee:energy:v:70:y:2014:i:c:p:612-617
    DOI: 10.1016/j.energy.2014.04.034
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214004472
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.04.034?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yue, Gentian & Wu, Jihuai & Xiao, Yaoming & Lin, Jianming & Huang, Miaoliang & Lan, Zhang & Fan, Leqing, 2013. "Functionalized graphene/poly(3,4-ethylenedioxythiophene):polystyrenesulfonate as counter electrode catalyst for dye-sensitized solar cells," Energy, Elsevier, vol. 54(C), pages 315-321.
    2. Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    3. Dubal, Deepak P. & Holze, Rudolf, 2013. "All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte," Energy, Elsevier, vol. 51(C), pages 407-412.
    4. Kalamse, Vijayanand & Wadnerkar, Nitin & Chaudhari, Ajay, 2013. "Multi-functionalized naphthalene complexes for hydrogen storage," Energy, Elsevier, vol. 49(C), pages 469-474.
    5. Jhan, Jing-Yi & Huang, Yu-Wei & Hsu, Chun-Han & Teng, Hsisheng & Kuo, Daniel & Kuo, Ping-Lin, 2013. "Three-dimensional network of graphene grown with carbon nanotubes as carbon support for fuel cells," Energy, Elsevier, vol. 53(C), pages 282-287.
    6. Kakaei, Karim & Gharibi, Hussien, 2014. "Palladium nanoparticle catalysts synthesis on graphene in sodium dodecyl sulfate for oxygen reduction reaction," Energy, Elsevier, vol. 65(C), pages 166-171.
    7. Mehrali, Mohammad & Latibari, Sara Tahan & Mehrali, Mehdi & Indra Mahlia, Teuku Meurah & Cornelis Metselaar, Hendrik Simon, 2013. "Preparation and properties of highly conductive palmitic acid/graphene oxide composites as thermal energy storage materials," Energy, Elsevier, vol. 58(C), pages 628-634.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Li & Zheng, Keqing & Ni, Meng & Leung, Michael K.H. & Xuan, Jin, 2015. "Partial modification of flow-through porous electrodes in microfluidic fuel cell," Energy, Elsevier, vol. 88(C), pages 563-571.
    2. Han, Chaoling & Chen, Zhenqian, 2021. "Study on the synergism of thermal transport and electrochemical of PEMFC based on N, P co-doped graphene substrate electrode," Energy, Elsevier, vol. 214(C).
    3. Yang, H.N. & Lee, D.C. & Park, K.W. & Kim, W.J., 2015. "Platinum–boron doped graphene intercalated by carbon black for cathode catalyst in proton exchange membrane fuel cell," Energy, Elsevier, vol. 89(C), pages 500-510.
    4. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    5. Xu, Ying & Ren, Li & Zhang, Zhongping & Tang, Yuejin & Shi, Jing & Xu, Chen & Li, Jingdong & Pu, Dongsheng & Wang, Zhuang & Liu, Huajun & Chen, Lei, 2018. "Analysis of the loss and thermal characteristics of a SMES (Superconducting Magnetic Energy Storage) magnet with three practical operating conditions," Energy, Elsevier, vol. 143(C), pages 372-384.
    6. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    7. Wang, Keliang & Cao, Yuhe & Wang, Xiaomin & Kharel, Parashu Ram & Gibbons, William & Luo, Bing & Gu, Zhengrong & Fan, Qihua & Metzger, Lloyd, 2016. "Nickel catalytic graphitized porous carbon as electrode material for high performance supercapacitors," Energy, Elsevier, vol. 101(C), pages 9-15.
    8. Fouda, M.E. & Elwakil, A.S. & Radwan, A.G. & Allagui, A., 2016. "Power and energy analysis of fractional-order electrical energy storage devices," Energy, Elsevier, vol. 111(C), pages 785-792.
    9. Liu, Chunli & Li, Qiang & Wang, Kai, 2021. "State-of-charge estimation and remaining useful life prediction of supercapacitors," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    10. Lee, Seul-Yi & Kim, Ji-Il & Park, Soo-Jin, 2014. "Activated carbon nanotubes/polyaniline composites as supercapacitor electrodes," Energy, Elsevier, vol. 78(C), pages 298-303.
    11. Shao, Zhou & Li, Hongji & Li, Mingji & Li, Cuiping & Qu, Changqing & Yang, Baohe, 2015. "Fabrication of polyaniline nanowire/TiO2 nanotube array electrode for supercapacitors," Energy, Elsevier, vol. 87(C), pages 578-585.
