IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v178y2016icp260-268.html
   My bibliography  Save this article

Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors

Author

Listed:
  • Yuan, Chuanjun
  • Lin, Haibo
  • Lu, Haiyan
  • Xing, Endong
  • Zhang, Yusi
  • Xie, Bingyao

Abstract

Hierarchically porous MnO2/rice husks derived carbon (MnO2/RHC) composite with excellent electrochemical properties has been prepared as active material for supercapacitors. In this study, a two-step process was utilized for constructing this composite, involving carbonization–activation of rice husks to obtain RHC and in situ chemical precipitation to incorporate MnO2. Ultimately, MnO2 was uniformly distributed on the surface of RHC and hierarchically porous structure was well retained in the resultant MnO2/RHC composite. Based on cyclic voltammetry and galvanostatic charge–discharge measurements in 0.5M Na2SO4 solution, MnO2/RHC composite exhibits much higher specific capacitance than that of RHC. The specific capacitance of MnO2/RHC composite reaches 197.6Fg−1 at the scan rate of 5mVs−1 and 210.3Fg−1 at the current density of 0.5Ag−1. MnO2/RHC composite also displays favorable cycling stability with 80.2% capacitance retention after 5000 galvanostatic charge–discharge cycles. Therefore, taking advantage of the interconnected hierarchical pores that exist in its microstructure, MnO2/RHC composite is supposed to be a promising electrode material for high-performance supercapacitors.

