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All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte

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  • Dubal, Deepak P.
  • Holze, Rudolf

Abstract

Recently, much effort has been devoted to accomplish thin, lightweight and flexible energy-storage devices for wearable electronics. Here, we demonstrate a novel kind of thin all-solid-state supercapacitor configuration with an extremely simple process using two slightly separated stacked nanosheets-like Mn3O4 electrodes well solidified in the H2SO4–polyvinyl alcohol gel electrolyte. This integrate device shows a high specific capacitance of 127 F g−1 for the electrode materials with good power and energy density values. These flexible and all-solid-state Mn3O4 supercapacitors bring new design opportunities of device configuration for future energy-storage devices. Present investigation first time reported that Mn3O4 is one of the most promising materials for the fabrication of all solid state thin film supercapacitors (ASSTFSs).

Suggested Citation

  • Dubal, Deepak P. & Holze, Rudolf, 2013. "All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte," Energy, Elsevier, vol. 51(C), pages 407-412.
    • Handle: RePEc:eee:energy:v:51:y:2013:i:c:p:407-412
    DOI: 10.1016/j.energy.2012.11.021
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    Cited by:

    1. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    2. Yuan, Chuanjun & Lin, Haibo & Lu, Haiyan & Xing, Endong & Zhang, Yusi & Xie, Bingyao, 2016. "Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors," Applied Energy, Elsevier, vol. 178(C), pages 260-268.
    3. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    4. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    5. Ghosh, Sampad & Withanage, Sajeevi S. & Chamlagain, Bhim & Khondaker, Saiful I. & Harish, Sivasankaran & Saha, Bidyut Baran, 2020. "Low pressure sulfurization and characterization of multilayer MoS2 for potential applications in supercapacitors," Energy, Elsevier, vol. 203(C).
    6. Rath, Tanmoy & Pramanik, Nilkamal & Kumar, Sandeep, 2017. "High electrochemical performance flexible solid-state supercapacitor based on Co-doped reduced graphene oxide and silk fibroin composites," Energy, Elsevier, vol. 141(C), pages 1982-1988.
    7. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    8. Patil, Bebi & Ahn, Suhyun & Park, Changyong & Song, Hyeonjun & Jeong, Youngjin & Ahn, Heejoon, 2018. "Simple and novel strategy to fabricate ultra-thin, lightweight, stackable solid-state supercapacitors based on MnO2-incorporated CNT-web paper," Energy, Elsevier, vol. 142(C), pages 608-616.
    9. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    10. Mohd Nor, Najah Syahirah & Deraman, Mohamad & Omar, Ramli & Awitdrus, & Farma, Rakhmawati & Basri, Nur Hamizah & Mohd Dolah, Besek Nurdiana & Mamat, Nurul Fatin & Yatim, Baharudin & Md Daud, Mohd Nori, 2015. "Influence of gamma irradiation exposure on the performance of supercapacitor electrodes made from oil palm empty fruit bunches," Energy, Elsevier, vol. 79(C), pages 183-194.
    11. Mirzaeian, Mojtaba & Abbas, Qaisar & Gibson, Des & Mazur, Michal, 2019. "Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications," Energy, Elsevier, vol. 173(C), pages 809-819.
    12. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    13. Inamdar, A.I. & Jo, Y. & Kim, J. & Han, J. & Pawar, S.M. & Kalubarme, R.S. & Park, C.J. & Hong, J.P. & Park, Y.S. & Jung, W. & Kim, H. & Im, Hyunsik, 2015. "Synthesis and enhanced electrochemical supercapacitive properties of manganese oxide nanoflake electrodes," Energy, Elsevier, vol. 83(C), pages 532-538.
    14. Park, Taehyun & Chang, Ikwhang & Jung, Ju Hae & Lee, Ha Beom & Ko, Seung Hwan & O'Hayre, Ryan & Yoo, Sung Jong & Cha, Suk Won, 2017. "Effect of assembly pressure on the performance of a bendable polymer electrolyte fuel cell based on a silver nanowire current collector," Energy, Elsevier, vol. 134(C), pages 412-419.

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