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Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes

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  • Kim, Jongmin
  • Ju, Haeri
  • Inamdar, Akbar I.
  • Jo, Yongcheol
  • Han, J.
  • Kim, Hyungsang
  • Im, Hyunsik

Abstract

Ternary Ag/MnO2/PANI (silver/manganese oxide/polyaniline) nanocomposite thin films were synthesized for supercapacitor applications using a new synthetic strategy including a pulsed potential electrodeposition technique. The agglomerated nanoscale-vermicular-like structure of the pure PANI is converted into more uniform vermicular morphology containing Ag and MnO2. The electrochemical supercapacitor properties of the ternary nanocomposite films are investigated in a 0.5 M LiClO4 + PC electrolyte. The current density of the Ag/MnO2/PANI nanocomposite film obtained from the CV (cyclic voltammogram) is much higher than that of the pure PANI. Furthermore, the specific capacitance of the ternary Ag/MnO2/PANI nanocomposite is calculated to be 621 F/g and 800 F/g from CV and CD (charge–discharge) measurements, respectively. The cycling stability of the ternary nanocomposites (as high as ∼83%) is significantly enhanced compared to that of a pure PANI (∼66%) sample.

Suggested Citation

  • Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    • Handle: RePEc:eee:energy:v:70:y:2014:i:c:p:473-477
    DOI: 10.1016/j.energy.2014.04.018
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    References listed on IDEAS

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    1. Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    2. Dubal, Deepak P. & Holze, Rudolf, 2013. "All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte," Energy, Elsevier, vol. 51(C), pages 407-412.
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    4. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
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    10. Inamdar, A.I. & Jo, Y. & Kim, J. & Han, J. & Pawar, S.M. & Kalubarme, R.S. & Park, C.J. & Hong, J.P. & Park, Y.S. & Jung, W. & Kim, H. & Im, Hyunsik, 2015. "Synthesis and enhanced electrochemical supercapacitive properties of manganese oxide nanoflake electrodes," Energy, Elsevier, vol. 83(C), pages 532-538.
    11. Pappu, Samhita & Rao, Tata N. & Martha, Surendra K. & Bulusu, Sarada V., 2022. "Electrodeposited Manganese Oxide based Redox Mediator Driven 2.2 V High Energy Density Aqueous Supercapacitor," Energy, Elsevier, vol. 243(C).
    12. Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.

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