    12. Li, Dezhi & Li, Shuo & Zhang, Shubo & Sun, Jianrui & Wang, Licheng & Wang, Kai, 2022. "Aging state prediction for supercapacitors based on heuristic kalman filter optimization extreme learning machine," Energy, Elsevier, vol. 250(C).
    13. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    14. Kai Wang & Wanli Wang & Licheng Wang & Liwei Li, 2020. "An Improved SOC Control Strategy for Electric Vehicle Hybrid Energy Storage Systems," Energies, MDPI, vol. 13(20), pages 1-13, October.
    15. Mirzaeian, Mojtaba & Abbas, Qaisar & Gibson, Des & Mazur, Michal, 2019. "Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications," Energy, Elsevier, vol. 173(C), pages 809-819.
    16. Lee, W.H. & Yang, H.N. & Park, K.W. & Choi, B.S. & Yi, S.C. & Kim, W.J., 2016. "Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 96(C), pages 314-324.
    17. Kuzmenko, Volodymyr & Naboka, Olga & Haque, Mazharul & Staaf, Henrik & Göransson, Gert & Gatenholm, Paul & Enoksson, Peter, 2015. "Sustainable carbon nanofibers/nanotubes composites from cellulose as electrodes for supercapacitors," Energy, Elsevier, vol. 90(P2), pages 1490-1496.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    2. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    3. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    4. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    5. Li, Li & Zheng, Keqing & Ni, Meng & Leung, Michael K.H. & Xuan, Jin, 2015. "Partial modification of flow-through porous electrodes in microfluidic fuel cell," Energy, Elsevier, vol. 88(C), pages 563-571.
    6. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    7. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    8. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    9. Ghosh, Sampad & Withanage, Sajeevi S. & Chamlagain, Bhim & Khondaker, Saiful I. & Harish, Sivasankaran & Saha, Bidyut Baran, 2020. "Low pressure sulfurization and characterization of multilayer MoS2 for potential applications in supercapacitors," Energy, Elsevier, vol. 203(C).
    10. Yue, Gentian & Wang, Lei & Zhang, Xin'an & Wu, Jihuai & Jiang, Qiwei & Zhang, Weifeng & Huang, Miaoliang & Lin, Jianming, 2014. "Fabrication of high performance multi-walled carbon nanotubes/polypyrrole counter electrode for dye-sensitized solar cells," Energy, Elsevier, vol. 67(C), pages 460-467.
    11. Ma, F. & Zhang, P. & Xia, Z.Z. & Li, M., 2015. "How to enhance the effective thermal conductivity of composite material based on optimization method?," Energy, Elsevier, vol. 87(C), pages 400-411.
    12. Shaari, N. & Kamarudin, S.K., 2017. "Graphene in electrocatalyst and proton conductiong membrane in fuel cell applications: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 862-870.
    13. Abdelwaheb Trigui & Makki Abdelmouleh, 2023. "Improving the Heat Transfer of Phase Change Composites for Thermal Energy Storage by Adding Copper: Preparation and Thermal Properties," Sustainability, MDPI, vol. 15(3), pages 1-19, January.
    14. Yuan, Wenjing & Xie, Anjian & Chen, Ping & Huang, Fangzhi & Li, Shikuo & Shen, Yuhua, 2018. "Combustion reaction-derived nitrogen-doped porous carbon as an effective metal-Free catalyst for the oxygen reduction reaction," Energy, Elsevier, vol. 152(C), pages 333-340.
    15. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    16. Hidalgo, Diana & Tommasi, Tonia & Cauda, Valentina & Porro, Samuele & Chiodoni, Angelica & Bejtka, Katarzyna & Ruggeri, Bernardo, 2014. "Streamlining of commercial Berl saddles: A new material to improve the performance of microbial fuel cells," Energy, Elsevier, vol. 71(C), pages 615-623.
    17. Amaral, C. & Vicente, R. & Marques, P.A.A.P. & Barros-Timmons, A., 2017. "Phase change materials and carbon nanostructures for thermal energy storage: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1212-1228.
    18. Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
    19. Mirzaei, Farokh & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2017. "Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell," Energy, Elsevier, vol. 138(C), pages 696-705.
    20. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:70:y:2014:i:c:p:612-617. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.