Suggested Citation

  • Yuan, Chuanjun & Lin, Haibo & Lu, Haiyan & Xing, Endong & Zhang, Yusi & Xie, Bingyao, 2016. "Synthesis of hierarchically porous MnO2/rice husks derived carbon composite as high-performance electrode material for supercapacitors," Applied Energy, Elsevier, vol. 178(C), pages 260-268.
    • Handle: RePEc:eee:appene:v:178:y:2016:i:c:p:260-268
    DOI: 10.1016/j.apenergy.2016.06.057
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916308327
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.06.057?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Su, Xiaohui & Yu, Lin & Cheng, Gao & Zhang, Huanhua & Sun, Ming & Zhang, Xiaofei, 2015. "High-performance α-MnO2 nanowire electrode for supercapacitors," Applied Energy, Elsevier, vol. 153(C), pages 94-100.
    2. Dubal, Deepak P. & Holze, Rudolf, 2013. "All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte," Energy, Elsevier, vol. 51(C), pages 407-412.
    3. Castaings, Ali & Lhomme, Walter & Trigui, Rochdi & Bouscayrol, Alain, 2016. "Comparison of energy management strategies of a battery/supercapacitors system for electric vehicle under real-time constraints," Applied Energy, Elsevier, vol. 163(C), pages 190-200.
    4. Lee, Seul-Yi & Kim, Ji-Il & Park, Soo-Jin, 2014. "Activated carbon nanotubes/polyaniline composites as supercapacitor electrodes," Energy, Elsevier, vol. 78(C), pages 298-303.
    5. Zhao, Haoran & Wu, Qiuwei & Hu, Shuju & Xu, Honghua & Rasmussen, Claus Nygaard, 2015. "Review of energy storage system for wind power integration support," Applied Energy, Elsevier, vol. 137(C), pages 545-553.
    6. Gromadskyi, Denys G. & Chae, Jung H. & Norman, Stuart A. & Chen, George Z., 2015. "Correlation of energy storage performance of supercapacitor with iso-propanol improved wettability of aqueous electrolyte on activated carbon electrodes of various apparent densities," Applied Energy, Elsevier, vol. 159(C), pages 39-50.
    7. Shao, Zhou & Li, Hongji & Li, Mingji & Li, Cuiping & Qu, Changqing & Yang, Baohe, 2015. "Fabrication of polyaniline nanowire/TiO2 nanotube array electrode for supercapacitors," Energy, Elsevier, vol. 87(C), pages 578-585.
    8. Lo, An-Ya & Jheng, Yu & Huang, Tsao-Cheng & Tseng, Chuan-Ming, 2015. "Study on RuO2/CMK-3/CNTs composites for high power and high energy density supercapacitor," Applied Energy, Elsevier, vol. 153(C), pages 15-21.
    9. Su, Xiaohui & Yu, Lin & Cheng, Gao & Zhang, Huanhua & Sun, Ming & Zhang, Lei & Zhang, Jiujun, 2014. "Controllable hydrothermal synthesis of Cu-doped δ-MnO2 films with different morphologies for energy storage and conversion using supercapacitors," Applied Energy, Elsevier, vol. 134(C), pages 439-445.
    10. Li, Ya-Hao & Li, Qing-Yu & Wang, Hong-Qiang & Huang, You-Guo & Zhang, Xiao-Hui & Wu, Qiang & Gao, Hong-Quan & Yang, Jian-Hong, 2015. "Synthesis and electrochemical properties of nickel–manganese oxide on MWCNTs/CFP substrate as a supercapacitor electrode," Applied Energy, Elsevier, vol. 153(C), pages 78-86.
    11. Wang, Xue & Deng, Jinxing & Duan, Xiaojuan & Liu, Dong & Liu, Peng, 2015. "Fluorescent brightener CBS-X doped polypyrrole as smart electrode material for supercapacitors," Applied Energy, Elsevier, vol. 153(C), pages 70-77.
    12. Gao, Yu & Li, Lei & Jin, Yuming & Wang, Yu & Yuan, Chuanjun & Wei, Yingjin & Chen, Gang & Ge, Junjie & Lu, Haiyan, 2015. "Porous carbon made from rice husk as electrode material for electrochemical double layer capacitor," Applied Energy, Elsevier, vol. 153(C), pages 41-47.
    13. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Wenli & Lin, Nan & Liu, Debo & Xu, Jinhui & Sha, Jinxin & Yin, Jian & Tan, Xiaobo & Yang, Huiping & Lu, Haiyan & Lin, Haibo, 2017. "Direct carbonization of rice husk to prepare porous carbon for supercapacitor applications," Energy, Elsevier, vol. 128(C), pages 618-625.
    2. Bao, Jinpeng & Liang, Chen & Lu, Haiyan & Lin, Haibo & Shi, Zhan & Feng, Shouhua & Bu, Qijing, 2018. "Facile fabrication of porous carbon microtube with surrounding carbon skeleton for long-life electrochemical capacitive energy storage," Energy, Elsevier, vol. 155(C), pages 899-908.
    3. Nahed Ahmed Hussien, 2023. "Antimicrobial Potential of Biosynthesized Zinc Oxide Nanoparticles Using Banana Peel and Date Seeds Extracts," Sustainability, MDPI, vol. 15(11), pages 1-12, June.
    4. Barzegar, Farshad & Bello, Abdulhakeem & Dangbegnon, Julien K. & Manyala, Ncholu & Xia, Xiaohua, 2017. "Asymmetric supercapacitor based on activated expanded graphite and pinecone tree activated carbon with excellent stability," Applied Energy, Elsevier, vol. 207(C), pages 417-426.
    5. Cuong, Dinh Viet & Matsagar, Babasaheb M. & Lee, Mengshan & Hossain, Md. Shahriar A. & Yamauchi, Yusuke & Vithanage, Meththika & Sarkar, Binoy & Ok, Yong Sik & Wu, Kevin C.-W. & Hou, Chia-Hung, 2021. "A critical review on biochar-based engineered hierarchical porous carbon for capacitive charge storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    6. Li, Dezhi & Li, Shuo & Zhang, Shubo & Sun, Jianrui & Wang, Licheng & Wang, Kai, 2022. "Aging state prediction for supercapacitors based on heuristic kalman filter optimization extreme learning machine," Energy, Elsevier, vol. 250(C).
    7. Sun, Bingkang & Zhang, Xiaoyun & Fan, Xing & Wang, Ruiyu & Bai, Hongcun & Wei, Xianyong, 2022. "Interface modification based on MnO2@N-doped activated carbon composites for flexible solid-state asymmetric supercapacitors," Energy, Elsevier, vol. 249(C).
    8. Mukhtar Yeleuov & Christopher Seidl & Tolganay Temirgaliyeva & Azamat Taurbekov & Nicholay Prikhodko & Bakytzhan Lesbayev & Fail Sultanov & Chingis Daulbayev & Serik Kumekov, 2020. "Modified Activated Graphene-Based Carbon Electrodes from Rice Husk for Supercapacitor Applications," Energies, MDPI, vol. 13(18), pages 1-10, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Su, Y. & Zhitomirsky, I., 2015. "Asymmetric electrochemical supercapacitor, based on polypyrrole coated carbon nanotube electrodes," Applied Energy, Elsevier, vol. 153(C), pages 48-55.
    2. Mirzaeian, Mojtaba & Abbas, Qaisar & Gibson, Des & Mazur, Michal, 2019. "Effect of nitrogen doping on the electrochemical performance of resorcinol-formaldehyde based carbon aerogels as electrode material for supercapacitor applications," Energy, Elsevier, vol. 173(C), pages 809-819.
    3. Wang, Xue & Deng, Jinxing & Duan, Xiaojuan & Liu, Dong & Liu, Peng, 2015. "Fluorescent brightener CBS-X doped polypyrrole as smart electrode material for supercapacitors," Applied Energy, Elsevier, vol. 153(C), pages 70-77.
    4. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    5. Patil, Bebi & Ahn, Suhyun & Park, Changyong & Song, Hyeonjun & Jeong, Youngjin & Ahn, Heejoon, 2018. "Simple and novel strategy to fabricate ultra-thin, lightweight, stackable solid-state supercapacitors based on MnO2-incorporated CNT-web paper," Energy, Elsevier, vol. 142(C), pages 608-616.
    6. Barzegar, Farshad & Bello, Abdulhakeem & Dangbegnon, Julien K. & Manyala, Ncholu & Xia, Xiaohua, 2017. "Asymmetric supercapacitor based on activated expanded graphite and pinecone tree activated carbon with excellent stability," Applied Energy, Elsevier, vol. 207(C), pages 417-426.
    7. Zhao, Liwei & Li, Hongji & Li, Mingji & Xu, Sheng & Li, Cuiping & Qu, Changqing & Zhang, Lijun & Yang, Baohe, 2016. "Lithium-ion storage capacitors achieved by CVD graphene/TaC/Ta-wires and carbon hollow spheres," Applied Energy, Elsevier, vol. 162(C), pages 197-206.
    8. Chen, Long Xiang & Xie, Mei Na & Zhao, Pan Pan & Wang, Feng Xiang & Hu, Peng & Wang, Dong Xiang, 2018. "A novel isobaric adiabatic compressed air energy storage (IA-CAES) system on the base of volatile fluid," Applied Energy, Elsevier, vol. 210(C), pages 198-210.
    9. Qin, Chao & Saunders, Gordon & Loth, Eric, 2017. "Offshore wind energy storage concept for cost-of-rated-power savings," Applied Energy, Elsevier, vol. 201(C), pages 148-157.
    10. Gui, Yonghao & Wei, Baoze & Li, Mingshen & Guerrero, Josep M. & Vasquez, Juan C., 2018. "Passivity-based coordinated control for islanded AC microgrid," Applied Energy, Elsevier, vol. 229(C), pages 551-561.
    11. Cheng, Meng & Sami, Saif Sabah & Wu, Jianzhong, 2017. "Benefits of using virtual energy storage system for power system frequency response," Applied Energy, Elsevier, vol. 194(C), pages 376-385.
    12. Bizon, Nicu, 2019. "Real-time optimization strategies of Fuel Cell Hybrid Power Systems based on Load-following control: A new strategy, and a comparative study of topologies and fuel economy obtained," Applied Energy, Elsevier, vol. 241(C), pages 444-460.
    13. Desreveaux, A. & Bouscayrol, A. & Trigui, R. & Hittinger, E. & Castex, E. & Sirbu, G.M., 2023. "Accurate energy consumption for comparison of climate change impact of thermal and electric vehicles," Energy, Elsevier, vol. 268(C).
    14. Mpho J. Lencwe & Shyama P. Chowdhury & Thomas O. Olwal, 2018. "A Multi-Stage Approach to a Hybrid Lead Acid Battery and Supercapacitor System for Transport Vehicles," Energies, MDPI, vol. 11(11), pages 1-16, October.
    15. Nyong-Bassey, Bassey Etim & Giaouris, Damian & Patsios, Charalampos & Papadopoulou, Simira & Papadopoulos, Athanasios I. & Walker, Sara & Voutetakis, Spyros & Seferlis, Panos & Gadoue, Shady, 2020. "Reinforcement learning based adaptive power pinch analysis for energy management of stand-alone hybrid energy storage systems considering uncertainty," Energy, Elsevier, vol. 193(C).
    16. Nallapaneni Manoj Kumar & Aneesh A. Chand & Maria Malvoni & Kushal A. Prasad & Kabir A. Mamun & F.R. Islam & Shauhrat S. Chopra, 2020. "Distributed Energy Resources and the Application of AI, IoT, and Blockchain in Smart Grids," Energies, MDPI, vol. 13(21), pages 1-42, November.
    17. Fichter, Tobias & Soria, Rafael & Szklo, Alexandre & Schaeffer, Roberto & Lucena, Andre F.P., 2017. "Assessing the potential role of concentrated solar power (CSP) for the northeast power system of Brazil using a detailed power system model," Energy, Elsevier, vol. 121(C), pages 695-715.
    18. Xiong, Rui & Duan, Yanzhou & Cao, Jiayi & Yu, Quanqing, 2018. "Battery and ultracapacitor in-the-loop approach to validate a real-time power management method for an all-climate electric vehicle," Applied Energy, Elsevier, vol. 217(C), pages 153-165.
    19. Mehrabankhomartash, Mahmoud & Rayati, Mohammad & Sheikhi, Aras & Ranjbar, Ali Mohammad, 2017. "Practical battery size optimization of a PV system by considering individual customer damage function," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 36-50.
    20. Wang, Bin & Xu, Jun & Cao, Binggang & Ning, Bo, 2017. "Adaptive mode switch strategy based on simulated annealing optimization of a multi-mode hybrid energy storage system for electric vehicles," Applied Energy, Elsevier, vol. 194(C), pages 596-608.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:178:y:2016:i:c:p:260-268. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.